• Title/Summary/Keyword: Complex Formation

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Abberant Root Morphology in the Permanent First Molars : Case Reports (제1대구치에서 관찰되는 비정형적 치근형태에 대한 증례보고)

  • Lee, Eunkyoung;Kim, Youngjin;Kim, Hyunjung;Nam, Soonhyeun
    • Journal of the korean academy of Pediatric Dentistry
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    • v.42 no.2
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    • pp.172-179
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    • 2015
  • The developmental mechanism of root formation is a complex process. Hereditary and environmental factors may affect the morphology of the developing root. A total of 12 cases was presented with permanent first molars with abberant root morphology. Clinically, these teeth appeared as a normal crown. However, radiographically, the root was slender, twisted and characterized by irregular lengths. In addition, root trunk length was shorter and pulp chamber was obliterated. In these cases, periapical radiolucency and loss of lamina dura were often observed. In 6 cases, an abnormal root of the primary second molars were also present, as well as root malformation of permanent first molars. In 3 cases, permanent central incisors also had a dysmorphic crown. These cases almost all had medical history, such as premature birth, brain infection or congenital heart disease in infants. The present paper describes cases of permanent first molars with an abnormal root that are rarely reported in literature. This case may intensify the variation in the permanent first molar and is intended to reinforce the clinician's awareness of rare morphology of the roots.

Electronic Structure of Iron and Molybdenum in $Li_2FeMoO_4Cl$ and Its Crystal Symmetry ($Li_2FeMoO_4Cl$의 결정구조와 Fe 및 Mo의 전자구조 연구)

  • Choy, Jin-Ho;Park, Nam-Gyu;Chang, Soon-Ho;Park, Hyung-Ho
    • Journal of the Korean Chemical Society
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    • v.39 no.6
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    • pp.446-452
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    • 1995
  • Lithium intercalates, $Li_xFeMoO_4Cl$ ($1{\leq}X{\leq}2$) prepared by electrochemical lithiation of $FeMoO_4Cl$ crystallizes in monoclinic structure for all x values as revealed by x-ray diffraction and galvanostatic discharge experiments. According to the x-ray photoelectron spectroscopic study, Fe(III) is at first reduced to Fe(II) upon lithium intercalation with the x domain of $0{\leq}X{\leq}1$, where the crystal symmetry is changed from tetragonal to monoclinic. On the other hand, Mo(VI) is reduced to lower valent state upon further lithium intercalation ($1{\leq}X{\leq}2$), where no crystal symmetry transformation and reduction of Fe(II) to lower valent state are observed. The Mo 3d spectrum for $Li_2FeMoO_4Cl$ appears as a complex shape, but can be deconvoluted into the three sets of the doublet on the basis of Gaussian function, those which correspond to Mo(VI), Mo(V) and Mo(IV) states, respectively. The mixed valent states of molybdenum after further lithiation may be due to a competitive reaction between the formation of Mo(V) and its disproportionation to Mo(IV) and Mo(VI).

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A Comparison Study on Kyedan of Korea Buddhist Temple and Kyedandokyung (한국(韓國) 불교사원(佛敎寺院)의 계단(戒壇)과 계단도경(戒壇圖經)의 비교(比較) 연구(硏究))

