• Korean Chemical Engineering Research
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• v.60 no.2
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• pp.260-266
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• 2022

Average aggregate size in particulate suspensions is estimated with scaling theories based on fractal concept and elasticity of colloidal gel. The scaling theories are used to determine structure parameters of the aggregates, i.e., fractal dimension and power-law exponent for aggregate size reduction with shear stress using scaling behavior of elastic modulus and shear yield stress as a function of particle concentration. The structure parameters are utilized to predict aggregate size which varies with shear stress through rheological modeling. Experimentally rheological measurement is conducted for aqueous suspension of zinc oxide particles with average diameter of 110 nm. The predicted aggregate size is about 1135 nm at 1 s^-1 and 739 nm at 1000 s^-1 on the average over the particle concentrations. It has been found that the predicted aggregate size near 0.1 s^-1 agrees with that the measured one by a dynamic light scattering analyzer operated un-sheared.

• Advances in concrete construction
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• v.3 no.3
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• pp.187-202
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• 2015

The present study addresses about the development of sustainable concrete utilizing recycled coarse aggregates manufactured form waste concrete and colloidal Nano-Silica. Experimental investigations are carried out to determine compressive and tensile strength of concrete mixes designed with recycled coarse aggregates and different percentages of Nano-Silica. Moreover, water absorption, density and volume voids of concrete mixes are also examined to ascertain the influence of Nano-Silica on behavior of recycled aggregate concrete. The outcomes of the research depict that properties of concrete mixes are significantly affected with the introduction of recycled coarse aggregates in place of the natural coarse aggregates. However, the study reveals that the depletion of behavior of recycled aggregate concrete could be restored with the incorporation of little amount (3%) of Nano-Silica.

• Journal of the Korea Institute of Building Construction
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• v.15 no.6
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• pp.561-567
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• 2015

The research, in order to enhance the quality of recycled aggregate, was carried out the quality characteristics test of the recycled aggregates by applying the four kinds of surface treatment using a colloidal suspension of approximately 5nm~60nm particle size with the alkalinity of pH 10.2. The quality tests of recycled aggregate have been processed by specific gravity, water absorption, porosity, surface properties, and the compression and tensile tests. The colloidal suspension was coated effectively the surface of the old cement mortars of recycled aggregate with a constant thickness by colloidal suspension is being applied to the recycled aggregate surface under constant pressure of 100kpa and then it was dried in at $60^{\circ}C$. The surface treatment method by the Method C out of 4 kinds of surface treatment improved effectively the quality of the recycled aggregates, whereby it obtained the best compressive strength and tensile strength of the recycled aggregate concrete.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.4A
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• pp.603-609
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• 2008

The recycled aggregates which were produced from the waste concretes have the disadvantages of inferior properties for natural aggregate. Therefore, in order to reuse the recycled aggregate it must be solved to improve the quality of recycled aggregate. In this study, the quality of recycled aggregate was improved by the surface treatment method using the colloidal silica solution. And, in order to examine the possibility of reusing the surface coated recycled aggregate in constructing concrete structures, we studied the mechanical properties and durability of the concrete using the surface coated recycled aggregates and the other concrete.

• Cement Symposium
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• no.31
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• pp.115-120
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• 2004

To improve the mechanical propertiesof concretes containing recycled aggregate, pozzolanic materials such as colloidal silica, water glass, and/or silica fume were used to decrease the porosity of the recycled aggregates. Some pozzolanic materials were ad

• Resources Recycling
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• v.20 no.1
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• pp.46-53
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• 2011

The recycled aggregate produced from the waste concrete have the disadvantages in the quality for the natural aggregate. Therefore, in order to reuse the recycled aggregate widely it is a previous subject to improve the quality of recycled aggregate. We deduced the more effective surface treatment method using the colloidal silica solution for quality improvement of recycled aggregate. This study aimed to verify the influences of the deduced surface treatment method and the reinforcement of steel fiber to the properties of concrete. For this object, we inquired into the results of the strengths and the flexural failure tests for the five kinds of concrete specimens.

