• Title/Summary/Keyword: Complex forming method

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Quantum Chemical Studies on Nicotinato Lead(II) Complex [Pb(II)(C5H4NCOO)2]

  • Zhao, Pu Su;Li, Rong Qing;Song, Jie;Guo, Meng Ping
    • Bulletin of the Korean Chemical Society
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    • v.29 no.3
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    • pp.546-550
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    • 2008
  • The title compound of nicotinato lead(II) complex [Pb$(C_5H_4NCOO)_2$] has been optimized at B3LYP/LANL2DZ and HF/LANL2DZ levels of theory. The calculated results show that the lead(II) ion adopts 2- coordinate geometry, which is the same as its crystal structure and different from the 4-coordinate geometry of isonicotinato lead(II) complex. Atomic charge distributions indicate that during forming the title compound, each nicotinic acid ion transfers their negative charges to central lead(II) ion. The electronic spectra calculated by B3LYP/LANL2DZ level show that there exist two absorption bands, which have some red shifts compared with those of isonicotinato lead(II) complex and the electronic transitions are mainly derived from intraligand $\pi$ -$\pi$ transition and ligand-to-metal charge transfer (LMCT) transition. CIS-HF method is not suitable for the system studied here. The thermodynamic properties of the title compound at different temperatures have been calculated and corresponding relations between the properties and temperature have also been obtained. The second order optical nonlinearity was calculated, and the molecular hyperpolarizability was $1.147754{\times}10^{-30}$ esu.

The Excavated Costume of Jeon-Ui Lee Unearthed in Ue-Ryoung (宜寧 全義李氏墓 출토복식에 관한 고찰)

  • Park, Fil-Soon;Park, Yoon-Mee;Jeong, Bok-Nam
    • The Research Journal of the Costume Culture
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    • v.13 no.1
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    • pp.102-120
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    • 2005
  • Three Jang-Ue's and eleven drapery were investigated in the excavated costume in Ue-Ryeong, Gyeong-Sang-Nam-Do. Three Jang-Ue's have three different colors. the length, the width, and the wide of quilting are different as well. The outer collar of a coat is a double collar while the inturned collar is a single collar. In case of Dark blue and Pink Jang-Ue. The large section of cloth forming the body of a Korean coat is getting narrower while the reinforcing cloth strip is getting wider as the time is passing by. All the three Jang-Ue's have the different handling methods of a attached to the top border of a Korean coat, and Pink Jang-Ue doesn't have a attached to the tip border of a Korean coat. The handling method of the hemline are all different. And the handling method of the cuffs are all different. The silk is main in the woven goods, partly hemp, mixed fabrics and cotton. Especially complex gauze with supplementary wefts that were found unusually in Cho-Sun Dynasty are very import to study the complex gauze. The fond relics of the Jeon-Ui Lee family reveal various formational methods and specific characters of the excavated costume. There fore these that bring the Jang-Ue shape and the textile's feature in Gyeong-Sang-Nam-Do region, from 16th to 17th are very valuable.

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Multicriteria shape design of a sheet contour in stamping

  • Oujebbour, Fatima-Zahra;Habbal, Abderrahmane;Ellaia, Rachid;Zhao, Ziheng
    • Journal of Computational Design and Engineering
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    • v.1 no.3
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    • pp.187-193
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    • 2014
  • One of the hottest challenges in automotive industry is related to weight reduction in sheet metal forming processes, in order to produce a high quality metal part with minimal material cost. Stamping is the most widely used sheet metal forming process; but its implementation comes with several fabrication flaws such as springback and failure. A global and simple approach to circumvent these unwanted process drawbacks consists in optimizing the initial blank shape with innovative methods. The aim of this paper is to introduce an efficient methodology to deal with complex, computationally expensive multicriteria optimization problems. Our approach is based on the combination of methods to capture the Pareto Front, approximate criteria (to save computational costs) and global optimizers. To illustrate the efficiency, we consider the stamping of an industrial workpiece as test-case. Our approach is applied to the springback and failure criteria. To optimize these two criteria, a global optimization algorithm was chosen. It is the Simulated Annealing algorithm hybridized with the Simultaneous Perturbation Stochastic Approximation in order to gain in time and in precision. The multicriteria problems amounts to the capture of the Pareto Front associated to the two criteria. Normal Boundary Intersection and Normalized Normal Constraint Method are considered for generating a set of Pareto-optimal solutions with the characteristic of uniform distribution of front points. The computational results are compared to those obtained with the well-known Non-dominated Sorting Genetic Algorithm II. The results show that our proposed approach is efficient to deal with the multicriteria shape optimization of highly non-linear mechanical systems.

