• 공업화학
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• 제24권5호
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• pp.489-493
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• 2013

기존의 EDLC용 활성탄소 대신 리튬이차전지용 탄소류 음전극(천연흑연, 인조흑연, 하드카본, MCMB)을 이용해 리튬이온 커패시터를 구성하면 리튬의 층간 삽입반응으로 인해 기존의 물질보다 에너지 밀도가 큰 전극소재를 개발할 수 있을 것이다. 이 실험에서는 기존 리튬이차전지 음극용 탄소 물질을 대칭 전극으로 사용하여 코인형 커패시터를 제조하여 성능을 측정하였다. 또한 리튬을 미리 삽입시킨 탄소류 전극을 이용한 커패시터를 제조한 후 성능을 측정한 결과, 축전현상이 일어나는 것을 알 수 있었다. 즉 전해액에서 전하분리에 의한 리튬이온의 이동을 보충할 수 있다면 기존의 리튬이온은 탄소류 전극의 층간으로 확산되어 들어가 기존의 대칭성 탄소류 전극의 경우에 비해 축전 용량이 증가한다. 또한 표면적이 매우 큰 graphene oxide를 사용하여 위와 같이 실험한 결과 용량이 크게 나왔으며 이로부터 슈퍼커패시터 전극용 물질에는 높은 비표면적이 중요한 요소로 작용한다는 것을 알 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제27권9호
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• pp.1418-1422
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• 2006

In this work the construction of a novel poly(vinyl chloride) membrane sensor based on 2,2'-dianiline disulfide (DADS) as a neutral carrier, o-nitrophenyloctyl ether (NPOE) as a plasticizer and sodium tetraphenyl borate (NaTPB) as an anionic site with unique selectivity towards Tm(III) ions is reported. The electrode has a linear dynamic range between $1.0\;{\times}\;10^{-6}$ and $1.0\;{\times}\;10^{-2}$ M, with a nice Nernstian slope of 19.5 ${\pm}$ 0.3 mV per decade and a detection limit of $4.0\;{\times}\;10^{-7}$ M at the pH range of 4.8-8.5. It has a very fast response time (<15 s) in the whole concentration range, and can be used for at least 4 weeks without any considerable divergence in the electrode potentials. The proposed sensor revealed comparatively good selectivity with respect to most common metal ions, and especially lanthanide ions. It was used as an indicator electrode in the potentiometric titration of Tm(III) ions with EDTA and in direct determination of concentration of Tm(III) ions in binary mixtures. It was also applied in determination of fluoride ions in mouth wash preparations.

• 한국전기전자재료학회논문지
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• 제17권3호
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• pp.305-310
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• 2004

We have studied the optimal phase retardation value of a homogeneously aligned liquid crystal (LC) driven by fringe-field when using the LC with positive dielectric anisotropy. In general, the transmittance of a homogeneous aligned LC cell under crossed polarizer is maximum when a twist angle of LC by in-plane rotation is 45$^{\circ}$ with polarizer and the cell retardation becomes λ/2. However, the device using the LC with positive dielectric anisotropy does not follow this since the degree of rotation of the LC is dependent on electrode position and in addition the LCs tilt up along the fringe-field. At the center of common and pixel electrode, the LC is most twisted around a middle position of a cell whereas at the edge position of pixel electrode, the LC is most twisted near bottom surface of a cell. Consequently, the optimal phase retardation of the device becomes much larger than λ/2 and the transmittance can be described using the combination of the in-plane switching and twisted nematic mode.

• 한국전기전자재료학회논문지
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• 제18권9호
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• pp.840-845
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• 2005

A three branches vortical Hall sensor for detecting rotation angle of brushless motor has fabricated. The sensor is constructed three branches of $150{\mu}m$ width and $300{\mu}m$ distance from central electrode to Hall electrode. Each branch has one Hall output and one Hall input. The central electrode acts as common driving input. According to rotation angle change of brushless motor, sensor gives three position signals phase shifted by $120^{\circ}$. The sensitivity of sensor is 200V/A$\cdot$T at magnetic field of 0.1 T and constant driving current of 1mA. It has also showed three sine waves of Hall output voltages with $120^{\circ}$ phase over one motor rotation. The noise can limit sensor's resolution. We have measured sensor's noise characteristics. The detectable minimum magnetic field is $20{\mu}T$ at driving current 1mA, measured frequency 1 kHz and bandwidth$({\Delta}f)$ of 1Hz.

