• Title/Summary/Keyword: Combustion Toxicity

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A Study on Combustion Characteristics of Fire Retardant Treated Pinus Densiflora and Pinus Koraiensis (난연처리된 소나무와 잣나무의 연소특성 연구)

  • Choi, Jung-Min
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.3
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    • pp.244-251
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    • 2011
  • The combustion characteristics were evaluated for Japanese Red Pine (Pinus Densiflora) and Korean Pine (Pinus Koraensis). These two species are widely used as building member of Korea-style house and volume density of Japanese Red Pine is relatively higher than that of Korean Pine. The combustion characteristics are closely connected with volume density. The differences of two species in both total heat release (THR) and average heat release rate (HRR) seemed to be resulted from the volume density. Toxicity of smoke from the specimens was increased because of fire-retardant treatment.

Comparative In Vitro Biological Toxicity of Four Kinds of Air Pollution Particles

  • Shin, Han-Jae;Cho, Hyun Gi;Park, Chang Kyun;Park, Ki Hong;Lim, Heung Bin
    • Toxicological Research
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    • v.33 no.4
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    • pp.305-313
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    • 2017
  • Accumulating epidemiological evidence indicates that exposure to fine air pollution particles (APPs) is associated with a variety of adverse health effects. However, the exact physiochemical properties and biological toxicities of fine APPs are still not well characterized. We collected four types of fine particle (FP) (diesel exhaust particles [DEPs], natural organic combustion [NOC] ash, synthetic organic combustion [SOC] ash, and yellow sand dust [YSD]) and investigated their physicochemical properties and in vitro biological toxicity. DEPs were almost entirely composed of ultrafine particles (UFPs), while the NOC, SOC, and YSD particles were a mixture of UFPs and FPs. The main elements in the DEPs, NOC ash, SOC ash, and YSD were black carbon, silicon, black carbon, and silicon, respectively. DEPs exhibited dose-dependent mutagenicity even at a low dose in Salmonella typhimurium TA 98 and 100 strains in an Ames test for genotoxicity. However, NOC, SOC, and YSD particles did not show any mutagenicity at high doses. The neutral red uptake assay to test cell viability revealed that DEPs showed dose-dependent potent cytotoxicity even at a low concentration. The toxicity of DEPs was relatively higher than that of NOC, SOC, and YSD particles. Therefore, these results indicate that among the four FPs, DEPs showed the highest in vitro biological toxicity. Additional comprehensive research studies such as chemical analysis and in vivo acute and chronic inhalation toxicity tests are necessary to determine and clarify the effects of this air contaminant on human health.

A Research for Assessment Fire Toxic Gas of Construction Material Using FT-IR and FED (FT-IR과 FED를 이용한 건축 재료의 연소독성평가에 관한 연구)

  • Kim, Sung-Soo;Cho, Nam-Wook;Rie, Dong-Ho
    • Fire Science and Engineering
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    • v.25 no.6
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    • pp.27-31
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    • 2011
  • In this study, combustion toxicity evaluation for building interior materials and study for toxicity as using FT-IR analysis. this experiment for the calculation of toxicity index, it using a cone calorimeter model in KS F ISO/TR 9122-4 as a fire model. It is following ISO 19702 procedure for assessing fire toxic gas using FT-IR. This experiment used calculation method for toxicity index (FED) among the international standards. $LC_{50}$ is a concentration that it can cause death to 50 % of experimental animal in 30 minutes - exposure gas test. comparison with the three kinds of toxicity fire gas of construction materials using toxicity index.

A Study on the Toxicity Analysis of Combustion Gases of Architectural Surface Materials and Architectural Adhesives (건축용 외장재와 접착제 연소가스의 독성분석에 관한 연구)

  • Kim, Won-Jong;Park, Young-Ju;Lee, Hae-Pyeong;Lim, Suk-Hwan;Kim, Jung-In
    • Journal of the Korean Society of Safety
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    • v.28 no.4
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    • pp.48-52
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    • 2013
  • This study was carried out, using toxicity test apparatus, to analyze toxic gases of heat insulation material and adhesives of composite panels used for the architectural surface material when a fire occurs. The findings of this study show that CO, $CO_2$, HCOH, $CH_2CHCN$ and $NO_x$ were detected from styrofoam, reinforced styrofoam, polyurethane foam and glass fiber, but in the case of the polyurethane foam, HCl and HCN were detected as well. All the architectural adhesives released CO, $CO_2$ and $NO_x$, but HCHO was only detected from the adhesives for styrofoam, wood, tile, windows and doors; $CH_2CHCN$ was only from those for wood and stone; $C_6H_5OH$ was only from those for wood. The toxicity index was also measured for architectural surface material and adhesives. Polyurethane foam showed the highest index, 11.7, and glass fiber was followed as 6.8. Reinforced styrofoam showed 5.7 and styrofoam revealed the least 4.9. In the case of architectural adhesives, the highest ranking was those for stone 7.4, windows and doors 6.1, wood 5.3, tile 3.8, and styrofoam 3.7 were followed, respectively.

COMBUSTION TOXICITY ANALYSIS: ADVANCES USING A SPECIALIZED SAMPLING TECHNIQUE FOR FOURIER TRANSFORM INFRARED (FTIR) ANALYSIS

  • Talandis, Jonas;Innes, J.D.;Cox, A.W.
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.178-184
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    • 1997
  • The cone calorimeter as defined by ISO 5660, ASTM 1354, and NFPA 264A is used to assess the reaction to fire of almost any material that must be evaluated in the fire science field. Typical combustion gas analyses include oxygen, CO and CO2. Oxygen consumption is used to determine rate of heat release. Analysis of combustion gases other than oxygen, CO and CO2 has been attempted using filters to remove the solid smoke particles before analysis. This method has generated unreliable results due to the adsorption of many gas components on the active carbon . particles deposited on the filters. A technique using fourier Transform Infrared (FTIB) analysis without filtration will be disclosed and a discussion will be presented of the analytical results of toxic gases produced from various flame retarded polymeric materials. Use of such data in lethal toxic potency determinations is also reviewed.