Dynamic Explicit Elastic-Plastic Finite Element Analysis of Large Auto-body Panel Stamping Process (대형 차체판넬 스템핑공정에서의 동적 외연적 탄소성 유한요소해석)

  • 정동원;김귀식;양동열
    • Journal of Ocean Engineering and Technology
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    • v.12 no.1
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    • pp.10-22
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    • 1998
  • In the present work the elastic-plastic FE formulations using dynamic explicit time integration schemes are used for numerical analysis of a large auto-body panel stamping processes. For analyses of more complex cases with larger and more refined meshes, the explicit method is more time effective than implicit method, and has no convergency problem and has the robust nature of contact and friction algorithms while implicit method is widely used because of excellent accuracy and reliability. The elastic-plastic scheme is more reliable and rigorous while the rigid-plastic scheme require small computation time. In finite element simulation of auto-body panel stamping processes, the roobustness and stability of computation are important requirements since the computation time and convergency become major points of consideration besides the solution accuracy due to the complexity of geometry conditions. The performnce of the dynamic explicit algorithms are investigated by comparing the simulation results of formaing of complicate shaped autobody parts, such as a fuel tank and a rear hinge, with the experimental results. It has been shown that the proposed dynamic explicit elastic-plastic finite element method enables an effective computation for complicated auto-body panel stamping processes.

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Arabidopsis cyclin D2 expressed in rice forms a functional cyclin-dependent kinase complex that enhances seedling growth

  • Oh, Se-Jun;Kim, Su-Jung;Kim, Youn Shic;Park, Su-Hyun;Ha, Sun-Hwa;Kim, Ju-Kon
    • Plant Biotechnology Reports
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    • v.2 no.4
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    • pp.227-231
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    • 2008
  • D-class cyclins play important roles in controlling the cell cycle in development and in response to external signals by forming the regulatory subunit of cyclin-dependent kinase (CDK) complexes. To evaluate the effects of D-class cyclins in transgenic rice plants, Arabidopsis cyclin D2 gene (CycD2) was linked to the maize ubiquitin1 promoter (Ubi1) and introduced into rice by the Agrobacterium-mediated transformation method. Genomic deoxyribonucleic acid (DNA), ribonucleic acid (RNA), and Western blot hybridizations of the Ubi1:-CycD2 plants revealed copy number of transgene and its increased expression in leaf and callus cells at messenger RNA (mRNA) and/or protein levels. The H1 kinase assay using the immunoprecipitates of protein extracts from the Ubi1:CycD2 plants and nontransgenic controls demonstrated that the introduced Arabidopsis CycD2 forms a functional CycD2/CDK complex with an unidentified CDK of rice. Shoot and root growth was enhanced in the Ubi1:CycD2 seedlings compared with nontransgenic controls, together, suggesting that Arabidopsis cyclin D2 interacts with a rice cyclin-dependent kinase, consequently enhancing seedling growth.

A Study on the logistics complex site selection factor (물류단지 입지선정요인에 관한 연구)

  • Back, Sun-Woo;Kang, Kyung-Sik
    • Journal of the Korea Safety Management & Science
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    • v.17 no.4
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    • pp.287-295
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    • 2015
  • modern logistics are required to carry out functions such as timely adjustment and swift adaptation to changing patterns, and this leads to the emphasis on forming logistics parks. Logistics parks make profits using the efficiency of time and space. Such logistics parks play an important role in a corporation creating operating profits as well as acting as a method of alternative investment for individuals. Logistics parks no longer simply store materials, but have become a place that plays an important role in various areas of corporate and individual activities, and thus the analysis of the selection of the location of logistics parks and the related characteristics is extremely important. There are many existing studies on the selection of locations of logistics parks but work on the factors related to location selection by industry seem lacking. As such, in the course of this study we have used preceeding studies to draft a questionnaire on which selection factors affect the selection of logistics park location in different industries and conducted empirical analysis of the questionnaire results to uncover the factors that affect the selection of the locations of logistics parks in different industries.

Optimal Matrix Standardization for Pattern Flattening Using Grid Method -Focused on Young Women's Upper Front Shell- (Grid method에 의한 3차원 형상의 평면전개를 위한 optimal matrix 표준화 연구 -$18{\sim}24$세 여성 Upper Front Shell을 중심으로-)

  • Choi, Young-Lim;Nam, Yun-Ja;Choi, Kueng-Mi
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.8
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    • pp.1242-1252
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    • 2006
  • Many applications in computer graphics require complex, highly detailed models. However, to control processing time, it is often desirable to use approximations in place of excessively detailed models. Therefore, we have developed the notion of an optimal matrix to simplify the model surface which can then rapidly obtain high quality 2D patterns by flattening the 3D surface. Firstly, the woman's 3D body was modeled based on Size Korea data. Secondly, the 3D model was divided by shell and block for the pattern draft. Thirdly, each block was flattened by the grid and bridge method. Finally, we select the optimal matrix and demonstrate it's efficiency and quality. The proposed approach accommodates surfaces with darts, which are commonly utilized in the clothing industry to reduce the deformation of surface forming and flattening. The resulting optimal matrix could be an initiation of standardization for pattern flattening. This can facilitate much better approximations, in both efficiency and exactness.

