• 제목/요약/키워드: Complex Modulus

검색결과 233건 처리시간 0.035초

수분함량에 따른 율무가루의 점도변화 및 동적물성 특성에 관한 연구 (Viscosity and Dynamic Rheological Properties of Job's-tears as a Function of Moisture Content)

  • 윤원병;김병용;신동훈
    • 한국식품과학회지
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    • 제29권5호
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    • pp.932-938
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    • 1997
  • Changes in viscosity and dynamic theological properties of Job's-tears were measured by Bohlin dynamic tester as a function of moisture, and measurement was performed within a linear viscoelastic range. The result of the shear stress vs shear rate of Job's-tears at different moisture contents $(50{\sim}75%)$ was applied to mathematical models and Herschel-Bulkley model showed the highest correlation coefficient. Lower moisture content (55%) produced higher yield stress and consistency index, but lower flow behavior index, whereas higher moisture content showed reverse effects. Job's-tears with $50{\sim}70%$ moisture contents showed a higher storage modulus (G') than loss modulus (G') at all frequencies, showing a higher concentrated polymer characteristics. However, higher moisture content (>75%) showed crossover point between G' and G', and frequency dependency. As the moisture content was increased, the amount of viscoelastic properties such as G', G', complex viscosity decreased during heating, and initial temperature and miximum value of viscoelastic properties shifted to higher temperatures, representing the moisture-dependence of Job's-tears upon theological properties.

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Linear Low Density Polyethylene (LLDPE)/Zeolite Microporous Composite Film

  • Jagannath Biswas;Kim, Hyun;Soonja Choe;Patit P. Kundu;Park, Young-Hoon;Lee, Dai-Soo
    • Macromolecular Research
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    • 제11권5호
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    • pp.357-367
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    • 2003
  • The linear low density polyethylene (LLDPE)/zeolite composite using novel inorganic filler, zeolite, is prepared by a conventional compounding procedure using a twin-screw extruder. The observed scanning electron microscopic (SEM) morphology shows a good dispersion and adhesion of zeolite in the LLDPE matrix. The mechanical properties in terms of the Young's modulus, the yield stress, the impact strength, and the elongation at break were enhanced with a successive increment of zeolite content up to 40 wt%. The X-ray diffraction measurement is of supportive for the improved mechanical properties and the complex melt viscosity is as well. Upon applying a certain level of strain on the composites, the dewetting, the air hole formation and its growth are characterized. The dewetting originates around the filler particles at low strain and induces elliptical micropores upon further stretching. The microporosity such as the aspect ratio, the number and the total area of the air holes is also characterized. Thus, the composites loaded 40 % zeolite and 300 % elongation may be applicable for breathable microporous films with improved modulus, impact and yield stress, elongation at break, microporosity and air hole properties.

Preparation and Characterization of Biodegradable Poly(butylene succinate)(PBS) Foams

  • Lim, Sang-Kyun;Jang, Suk-Goo;Lee, Seok-In;Lee, Kwang-Hee;Chin, In-Joo
    • Macromolecular Research
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    • 제16권3호
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    • pp.218-223
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    • 2008
  • In order to obtain crosslinked poly(butylene succinate) (PBS) foams with a closed-cell structure, a commercial-grade PBS was first modified in the melt using two different branching agents to increase the melt viscosity. The rheological properties of the branched and crosslinked PBS were examined by varying the amount of the branching agents. The complex viscosity of the crosslinked PBS increased with increasing amount of the branching agent. However, it decreased with increasing frequency. When 2 phr of the branching agent was added to PBS, the storage modulus (G') was higher than the loss modulus (G") throughout the entire frequency range, showing that the addition of a branching agent increases the melt viscosity and elasticity of PBS effectively. Closed-cell PBS foams were prepared by mixing the chemical blowing agent with the crosslinked PBS. The effect of the foaming conditions such as temperature and time, and the amount of the crosslinking agent on the structure of the expanded PBS foams were also investigated.

Static performance of a new GFRP-metal string truss bridge subjected to unsymmetrical loads

