• Title/Summary/Keyword: Combustion reactivity

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An Investigation on the Spray Characteristics of Diesel-DME Blended Fuel with Variation of Ambient Pressure in the Constant Volume Combustion Chamber (정적연소기에서 분위기 압력에 따른 Diesel-DME 혼합연료의 분무 특성에 관한 연구)

  • Yang, Jiwoong;Lee, Sejun;Lim, Ocktaeck
    • Journal of ILASS-Korea
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    • v.17 no.4
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    • pp.178-184
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    • 2012
  • The aim of this study was to compare the spray characteristics of a typical fuel (100% diesel, DME) and diesel-DME blended fuel in a constant volume combustion chamber (CVCC). The typical fuel (100% diesel, DME) and diesel-DME blended fuel spray characteristics were investigated at various ambient pressures (pressurized nitrogen) and fuel injection pressures using a common rail fuel injection system when the fuel mixture ratio was varied. The fuel injection quantity and spray characteristics were measured including spray shape, penetration length, and spray angle. Common types of injectors were used.

Synthesis of the $\textrm{BaTiO}_3$ Powders by the Glycine-Nitrate Process and Sintering Characteristics (Glycine-Nitrate 법에 의한 $\textrm{BaTiO}_3$ 분말합성 및 소결특성)

  • Kim, Gu-Dae;Park, Ji-Ae;Lee, Hong-Rim;Song, Hyu-Seop
    • Korean Journal of Materials Research
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    • v.9 no.1
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    • pp.51-56
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    • 1999
  • The $BaTiO_3$ powders were synthesized by GNP (Glycine-Nitrate process). The powders were prepared using carbonate and alkoxide as starting materials and nitric acid was used as a solvent for starting materials as well as an oxidant for combustion. the effects of aggregates in $BaTiO_3$ powders on green densities, sintering and dielectric characteristics were investigated. When the glycine/cation molar ratio was 1.2, reactivity of self-combustion was most intensive and the degree of aggregates after calcination was low. On sintering at $1400^{\circ}C$, maximum theoretical relative density(94.99%%0 was obtained in case of 1.2 molar ratio of glycine/cation. The dielectric constant of this sintered $BaTiO_3$ was 1919.

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Numerical Study of Combustion Characteristics for Hydrogen Content in Syngas in Opposed-Flow Flame (대향류 화염에서의 합성가스 내 수소 함량에 따른 연소 특성 변화에 관한 수치해석 연구)

  • KIM, DONGHEE;PARK, JINJE;HUH, KANG Y.;LEE, YOUNGJAE
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.5
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    • pp.467-479
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    • 2020
  • Various researches are being conducted to reduce greenhouse gases generated by the consumption of traditional energy resources. This study was conducted to numerically analyze the combustion characteristics and N-S reaction behavior with respect to the H2 content of syngas composed of CO and H2 in pressurized air combustion. A non-premixed opposed flow flame model was applied a modified detailed mechanism with S-chemistry was developed based on GRI 3.0 to simulate the syngas reaction. As the hydrogen content increased, the flame thickness increased due to the fast reactivity of hydrogen. In the rich region, NO and SO2 were reduced by reaction with H radical and H bonding of NO was suppressed by the formation of HOSO.

A Computational Study on DME HCCI Combustions Characteristics with Methanol Concentrations (DME HCCI 운전조건에서 Methanol 분율에 따른 HCCI엔진연소 특성에 관한 수치해석적 연구)

  • Lee, Hyowon;Lim, Ocktaeck;Park, Kyuyeol;Cho, Wonjun;Baek, Youngsoon
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.1
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    • pp.79-86
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    • 2014
  • In Dimethyl Ether (DME) indirect production processes, DME have a reforming process to separate Methanol. DME has a high cetane number and Methanol has a high octane number. Each fuel has a different combustion characteristics and reactivity. So, this paper was investigated on the combustion characterisitics of DME and Methanol. Basically, Methanol has a effect of retarding ignition. However, Within 10% of total carbon mole number in DME, Methanol slightly changed the onset timing of Low Temperature Reaction (LTR) with increasing thermal-ignition preparation range. It means that controlling combustion phasing of DME can be possible without eliminated LTR. In case of IMEP, the ranges.

Solid Circulation and Reaction Characteristics of Mass Produced Particle in a 0.5 MWth Chemical Looping Combustion System (0.5 MWth 급 케미컬루핑 연소시스템에서 대량생산 입자의 고체순환 특성 및 반응 특성)

  • RYU, HO-JUNG;JO, SUNG-HO;LEE, SEUNG-YONG;LEE, DOYEON;NAM, HYUNGSEOK;HWANG, BYUNG WOOK;KIM, HANA;KIM, JUNGHWAN;BAEK, JEOM-IN
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.2
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    • pp.170-177
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    • 2019
  • Continuous solid circulation test at high temperature and high pressure conditions and batch type reduction-oxidation tests were performed to check feasibility of a 0.5 MWth chemical looping combustion system. Pressure drop profiles were maintained stable during continuous solid circulation up to 16 hours. Therefore, we could conclude that the solid circulation between an air reactor and a fuel reactor could be smooth and stable. The measured fuel conversion and $CO_2$ selectivity were high enough even at high capacity and even after cyclic tests. Therefore, we could expect high reactivity of oxygen carrier at real operation condition.