Synthesis, Crystal Structure and Theoretical Calculation of a Novel Nickel(II) Complex with Dibromotyrosine and 1,10-Phenanthroline

  • Huang, Guimei;Zhang, Xia;Fan, Yuhua;Bi, Caifeng;Yan, Xingchen;Zhang, Zhongyu;Zhang, Nan
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.2889-2894
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    • 2013
  • A new complex [$Ni(phen)(C_9H_8Br_2NO_3)_2{\cdot}2CH_3OH{\cdot}2H_2O$] [phen: 1,10-phenanthroline $C_9H_8Br_2NO_3$: 3,5-dibromo-L-tyrosine] was synthesized and characterized by IR, elemental analysis and single crystal X-ray diffraction. X-ray crystallography shows that Ni(II) ion is six-coordinated. The Ni(II) ion coordinates with four nitrogen atoms and two oxygen atoms from three ligands, forming a mononuclear Ni(II) complex. The crystal crystallizes in the Orthorhombic system, space group $P2_12_12$ with a = 12.9546 ${\AA}$, b = 14.9822 ${\AA}$, c = 9.9705 ${\AA}$, V = 1935.2 ${\AA}$, Z = 1, F(000) = 1008, S = 0.969, ${\rho}_{calcd}=1.742g{\cdot}cm^{-3}$, ${\mu}=4.688mm^{-1}$, $R_1$ = 0.0529 and $wR_2$ = 0.0738 for 3424 observed reflections (I > $2{\sigma}(I)$). Theoretical study of the title complex was carried out by density functional theory (DFT) method and the B3LYP method employing the $6-3l+G^*$ basis set. The energy gap between HOMO and LUMO indicates that this complex is prone to interact with DNA. CCDC: 908041.

Performance Evaluation and Analysis of the Screw and Die of the Single Screw Extruder Using the CFD (CFD를 이용한 단축압출기 스크류 및 다이스의 성능시험평가 및 해석에 관한 연구)

  • Kim, Jae-Yoel;Chung, Hyo-Hee
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.18 no.2
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    • pp.194-200
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    • 2009
  • The extruder type is classified as screw type and non-screw type in terms of the extrusion method. The screw type extruder, which is the most frequently used, is classified as the single screw extruder and the multi-screw extruder. They are classified as vertical type and horizontal type in terms of structure; and those for compounding and for forming in terms of function. The single screw extruder is a universal extruder, most of which is suitable for the extrusion forming of thermoplastic resin. The multi-screw(two-screw, three-screw and four-screw) extruder can increase the extrusion power using the engagement of the screw flank. The single screw extruder does not have a good mixing ratio of the raw material and stable extrusion power, while it has low construction cost and operation cost. In this study, the single screw extruder, which has many weak points compared with the multi-screw extruder, was studied. There have been many studies on the single screw extruder, and they led to its significant development. The existing study method, however, had complex analysis processes and required much time. In this study, the CFD was applied to the performance test and analysis of the extruder, and the optimal design condition of the extrusion power for the screw and die of the single screw extruder was found by comparing the analysis results with the actual performance measurement of the single screw extruder.

FEA of Pipe Rolling Process Using Planetary Rolling Mill for Stainless Steel (유성압연기를 사용한 스테인리스 강관 압연공정의 유한요소해석)

  • Lee, Jung-Kil;Kim, Kwan-Woo;Cho, Hae-Yong
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.2
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    • pp.244-251
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    • 2011
  • Pipe rolling process using the planetary rolling mill for AISI 304 stainless steel has been studied by using finite element method. Mannesmann method using three-roll is applied to this rolling process. Commonly, rolling process has started from the cold working and finished to the hot working. This rolling process has more advantage that make reduction of process and cost than existing extrusion process. This process includes various and complex process parameters. Each of the process parameters affects forming result. Therefore, all of the process parameters should be considered in FEA. In this study, possibility and productivity of forming pipe for AISI 304 stainless steel had been investigated. Also, preheating process and variations of rotation velocity and product thickness were considered in FEA. Rolling process for AISI 304 stainless steel pipe was successfully simulated and it should be useful to determine optimal rolling condition.