• 분석과학
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• 제24권3호
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• pp.219-224
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• 2011

카본나노튜브 전극과 금 전극을 사용한 Cl(I) 이온의 전압전류 분석법을 비교 연구하였다. 금 전극이 카본나노튜브 전극보다 Cl(I) 이온에 민감하게 반응함을 보였다. 위 조건에서 금 전극의 순환 전압 전류법과 벗김 전압 전류법의 최적 조건을 실험한 결과 $6.5\;{\mu}g/L$ Cl(I) 이온의 검출한계에 도달 하였다. 최적의 조건에서 기존에 상용되는 Cl이온 미터와 먹는 물 속의Cl(I) 이온 농도를 비교한 결과 보다 민감하게 반응하였다.

• Bulletin of the Korean Chemical Society
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• 제34권10호
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• pp.3088-3092
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• 2013

A novel PVC membrane sensor for perindopril based on perindopril-phosphotungstate ion pair complex was prepared. The influence of membrane composition (i.e. percent of PVC, plasticizer, ion-pair complex, and kind of plasticizer), inner solution, pH of test solution and foreign cations on the electrode performance was investigated. The optimized membrane demonstrates Nernstian response ($30.9{\pm}1.0$ mV per decade) for perindopril cations over a wide linear range from $9.0{\times}10^{-7}$ to $1{\times}10^{-2}$ M at $25^{\circ}C$. The potentiometric response is independent of the pH in the range of 4.0-9.5. The proposed sensor has the advantages of easy preparation, fast response time. The selectivity coefficients indicate excellent selectivity for perindopril over many common cations (e.g., $Na^+$, $K^+$, $Mg^{2+}$, $Cu^{2+}$, $Ni^{2+}$, rhamnose, maltose, glycine and benzamide. The practical applications of this electrode was demonstrated by measuring the concentrations of perindopril in pure solutions and pharmaceutical preparations with satisfactory results.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1991년도 추계학술대회 논문집 학회본부
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• pp.67-70
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• 1991

When analyzing field or optimizing the shape of electrode in three dimensional space by using the surface charge method, we need to divide finely the surface of electrode into surface element like triangle or rectangle. In this case, there exist any variables in field analysis or field optimization. In particular, smoothness on the surface of optimized shape is not good. Recently, A paper is published where introducing NURB curve to field analysis and field optimization about two dimensional space model and axial symmetric three dimensional space model results in reduced variables, enhenced accuracy and improved smoothness. NURB curve has some useful properties like continuity, controllability and locality. Therefore in this paper, in order to improve the demerits of the established optimization method for three dimensional space models, the NURB surface that has same properties in common with NURB curve is used to analyze and optimize simple model.

• 전기학회논문지
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• 제60권5호
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• pp.993-998
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• 2011

In this paper we suggest new criteria for the classification of the electrode gap between common and scan electrodes. The electrode gap is categorized as a short, middle, and long gap according to the criteria. Among these structures, we focus on the erase waveform of a mid-gap structure. we report an unstable discharge arising from the erase ramp period in a mid-gap structure. Based on the Vt close curve, we analyze the unstable discharge at various conditions. Our analysis reveals that the unstable discharge is ignited between surface electrodes and caused by un-erased wall charges accumulated on the outer edges of electrodes. By reducing the voltage level of the last sustain pulse, the problem is solved.

• International Journal of Safety
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• 제7권1호
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• pp.21-25
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• 2008

The occurrence of a corona is that electrical discharge due to the heterogeneity that occurs when an electrical field is concentrated in an electrode due to a cusp formed on said electrode. Wire treatment at the end of a 154kV dead end clamp for end users accelerates the occurrence of corona, which in turn leads to power loss and noise. In this study, the characteristics of the corona which occurs between porcelain insulators and support clamps of overhead lines used in l54kV power receiving facilities for end users were investigated. The corona, which cannot be identified by one common method, was measured utilizing a UV image camera. A risk assessment for fire damage and its status was suggested. The stress distribution of the electrical field by length of bare wire was suggested by means of the finite element method (FEMLAB). As a result, it was found to affect a porcelain insulators. These results can be utilized for the enhancement of clamp installation and safety in power facilities.

• Bulletin of the Korean Chemical Society
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• 제24권1호
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• pp.23-26
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• 2003

Titanium acetylacetonate was used in the construction of a PVC-based membrane electrode. This sensor shows very good selectivity for iodide ion over a wide variety of common inorganic and organic anions. It exhibits Nernstian behavior with a slope of 59.1 mV per decade. The working concentration ranges of the sensor are with a detection limit of $3.0\;{\times}\;10^{-6}\;M$. The response time of the sensor is very fast (<8 s), and can be used for at least twelve weeks in the pH range of 4.0-9.2. The best performance was obtained with a membrane composition of 30% PVC, 65% dibutylphthalate, 3% titanium acetylacetonate and 2% hexadecyltrimethylammonium bromide. The proposed sensor was successfully applied as an indicator electrode for titration of iodide with silver ion.