• Journal of Korean Society of Water and Wastewater
• /
• v.22 no.6
• /
• pp.633-640
• /
• 2008

In this research, the $3.6m^3/day$ scale pilot plant consisting preozonation, coagulation, flocculation, and ceramic membrane processes was operated for long term period to evaluate the validity of ceramic membrane filtration process for treating lake water containing high concentration manganese. The higher concentration of dissolved manganese($Mn^{2+}$) was effectively oxidized to the bigger insoluble colloidal manganese ($MnO^2$) by 1~2 mg/L ozone. The colloidal manganese reacted with coagulant (poly aluminium chloride, PAC) and then formed the big floc. Ceramic membrane rejected effectively manganese floc during membrane filtration. Dissolved organic carbon(DOC) removal was dependent upon $Mn^{2+}$ concentration. While average $Mn^{2+}$ concentration was 0.43 and 0.85 mg/L in raw water, DOC removal rate in preozonation was 26.5 and 13.5%, respectively. The decrease rate of membrane permeability was faster without preozonation than with preozonation while membrane fouling decreased with NOM oxidation by ozone. In conclusion, raw water containing high concentration of manganese can be effectively treated in preozonation-coagulation-ceramic membrane filtration system.

• Membrane Journal
• /
• v.15 no.4
• /
• pp.338-348
• /
• 2005

The permeate flux decline on microfiltration capillary membrane operation was investigated with inorganic colloidal solutions. The permeate flux of the alumina solution is two times higher in average than that of the bentonite solution. The flux decline with increase in operation time was less in the alumina solution than in the bentonite solution. The rate of initial flux decline until 10 min was higher on the bentonite solution over the alumina solution. The decline in permeate flux was due to both the cake formation and the pore blocking. The latter effect was higher in the operation of the bentonite solution. In comparing the ratio of each fouling component to the total fouling fur the $1.0\;kg_f/cm^2$ TMP condition, complete blocking was $9.35\%$, standard blocking was about $6.82\%$ and cake filtration was $83.83\%$, respectively. With the increase in cross flow velocity, the permeate flux increased by $6.0\%$ for the alumina solution and by 14.0 for the bentonite solution. With the increase in average pore size fromm $0.24\;{\mu}m\;to\;0.34\;{\mu}m$, the permeate flux increases 1.61 times for the alumina solution and 1.76 times far the bentonite solution.

• Membrane Journal
• /
• v.15 no.1
• /
• pp.52-61
• /
• 2005

Permeate flux decline in a microfiltration was analyzed by measuring the permeability of bentonite colloidal solution through polyethylene capillary membranes. The flux decline with time was due to the growth of cake layer on the membrane surface and to the pore blocking by particles. As the time approaches to steady state, the permeate flux is almost controlled by the cake filtration model. Faster flux decline at high trans-membrane pressure was attributed to the formation of denser packed cake layer and pore blocking. The ratio of permeate flux to the initial permeate flux, J/J₁, decreased with increasing the trans-membrane pressure, from 45% for 0.5 kg/sub f//㎠ to 38% for 2.0 kg/sub f//㎠. In comparing the ratio of each fouling component to the total fouling for the 0.5 kg/sub f//㎠ TMP condition, complete blocking was 23.4%, standard blocking was about 14.6% and cake filtration was 62.0%, respectively. Permeate flux through the membrane increases with cross flow velocity, and the effect of the variation of velocity is more significant at 1.0 kg/sub f//㎠ rather than at 2.0 kg/sub f//㎠ of the operation pressure. Permeate flux for the membrane having the average pore diameter of 0.34 ㎛ was higher than that for the membrane of 0.24 ㎛ pore size, with the higher flux with the low concentration of feed. On the operation using the membrane of 0.34 ㎛ pore, the pore blocking in the low concentration of 200 ppm is negligible relative to the pore blocking in the 1000 ppm feed.

• Membrane Journal
• /
• v.8 no.3
• /
• pp.130-137
• /
• 1998

Membrane fouling characteristics in the membrane-coupled activated sludge system were investigated. The influence of the floc size variation on the filtration resistance was analyzed using resistance-in-series model and mixed liquor was fractionated into three components to verify which component would give rise to a major contribution to the total resistance. The microbial floc size was rapidly reduced during the initial 4~6 hours of operation, and then decreased slightly but steadily, followed by leveling off at the size of 20 $\mu$m. The specific resistance of activated sludge increased with operation time, and measured values of specific resistance were matched well with the values estimated on the basis of the mean particle size in the mixed liquor. The contribution of soluble organics and cells to the total resistance was relativdy small compared with that of the supematant. Colloidal particles in the supematant showed much higher specific resistance than that of microbial floc, and played the most important role in the cake resistance.