  • Park, Eon-Kon;Lee, Jae-In;Choi, Hyo-Sik
    • Journal of architectural history
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    • v.16 no.2
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    • pp.99-118
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    • 2007
  • Kyedan(戒壇) is an altar to perform a rite of Buddhist Initiation which gives Precept to a Buddhist monk. Sometimes it is called the Place of Precept and Mandala by Sanskrit. In this study, the Sutra of the Tang(唐) Dosun(道宣) regarding First Kyedan of Jetavana-anathapindasyarama(祇園精舍), which was the first temple such as, Kyedandokyung(戒壇圖經), Kiwonsadokyung(祇洹寺圖經), Sabunyul(四分律) were analyzed to find out original form and layout. Ultimately, the study was intended to examine the spatial formation-principle by comparing with Kyedan Temple. The results of this study could be summarized as below. First. Except for Kyedan in Bakryensa, the height of lower stone plate of Buddhist Bell-Shaped Stupa of Korean Kyedan is higher than three storied Kyedan that described in Kyedandokyung. Second. Buddhist Bell-Shaped Stupa above Kyedan was presumed that embodied image of Bell Pedestal and symbolism of overturned-bowl were combined together, when Kyedandokyung and Kiwonsadokyung were referred. It could be examined by the existence of stone lantern. Third. In Korea, the rite of Buddhist initiation that gives Precept in Kyedan has been considered impossible. However, when the rite was conducted, there was a possibility to establish wood stair. It is because that the Buddhist Stupa of Silleuuksa(神勒寺) and Woljeongsa(月精寺), which reflected the image of Kyedan had stone stair. Fourth, The method to build Kyedan of Dosun divided into Large Region and Small Region was applied to the method to construct Stone terrace behind Jeongmyeolbogung(寂滅寶宮) like Tongdosa(通度寺) and complete Kyedan on the stone terrace. In other words, Jeongmyeolbogung became Kyedanwon(戒壇院) and Kyedan, itself became Small Region. The area of Stone terrace became Large Region and naturally, they constituted an Institution. Fifth, Korean Kyedan which is consist of Jeongmyeonlbogung and Kyedan is a Korean original composition principles of Kyedangaram(戒壇伽藍) that can satiate all the functions of Kyedan as a religious subject and the place of the rite of Buddhist initiation, as it had complex of Outdoor Kyedan, which was suggested by the sutra of Dosun and Institution of Kyedan.

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A Newer Short Synthesis of dl-Muscone(Ⅰ) (새로운 짧은 경로로의 dl-Muscone 합성(Ⅰ))

  • Im, D.S.;Shin, D.H.;Park, D.K.
    • Journal of the Korean Chemical Society
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    • v.40 no.4
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    • pp.243-248
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    • 1996
  • New routes have been developed for the practical syntheses of dl-Muscone(1) employing cyclopentadecanone(2) as the starting material. In this experiment, addition of bromine to cyclopentadecanone in dried E. Ether solution with a trace of $AlCl_3$ as the catalyst were produced 2-bromocyclopentadecanone(3). This process was enhanced formation of regioselective enolate anion at $C_2$ position. 2-Bromocyclopentadecanone was put into $Li_2CO_3$-LiBr-DMF solution at 140∼150$^{\circ}C$, were produced trans- and cis-2-cyclopentadecen-1-one(4) mixture. Other by-products were reduced by control of reaction temperature and time. Trans- and cis-2-cyclopentadecen-1-one(4) mixture was directly put into dried E. Ether solvent and induce to react dropwise with $CH_3MgBr-Cu_2Cl_2$ complex, all of them got into 1,4-addition, dl-Muscone (1) was formed as the result. Conculsion, through three steps procedure from cyclopentadecanone(2) to dl-Muscone(1), the pure dl-Muscone was obtained with the high proportion of 85%, and synthetic cost was able to be much lower than any other conventional methods as there were no chemical separating steps.

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Emulsion Graft Polymerization of MMA to Sodium Alginate : Mechanism and Solvent Effect (알긴산 소다에의 MMA유화 그래프트 중합 : 메커니즘 및 용매효과)

  • Park, Hwan-Man
    • Journal of Adhesion and Interface
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    • v.2 no.4
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    • pp.10-23
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    • 2001
  • In order to increase the lower values of % grafting and monomer conversion in the emulsion graft polymerization of methylmethacrylate(MMA) onto sodium alginate (SA; a polymer electrolyte) with alginic acid-g-PMMA, the graft polymerization with water soluble (methanol and acetone) and insoluble solvents was carried out using a varity of solvent amounts and agitating rates. And some physical properties of the graft polymer were also investigated. In the polymerizations with water insoluble solvent, there were pronounced improvements in both % grafting and MMA conversion by the promotion of MMA diffusion from the core to the SA adsorpted on the outer layer of particle and that of MMA complex formation with SA. And the effect was larger for the solvents (cyclohexane, decalin) which do not dissolve PMMA. On the other hand, in the polymerization with water soluble solvent, there was an significant increase in MMA conversion and a considerable increase in the % grafting by the destruction of electrical double layer around the SA chains, abstracting the hydrated water in the layer and the effect was more potential in the case of methanol which is a precipitant of PMMA.