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A Toxicity Evaluation for the Toxic Gases of Building Finish Materials (건축물 마감재료 연소가스에 의한 독성평가)

  • Cho, Nam-Wook;Cho, Dong-Ho;Oh, Eun-Ha
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.129-140
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    • 2012
  • Smoke toxicity is the test for the toxicity evaluation of smoke and hazardous gas, caused by combustion of building materials and finishing materials. Smoke toxicity can be evaluated by the mean incapacitation time of mice. This test result can be influenced by the health status of mice and test condition. In acute inhalation toxicity test of hazardous gas, no typical clinical findings and histopathologic abnormalities were observed. Tracheitis and bronchitis as well as acute lung inflammation around terminal bronchiole in some mouse of the highest dose group. Through this study, we established the method for inhalation toxicity test of hazardous gas as well as the SOP of inhalation toxicity test. However, in the future studies, the concentration control methods for inhalation technologies on hazardous gas will be needed to improve continuously and also further studies on other gas inhalation toxicity will be needed to conduct.

Evaluation of the Burning Properties of Various Carpet Samples by using the Cone Calorimeter and Gas Toxicity Test (콘칼로리미터와 가스유해성 시험법을 이용한 카페트류의 연소특성 평가)

  • Lee, Bong-Woo;Kwon, Seong-Pil;Lee, Jang-Won;Lee, Byoung-Ho;Kim, Hee-Soo;Kim, Hyun-Joong
    • Fire Science and Engineering
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    • v.23 no.6
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    • pp.1-9
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    • 2009
  • In this study, the burning behaviours of five different kinds of carpet samples covered with nylon, PP (polypropylene), PTT (poly(trimethylene terephthalate)), wool fabric and NW (nylon and wool) were evaluated by using the cone calorimeter having a radiant flux of 50kW/$m^2$. And the combustion gas toxicity was evaluated according to KS F 2271 test method. As a result of the cone calorimeter test (KS F ISO 5660-1), nylon carpet samples were ignited most easily. In ignition ability or initial flammability, NW carpet samples showed the highest value. In heat release rate (HRR), fire intensity, PP carpet samples were larger than any other samples. Nylon carpet samples were the highest smoke production rate, while N/W carpet samples the lowest. The following were in mass loss rates: NW > wool > nylon > PP > PTT. CO (carbon monoxide) was one of the most toxic gases released from the combustion. PTT carpet samples gave rise to the highest CO concentration, while NW carpet samples the lowest. In addition, PP carpet samples caused the highest $CO_2$ (carbon dioxide) concentration, while NW carpet samples the lowest. Toxicity of the gas produced from carpet samples was determined by the mouse stop motion, and it resulted in the fact that the combustion gas of PTT carpet samples was more toxic than that of any other samples.

Comparison of combustion gas release for FRP and seat cover materials to the Furnace temperature (연소온도 조건에 따른 FRP 및 시트커버 내장재의 연소가스 발생량 비교)

  • Lee, Duck-Hee;Jung, Woo-Sung;Lee, Cheul-Kyu;Yu, Mun-Chun
    • Proceedings of the KSR Conference
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    • 2007.05a
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    • pp.1527-1532
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    • 2007
  • We have evaluated the toxicity of interior materials for the railway passenger car by checking the release of $CO_2$, CO, NOx, SO2, HCl, HF, HBr, HCN. The NOx is one of the most effective for the determination of Toxic Index R value. It is generally known that the mechanism of thermal NOx generation without the Interior Material nitrogen source. This study started from the idea to check the NOx difference according to the furnace temperature. But from the results, it was revealed that NOx is not so sensitive for the furnace temperature in case of solid burning. Other gases such as HCN, CO were more changeable to the furnace Temp. We reported the test result as for toxicity index r(x).

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A Study on Combustion Characteristics of Finishing Materials in Interior Decoration (실내장식물 인테리어마감재의 연소특성에 관한 연구)

  • Cho, Kwang-Hyun;Lee, Bong-Woo;Yun, Mung-Oh
    • Journal of the Korean Institute of Gas
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    • v.23 no.4
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    • pp.10-18
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    • 2019
  • The Interior finishing materials tried to evaluate the combustion characteristics and the dangerous characteristic of Floor finish and Wall finish. We often use, conducting the experiment ISO 5660-1, Cone Calorimeter method, and ISO-TR-9122 FT-IR. According to the result of Cone calorimeter experiment, the tile carpet FF3 of Floor material had the highest THR $74.6mj/m^2$ because of the highest risk, and the PHRR of FF1 was $726kW/m^2$, which was easy to bum. As a result FT-IR test, The CO, $CO_2$ ratio was 8,146 PPM for roll carpet FF1 than tile carpet FF2, FF3 5,996, 5,171 PPM, which was a carpet with a high toxicity risk. In the case of wall finishes, The MDF plate(WF3) was THR $86.7mj/m^2$ with a high risk, PHRR $384kW/m^2$ was easy to ignite and toxicity index was 5.5. The CO, $CO_2$ ratio was 1,340~8,596 PPM, But the WF4 was the most toxic with 8,596 PPM.