• Applied Chemistry for Engineering
• /
• v.34 no.1
• /
• pp.51-56
• /
• 2023

Composite membranes consisting of TiO₂ nanoparticles (NPs) and porous polymers have been widely utilized in photocatalytic water treatment because the composite membranes can allow an easy recovery of NPs after the photocatalytic reaction as well as the reduction of fouling in the membrane. However, the photocatalytic efficiency of the immobilized TiO₂ NPs in the composite membranes has been discussed to a limited degree. In this study, we prepared polyethersulfone (PES)/TiO₂ composite membranes to study the photocatalytic decomposition of organic dyes under light illumination. The decomposition kinetics of dye molecules by the PES/TiO₂ composite membranes and colloidal TiO₂ NPs have been compared to discuss the photocatalytic efficiency of NPs before and after their immobilization on the polymer membrane.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.31 no.3
• /
• pp.137-142
• /
• 2021

In this study, the development of the room temperature curable silica-based coating compositions for anticorrosive and antifouling performance in marine environments was carried out. The marine (plant) structures with many exposed parts are operated in harsh marine environments such as strong ultraviolet rays, extreme temperature differences and salt water corrosion. Organic paints that are easily degraded under these environments and easily eroded by physical stimuli such as waves can not play a role properly. Dense ceramic coatings on marine structures provide careful protections even in saltwater environments due to their high hardness and rust resistance. Therefore, in the case of ceramic coatings, their use and application range in marine structures can be greatly improved due to their functional advantages. In the present study, silica-based coating compositions based on colloidal silica with silane coupling agents, curing salts, and ceramic fillers were developed, and their applications as protective coatings for corrosion protection and fouling prevention in seawater were also studied.

• Membrane Journal
• /
• v.25 no.4
• /
• pp.301-309
• /
• 2015

Importance of pretreatment for seawater desalination is growing rapidly. Proper selection of pretreatment is critical for the successful, long-term operation in the seawater desalination plant such as seawater reverse osmosis (SWRO). The purposes of seawater pretreatment are to remove particulate, colloidal materials, organic, inorganic materials, microorganisms and their by-products present in the seawater, and thus to improve the performance of seawater desalination systems. However, pretreatment is most challenging for designing and operating seawater desalination plants because of fluctuations of water qualities, site specifications and wide ranges of target materials present in the seawater to be treated. In addition, it is also becoming evident increasingly that microscopic algae are a major cause of operational problems, for example, membrane fouling which is long-standing problem in SWRO process. Pretreatment strategies prior to the operation of seawater desalination technologies should be even more complicated by algae blooms and release of their harmful by-products in marine environment. This paper reviews the roles of various pretreatment methods in seawater desalination process. Benefits and drawbacks are described, which should be taken into account in future studies on selecting pretreatment for seawater desalination process.

• Clean Technology
• /
• v.5 no.2
• /
• pp.25-35
• /
• 1999

Behavior of permeate flux decline was examined through the hollow fiber membrane in ultrafiltration system for Si colloidal solution. Flux decline with time was due to the growth of Si cake deposited on the membrane surface and the pore blocking by Si particles for the hollow fiber membrane. At the pseudo steady state of operation, the permeate flux of dead-end flow was 60 % to that of the cross flow. The ratio of permeate flux to the pure water flux, $J/J_w$, decreased with increasing the trans-membrane pressure, from 64.2 % for $0.5kg_f/cm^2$ to 45.7 % for $2.0kg_f/cm^2$. When the feed flow rate was 3 L/min, the pore blocking model was dominant at the initial period of filtration and was followed by the cake filtration model. And with increasing the feed flow rate from 1 L/min to 3 L/min, $R_c$ was $1.79{\times}10^{12}{\sim}2.34{\times}10^{12}m^{-1}$ which was the about 40 % decreased value to that of the 1 L/min while $R_p$ was not changed and was $1.71{\times}10^{12}m^{-1}$ approximately.