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A VE Incentive System for Construction Industry (건설VE 인센티브 제안)

  • Song, Yong-Chul;Song, Nak-Hyun;Lee, Chan-Sik
    • Proceedings of the Korean Institute Of Construction Engineering and Management
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    • 2007.11a
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    • pp.1019-1022
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    • 2007
  • Recent construction projects are becoming larger, more complex and higher rising. Accordingly, necessity of the VE is emphasized as more suitable for expense, function and quality. However, the VE is not functional because of difficulty of application process or of the methods in use in the field of construction. One of the alternative is to introduce the incentive system to activate the VE in the field of construction. By using the incentive system, employers can reduce the relevant project's prime cost and builders will maximize profit creation. In domestic case, they presented the systematic support policy 'Technical development compensation system' which is similar to the 1992 American's VE incentive system about builder's technical development effort but the result was not positive. This study investigates both domestic and other country's construction VE incentive system and reported problems in the construction VE incentive system to executives and construction VE experts. From this survey, conclusions were drawn about problems in the domestic construction VE incentive system's similarity system: 'Insufficiency of the construction VE incentive's article and standards', 'Insufficiency of the appraiser of the construction VE and of the full charge department' etc. I had interviews with the experts of the construction VE which were based on the above-mentioned problems and then presented 'Improvement of the construction VE's incentive system relevant law and system', 'Construction VE experts and construction formation' etc. for ways to bring acceptance of the construction VE in the construction industry.

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Analysis of Pipe Failure Period Using Pipe Elbow Erosion Model by Computational Fluid Dynamics (CFD) (전산유체역학 배관 곡면 침식 모사를 통한 배관 실패 주기 분석)

  • Nam, Chongyong;Lee, Yongkyu;Park, Gunhee;Lee, Gunhak;Lee, Won Bo
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.133-138
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    • 2018
  • Safety management has become even more important because of the safety and environmental issues that have arisen since the 2000s. However, the safety study requires many empirical data, so there are many limitations. In the case of pipe safety, simulation programs exist, but it is difficult to get data about the pipe internal erosion of the pipe. In this study, the erosion rate of the pipe elbow was simulated using computational fluid dynamics (CFD). Also, the failure period of the pipe was calculated by the limit state function using erosion rate. In the case of CFD pipe, a sample which is actually operated in Yeosu industrial complex was used, and the geometry and mesh formation were rationalized in terms of typical fluid dynamics simulations. Using the Discrete Phase Model (DPM) and the corrosion model, the erosion rate ($3.09227mm{\cdot}yr^{-1}$) was obtained from CFD simulations. As a result of applying the erosion rate to the limit state function, we obtained the pipe failure period value, 14.2 years to trigger a leak and 28.2 years to trigger a burst. Through these processes, we concluded that pipe erosion is one of the major failure modes. In addition to the results, this study has significance for suggesting the methodology of the pipe safety study.

Characteristics of Shear Strength and Consolidation Behavior of Soft Ground according to Stage Fill (단계성토에 따른 연약지반의 전단강도 및 압밀거동 특성)

  • Bang, Seongtaek
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.7
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    • pp.17-26
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    • 2020
  • The soft ground in the southwest coastal area composed of marine clay is greatly influenced by sediment composition, particle size distribution, particle shape, adsorption ions and pore water characteristics, tide and temperature. In addition, the geotechnical properties are very complex due to stress history, change in pore water, dissolution process and gas formation. In this study, the physical and mechanical properties of the soft ground were evaluated through field tests and laboratory tests to investigate the strength increase characteristics according to consolidation on the soft ground in the southwest coast. In addition, in order to understand the consolidation behavior of soft ground such as subsidence, pore water pressure, horizontal displacement of soil by embankment load, measuring instruments such as pore water pressuremeter, settlement gauge, inclinometer and differential settlement gauge was installed, and a piezocon penetration test was carried out step by step to confirm the increase in shear strength of the ground. Through this, it was confirmed that the shear strength of the ground is increased according to the stages of filling. In addition, by evaluating the properties of consolidation behavior, strength increase and consolidation prediction by empirical methods and theories were compared to analyze the characteristics of strength increase rate and consolidation behavior in consideration of regional characteristics.