Effects of Temperature, Pressure, Gas Velocity, and Capacity on Reduction Characteristics of Mass Produced Particle in a 0.5 MWth Chemical Looping Combustion System (0.5 MWth 급 케미컬루핑 연소시스템에서 대량생산 산소전달입자의 환원반응 특성에 미치는 온도, 압력, 유속 및 용량의 영향)

  • RYU, HO-JUNG;LEE, DOYEON;NAM, HYUNGSEOK;HWANG, BYUNG WOOK;KIM, HANA;WON, YOOSEOB;BAEK, JEOM-IN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.1
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    • pp.53-62
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    • 2021
  • Batch type reduction-oxidation tests were performed to check effects of temperature, pressure, gas velocity, and capacity on reduction characteristics of mass produced particle in a 0.5 MWth chemical looping combustion system. The fuel conversion and the CO2 selectivity increased as the temperature increased and as the gas velocity decreased. However the CO2 selectivity showed the maximum and decreased as the capacity increased because the CO emission increased. The results show that high temperature, low gas velocity and low inert gas concentration are preferable to ensure high reactivity of oxygen carrier in the fuel reactor.

Anthracite Oxygen Combustion Simulation in 0.1MWth Circulating Fluidized Bed (0.1 MWth 급 순환유동층에서의 무연탄 연소 전산유체역학 모사)

  • Go, Eun Sol;Kook, Jin Woo;Seo, Kwang Won;Seo, Su Been;Kim, Hyung Woo;Kang, Seo Yeong;Lee, See Hoon
    • Korean Chemical Engineering Research
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    • v.59 no.3
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    • pp.417-428
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    • 2021
  • The combustion characteristics of anthracite, which follow a complex process with low reactivity, must be considered through the dynamic behavior of circulating fluidized bed (CFB) boilers. In this study, computational fluid dynamics (CFD) simulation was performed to analyze the combustion characteristics of anthracite in a pilot scale 0.1 MWth Oxy-fuel circulating fluidized bed (Oxy-CFB) boiler. The 0.1MWth Oxy-CFB boiler is composed of combustor (0.15 m l.D., 10 m High), cyclone, return leg, and so on. To perform CFD analysis, a 3D simulation model reactor was designed and used. The anthracite used in the experiment has an average particle size of 1,070 ㎛ and a density of 2,326 kg/m3. The flow pattern of gas-solids inside the reactor according to the change of combustion environment from air combustion to oxygen combustion was investigated. At this time, it was found that the temperature distribution in air combustion and oxygen combustion showed a similar pattern, but the pressure distribution was lower in oxygen combustion. addition, since it has a higher CO2 concentration in oxygen combustion than in air combustion, it can be expected that carbon dioxide capture will take place actively. As a result, it was confirmed that this study can contribute to the optimized design and operation of a circulating fluidized bed reactor using anthracite.

A Parametric Study on the Catalytic Combustion of Gaseous Methane, Ethane and Propane Fuels (메탄, 에탄 및 프로판 가스 연료의 촉매연소에 관한 매개변수 연구)

  • Jung, Min-Seung;Kim, Chong-Min;Kim, Man-Young
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.4
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    • pp.309-315
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    • 2012
  • Catalytic combustion is generally accepted as one of the environmentally preferred alternatives for heat and power from fossil fuels, as it has the advantage of stable combustion under very lean conditions with such low emissions as UHC, CO, and NOx. In this work, therefore, comparative numerical studies on the catalytic combustion behaviors over Pd-based catalysts have been conducted with the gaseous $CH_4$, $C_2H_6$, and $C_3H_8$. In the following, after introducing the governing equations with 1D channel and Langmuir-Hinshelwood models, numerical investigations on the catalyst performance are conducted by changing such various parameters as inlet temperature, excess air ratio, and space velocity. The numerical results show that outlet temperature and conversion of $C_3H_8$ are highest among others because of its chemical structure and reactivity.

Basic Design and Sensitivity Analysis of 3 MWth Chemical Looping Combustion System for LNG Combustion and Steam Generation (LNG 연소 및 스팀생산을 위한 3 MWth 급 매체순환연소 시스템의 기본설계 및 민감도 분석)

  • RYU, HO-JUNG;NAM, HYUNGSEOK;HWANG, BYUNG WOOK;KIM, HANA;WON, YOOSEOB;KIM, DAEWOOK;KIM, DONG-WON;LEE, GYU-HWA;BAEK, JEOM-IN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.5
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    • pp.374-387
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    • 2021
  • Basic design of 3 MWth chemical looping combustion system for LNG combustion and steam generation was conducted based on the mass and energy balance and the previous reactivity test results of oxygen carrier particles. Process configuration including fast fluidized bed (air reactor), loop seal and bubbling fluidized bed (fuel reactor) was confirmed and their dimensions were determined by mass balance. Then, the external fluidized bed heat exchanger (FBHE) was adopted based on the energy balance to extract heat from the system. The optimum reactor design and operating condition was confirmed with sensitivity analysis by modifying system configuration based on the mass and energy balance.

Properties of Cement Mortar According to Mixing of Circulating Fluidized Bed Fly Ash and Pulverized Coal Fly Ash based on Blast Furnace Slag (고로슬래그 기반 순환유동층 플라이애시 및 미분탄 플라이애시 혼입에 따른 시멘트 모르타르의 특성)

  • Cho, Seong-Woo;Na, Hyeong-Won;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.21 no.2
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    • pp.141-148
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    • 2021
  • In this study, the characteristics of the cement mortar replaced with fly ash and ground granulated blast furnace slag generated during circulating fluidized bed combustion method and pulverized coal combustion process were investigated. As a result of the study, when mixed with circulating fluidized bed combustor fly ash and pulverized coal combustion fly ash, it is advantageous not only in terms of strength development but also in terms of durability. The circulating fluidized bed combustor fly ash contributes to the improvement of initial reactivity, and the pulverized coal combustion fly ash is involved in long-term strength development through pozzolanic reaction. Therefore, it can be seen that the mixed use of circulating fluidized bed combustor fly ash and pulverized coal combustion fly ash acts as a complementary factor for cement mortar substituted with ground granulated blast furnace slag.