  • Zhang, Dongdong;Yuan, Jiaxin;Zhao, Qilin;Li, Feng;Gao, Yifeng;Zhu, Ruijie;Zhao, Zhiqin
    • Steel and Composite Structures
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    • 제35권5호
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    • pp.641-657
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    • 2020
  • A unique lightweight string truss deployable bridge assembled by thin-walled fiber reinforced polymer (FRP) and metal profiles was designed for emergency applications. As a new structure, investigations into the static structural performance under the serviceability limit state are desired for examining the structural integrity of the developed bridge when subjected to unsymmetrical loadings characterized by combined torsion and bending. In this study, a full-scale experimental inspection was conducted on a fabricated bridge, and the combined flexural-torsional behavior was examined in terms of displacement and strains. The experimental structure showed favorable strength and rigidity performances to function as deployable bridge under unsymmetrical loading conditions and should be designed in accordance with the stiffness criterion, the same as that under symmetrical loads. In addition, a finite element model (FEM) with a simple modeling process, which considered the multi segments of the FRP members and realistic nodal stiffness of the complex unique hybrid nodal joints, was constructed and compared against experiments, demonstrating good agreement. A FEM-based numerical analysis was thereafter performed to explore the effect of the change in elastic modulus of different FRP elements on the static deformation of the bridge. The results confirmed that the change in elastic modulus of different types of FRP element members caused remarkable differences on the bending and torsional stiffness of the hybrid bridge. The global stiffness of such a unique bridge can be significantly enhanced by redesigning the critical lower string pull bars using designable FRP profiles with high elastic modulus.

Ti염 및 Fe염으로 화학처리된 염색공단 슬러지를 재활용한 인공경량골재의 물리적 특성에 관한 연구 (Study on the Physical Properties of the Artificial Lightweight Aggregate Recycled from the Dyestuff Sludge Treated Chemically With Ti and Fe Salt)

  • 최종오;정용욱
    • 한국건설순환자원학회논문집
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    • 제3권1호
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    • pp.34-42
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    • 2015
  • 본 연구는 단순매립 및 소각처리 되고 있는 염색공단 슬러지의 재활용을 목적으로 Ti염과 Fe염으로 화학 처리된 염색공단 슬러지를 이용하여 인공경량골재를 제조하고, 인공경량골재로의 활용성 검토를 위하여 골재의 물리적 특성과 환경유해성 등을 평가하였다. 인공경량골재 제조는 점결제로 점토를 이용하여 점토와 슬러지 배합비율에 따른 성형성을 평가하여 최적 함수량을 선정하고, 최적 배합비를 기준으로 둥근 모양의 형태로 가공한 후 건조과정과 2단계의 소성과정을 거쳐 제조하였다. 제조된 경량골재는 KS F 2534 "구조용 경량 골재"를 기준으로 인공경량골재의 입도 및 조립률, 밀도 및 흡수율, 단위용적질량, 안정성 및 환경유해성 등을 평가하였다. 실험 결과 입도와 조립률에서 기준 범위를 일부 벗어났으나 다른 모든 물리적 특성은 기준 값을 모두 만족하는 것으로 나타났으며, 입도와 조립률도 향후 제조공정에서 충분히 해결할 수 있는 것을 확인할 수 있었다.

Neuro-fuzzy based prediction of the durability of self-consolidating concrete to various sodium sulfate exposure regimes

  • Bassuoni, M.T.;Nehdi, M.L.
    • Computers and Concrete
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    • 제5권6호
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    • pp.573-597
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    • 2008
  • Among artificial intelligence-based computational techniques, adaptive neuro-fuzzy inference systems (ANFIS) are particularly suitable for modelling complex systems with known input-output data sets. Such systems can be efficient in modelling non-linear, complex and ambiguous behaviour of cement-based materials undergoing single, dual or multiple damage factors of different forms (chemical, physical and structural). Due to the well-known complexity of sulfate attack on cement-based materials, the current work investigates the use of ANFIS to model the behaviour of a wide range of self-consolidating concrete (SCC) mixture designs under various high-concentration sodium sulfate exposure regimes including full immersion, wetting-drying, partial immersion, freezing-thawing, and cyclic cold-hot conditions with or without sustained flexural loading. Three ANFIS models have been developed to predict the expansion, reduction in elastic dynamic modulus, and starting time of failure of the tested SCC specimens under the various high-concentration sodium sulfate exposure regimes. A fuzzy inference system was also developed to predict the level of aggression of environmental conditions associated with very severe sodium sulfate attack based on temperature, relative humidity and degree of wetting-drying. The results show that predictions of the ANFIS and fuzzy inference systems were rational and accurate, with errors not exceeding 5%. Sensitivity analyses showed that the trends of results given by the models had good agreement with actual experimental results and with thermal, mineralogical and micro-analytical studies.