Antioxidant Activity and Identification of Lunasin Peptide as an Anticancer Peptide on Growing Period and Parts in Pepper (생육시기 및 부위별 고추의 항산화력 및 항암 Lunasin peptide의 동정)

  • Kwon Ki Soo;Park Jae Ho;Kim Dae Seop;Jeong Jin Boo;Sim Young Eun;Kim Mi Suk;Lee Hee Kyung;Chung Gyu Young;Jeong Hyung Jin
    • Journal of Life Science
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    • v.15 no.4 s.71
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    • pp.528-535
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    • 2005
  • The non-enzymatic anti-oxidants and lunasin peptide from the extracts of the pepper were examined in order to utilize the discovery in natural products as cancer chemopreventive agents. The DPPH (1,1-diphenyl-2-picryl-hydrazyl) free radical scavenging activity on the fruit parts of the pepper was higher than that of the seed, but the difference was low. The Inhibition activity of xanthine/ xanthine oxidase in extracts of the seed was higher than that of the fruit and that of the seed on 20 days after flowering was the highest at the growing period. These were identified as fatty acids and phenolic compounds such as 1-eicosanol, palmitic acid, linoleic acid, linolenic acid and benzonitrile. The contents of fatty acids and phenolic compounds increased according to the time passing at the growing period. Peroxidase (POD) activity of the fruit at middle stage was high than that of other growing stages and that of the seed was the highest at later growing period. Though superoxide dismutase (SOD) activities in fruit were hish by passage of Slowing stage, the activity in seed was low. Lunasin was searched from seeds of the peppers by coomassie blue staining and western blot among them and we just found lunasin peptide from extracted protein of the pepper by western blot. In addition, we observed the contents of lunasin after flowering and confirmed to appear the lunasin at 35 days after flowering. We confirmed that lunasin is complex protein of maturing seeds. 100nM lunasin peptide in pepper showed inhibition effect on colony formation in $2\~12$ cells.

Ultrastructural Study on Development of the Superior Cervical Ganglion of Human Fetuses (인태아 상경신경절 발육에 관한 전자현미경적 연구)

  • Kim, Dae-Young;Kim, Baik-Yoon;Yoon, Jae-Rhyong
    • Applied Microscopy
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    • v.28 no.2
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    • pp.139-158
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    • 1998
  • The development of the superior cervical ganglion was studied by electron microscopic method in human fetuses ranging from 40 mm to 260 mm of crown-rump length (10 to 30 weeks of gestational age). At 40 mm fetus, the superior cervical ganglion was composed of clusters of undifferentiated cell, primitive neuroblast, primitive supporting cell, and unmyelinated fibers. At 70mm fetus, the neuroblasts and their processes were ensheated by the bodies or processes of satellite cells. The cytoplasm of the neuroblast contained rough endoplasmic reticulum, mitochondria, Golgi complex, Nissl bodies and dense-cored vesicles. As the neuroblasts grew and differentiated dense-cored vesicles moved away from perikaryal cytoplasm into developing processes. Synaptic contacts between the cholinergic axon and dendrites of postganglionic neuron and a few axosomatic synapses were first observed at 70 mm fetus. At 90 mm fetus the superior cervical ganglion consisted of neuroblasts, satellite cells, granule-containing cells, and unmyelinated nerve fibers. The ganglion cells increased somewhat in numbers and size by 150 mm fetus. Further differentiation resulted in the formation of young ganglion cells, whose cytoplasm was densely filled with cell organelles. During next prenatal stage up to 260 mm fetus, the cytoplasm of the ganglion cells contained except for large pigment granules, all intracytoplasmic structures which were also found in mature superior cervical ganglion. A great number of synaptic contact zones between the cholinergic preganglionic axon and the dendrites of the postganglionic neuron were observed and a few axosomatic synapses were also observed. Two morphological types of the granule-containing cells in the superior cervical ganglion were first identified at 90 mm fetus. Type I granule-containing cell occurred in solitary, whereas type II tended to appeared in clusters near the blood capillaries. Synaptic contacts were first found on the solitary granule-containing cell at 150 mm fetus. Synaptic contacts between the soma of type I granule-containing cells and preganglionic axon termials were observed. In addition, synaptic junctions between the processes of the granule- containing cells and dendrites of postganglionic neuron were also observed from 150 mm fetus onward. In conclusion, superior cervical ganglion cells and granule-containing cells arise from a common undifferentiated cell precursor of neural crest . The granule-containg cells exhibit a local modulatory feedback system in the superior cervical ganglion and nay serve as interneurons between the preganglionic and postganglionic cells.

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