• Bulletin of the Korean Chemical Society
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• v.19 no.10
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• pp.1054-1059
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• 1998

Fluorescence and dynamic light scattering measurements were applied to the study of formation and structure of aggregated colloidal particles in modified poly(ethylene-co-methylacrylate) ionomers in aqueous solution. Both 8-anillino-l-naphthalene-sulfonic acid (ANS) and pyrene were used as fluorescence probe to obtain the information on the structure of particle surface and inside, respectively. Three different ionomers used in this study started to aggregate at very dilute concentration, 3-8 x 10-6 g/mL. In this study, we demonstrate that the polyethylene ionomers can form stable nanoparticles. The hydrophobic core made of the polyethylene backbone chains is stabilized by the ionic groups on the particle surface. Such a formed stable nanoparticles have a relatively narrow size distribution with an average radius in the range of 27-48 nm, depending on the kind of ionic groups. Once the stable particles are formed, the particle size distributions were nearly constant. This study shows another way to prepare surfactant-free polyethylene nanoparticles.

• Advances in concrete construction
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• v.8 no.4
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• pp.321-333
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• 2019

The present study targets to access the consequence of utilization of coarse aggregates retrieved from waste concrete as a substitution of coarse fraction of natural aggregates and silica nano-particles as partial substitution of cement using principles of factorial design. Furthermore, procedures of design of experiments are employed to examine the effect of use of recycled aggregates and nano-silica. In this investigation, compressive strength found after at 7, 28, 90 and 365 days, split and flexural tensile strength, ultrasonic pulse velocity and rebound number and are chosen as responses, whereas the percentages of recycled coarse aggregates (RCA%) and nano-silica (NS(%)) are selected as factors. Analysis of Variance has been conducted on the experimental results for the selected responses with consideration the both factors, which indicates that RCA (%) and NS (%) have substantial impact on the various responses. However, the present analysis depicts that interaction between factors has considerable effect on the chosen parameters of concrete. Furthermore, validation experiments are carried to validate these models for compressive and tensile strength for 100% RCA and 1% NS. The results of comparative study indicates that that the error of the estimation determined using the relevant models are found to be small (±5%) in comparison with the analogous experimental results, which authenticates the calculated models.

• Bulletin of the Korean Chemical Society
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• v.32 no.12
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• pp.4171-4175
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• 2011

Bio-functionalized gold nanoparticles (AuNPs), which bio-specifically interact with biotin-(strept)avidin, were investigated in this study. AuNPs were functionalized with a synthetically-provided biotin-linked thiol (BLT), which was synthesized by amidation of the active ester of biotin with 2-mercaptoethylamine. The BLT-attached AuNP was bio-specific for streptavidin, making it potentially useful for biosensor applications. To test the bio-specific interactions, the colors, absorption spectra and TEM images were investigated for proteins such as streptavidin, cytochrome C, myoglobin and hemoglobin. The colors and absorption spectra changed when streptavidin was added to the BLT-attached AuNP solution. However, the color and spectra did not change when the other proteins were added to the same solution. These results show that the AuNPs provided a colloidal solution with excellent stability and highly selective absorption characteristics for streptavidin as a target molecule. Proteins were also screened in order to identify a general strategy for the use of optical biosensing proteins based on AuNPs. In addition, TEM images confirmed that streptavidin led the BLT-attached AuNPs to aggregate or precipitate.

• Korean Journal of Soil Science and Fertilizer
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• v.18 no.3
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• pp.289-296
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• 1985

To clarify the soil characteristics and genesis of the clayey terrace soils distributed in Yeongcheon (inland region) and Yeongil (coastal region), 9 typifying pedons including a recent local deposits were studied. The physico-chemical properties found were summarized as follows; 1. The contents of available water of the terrace soils were ranged from 12.0 to 20.3%. They were increased with increaseing clay content up to 35%, and then decreased at clay content of 35 to 55%, but were maintained about 12 to 13% when the clay content exceeds 55%. 2. The amount of water stable aggregates in the surface soils were ranged from 55.0 to 81.1%, and were low in cultivated upland where water erosion were accelerated while high in the paddy where the double cropping were practiced. The index of aggregate in cultivated upland were higher in the surface soils but the paddy soils were higher in subsoils. 3. The colloidal reactions checked by the differences between pH in $0.01N-Na_2SO_4$ and $H_2O$ indicate exchangeable acidity to exchangeable neutrality, which means a sort of Red-yellow soil forming process had been prevailed during genesis of the terrace soils. 4. Cation exchange capacity of the clayey terrace soils were averaged about 15.8-20.2me/100g of fine earth and 35.6-52.6me/100g of clay. The rates of base saturation were 32.7 to 57.6% and the rates decreased with increasing the elevations of terraces. 5. The activities of free iron oxides were 0.061 to 0.739 and the values decreased with increasing elevation while the crystallinity index of iron oxides positively correlated with elevations the values ranged from 0.067 to 0.537.