Poly(carbonate-g-styrene)공중합체의 유리정이 영역에서의 동적 점탄성과 광학특성 (Dynamic Viscoelasticity and Optical Properties of Poly(carbonate-g-styrene) Copolymers in the Glass Transition Zone)

  • 황의정
    • 유변학
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    • 제9권4호
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    • pp.163-173
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    • 1997
  • Polystyrene/polycarbonate 조성이 약 50/50인 3종류의 Poly(carbonate-g-styrene) 공중합체의 동적 탄성율, E*($\omega$)와 동적 스트레인-광학계수 O*($\omega$)을 유리전이 영역부근의 여러온도에서 동시에 측정하여 연구하였다. 두 개의 공중합체는 각각의 스티렌 그라프트쇄 에 5, 10 wt%의 MAH를 함유하고 있다. 이들 공중합체의 E*($\omega$)와 O*($\omega$)완화거동과 그라 프트 공중합체의 상용성과 연관하여 비교 고찰하였다. 공중합체들의 E*($\omega$)는 전형적인 무 정형 고분자의 유리전이 완하거동을 보였으며 정성적인 차이를 발견할수 없었다. 그러나 고 강도의 단일 tan$\delta$분산의 저주파수 영역에 미세분산을 나타내, 공중합체는 2상으로 분리되 어 있음이 추정되엇다. 폴리스티렌 그라프트체에 무수 말레인산 함유량이 증가함에 따라, 저 주파수 영역의 미세피크가 $\alpha$주분산에 병합되어 성분 고분자간의 상호 형동성이 증가함을 알수 있었다. 3공중합체의 유사한 기계적 특성과는 달리, 광학적 완화 스펙트럼 O*($\omega$)는 정 성적으로 명확한 차이를 보여 공중합체들의 광학완화 거동이 명확히 다름을 나타냈다. 기계 적 특성보다는 광학적 특성이 공중합체내의 성분 고분자의 미세한 완하 거동에 훨씬 민감한 응답을나타냈다. 이러한 특성적인 공중합체의 O*($\omega$)차이를 공중합체의 조성단일 고분자 PS, PC의 O*($\omega$)의 가성성을 가정하여 모사하였다 모사에서 구한 광학적 부분 기여 파라메 터를 사용하여 공중합체의 상용성을 고찰하였다.

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소일시멘트의 일축압축강도 특성 및 시간의존 거동 (Unconfined Compressive Strength Characteristics and Time Dependent Behavior of Soil-Cement)

  • 김종렬;강희복;강화영;김도형
    • 한국구조물진단유지관리공학회 논문집
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    • 제8권4호
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    • pp.87-96
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    • 2004
  • 소일시멘트는 자연 상태의 흙을 주원료로 시멘트, 혼합수를 배합하여 일반포장용 콘크리트에 준하는 강도를 발휘하는 특수콘크리트로서 최근 도로포장뿐만 아니라 연악지반 개량 동 여러 분야에 활용되고 있다. 본 연구에서는 화강토 및 붕적토에 고화제를 첨가하여 일축압축강도의 특성 및 시간의존 거동을 규명하고자 하였다 연구 결과 일축압축강도는 시멘트 함량의 증가와 양생기간의 증가에 따라 뚜렷한 강도 증가를 타나내었으며 미 세립분이 많을 수 록 강도가 감소하였으며 X-선 회절 분석 결과 소일시멘트에서 반응생성물인 Vermiculite가 발견되었다 동적반복재하크리프 시험 결과 히스테리시스 곡선으로부터 재료의 동적특성인 복합전단컴플라이언스, 복합전단계수, 위상각을 구하였으며 재료의 동적특성으로부터 크리프 거동의 예측이 가능 하였다

와이어의 연선공정시 스틸 코드에서의 잔류 비틀림 모멘트의 해석 (Analysis for Residual Twisting Moment in a Steel Cord during Twisting Wires)

  • 이규남;이형만;김기태
    • 대한기계학회논문집A
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    • 제24권2호
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    • pp.403-410
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    • 2000
  • The effects of various factors were studied on the process of a steel cord by twisting wires. To remove residual twisting moment after the steel cord process, the twisting angles of residual elasti c twisting and overtwisting were measured and compared with finite element results. The agreement between experimental data and finite element calculations was good for the angles of residual elastic twisting and over-twisting. The stress distributions in a steel cord under complex loading conditions were also obtained by using the finite element analysis.

유한요소법을 이용한 샌드위치형 감쇠 보구조물의 진동해석 (Vibration Analysis of Damped Sandwich Beam Using Finite Element Method)

  • 서영수;정의봉;신준엽
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2005년도 춘계학술대회논문집
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    • pp.978-981
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    • 2005
  • The vibration analysis of damped sandwich beam is conducted using finite element method. The equation of motion presented by Mead and Markus is used to formulate FEM. Also as the thickness of the core in the damped sandwich beam goes to zero, conventional beam theory based on the transformed-section method and the equation of Mead and Markus are compared. According to the change of thickness and loss factor of the core, the forced frequency response of beam is calculated and discussed. And then using the half-power band width method, the damping ratio of each mode is calculated and discussed about each case.

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