• 한국세라믹학회지
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• 제48권6호
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• pp.636-640
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• 2011

Nano-sized cobalt (II) oxide nanoparticles with a high crystallinity were synthesized using thermolysis of a $Co^{2+}$-oleate precursor at 310$^{\circ}C$. The phase and morphology of as-prepared cobalt oxide nanoparticles were characterized using X-ray diffraction, high-resolution transmission electron microscopy, and Brunauer-Emmett-Teller surface area measurements. The cobalt oxide nanoparticles were found to be spherical nanoclusters with an average diameter of approximately 200 nm, consisting of tiny nanocrystals (10-20 nm). Furthermore, the Li electroactivites of the cobalt oxide nanoparticles were investigated using cyclic voltammetry and galvanostatic cycling. The cobalt oxide nanoparticles could deliver high capacities over 420 mA h $g^{-1}$ at a C/5 current rate.

• 한국재료학회지
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• 제30권6호
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• pp.273-278
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• 2020

This research is conducted to analyze the compatibility of used monomers and produce the high functional hydrogel ophthalmic polymer containing silane and nanoparticles. VTMS (vinyltrimethoxysilane), TAVS [Triacetoxy(vinyl)silane] and cobalt oxide nanoparticles are used as additives for the basic combination of SilM (silicone monomer), MMA (methyl methacrylate) and MA (methyl acrylate). Also, the materials are copolymerized with EGDMA (ethylene glycol dimethacrylate) as cross-linking agent, AIBN (thermal polymerization initiator) as the initiator. It is judged that the lenses of all combinations are optically excellent and thus have good compatibility. Measurement of the optical and physical characteristics of the manufactured hydrophilic ophthalmic polymer are different in each case. Especially for TAVS, the addition of cobalt oxide nanoparticles increases the oxygen permeability. These materials are considered to create synergy, so they can be used in functional hydrogel ophthalmic lenses.

• 한국분말재료학회지
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• 제11권1호
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• pp.16-21
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• 2004

The nano-sized Co particles were successfully synthesized by chemical vapor condensation (CVC) process using the precursor of cobalt carbonyl ($Co_2(CO)_8$). The influence of carrier gases on the microstructure and magnetic properties of nanoparticles was investigated by means of XRD, TEM, XPS and VSM. The Co nano-particles with different phases and shapes were synthesized with a change of carrier gas : long string morphologies with coexistence of fcc and hcp structure in Ar carrier gas condition; finer Co core in a mass of cobalt oxide with only fcc structure in He; rod type cobalt oxide phase in Ar＋6vol％$O_2$. The saturation magnetization and coercivity was lower in Co nanoparticles synthesized in He carrier gas, due to their finer size.

• Journal of the Korean Physical Society
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• 제73권12호
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• pp.1867-1872
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• 2018

This study proposes a route for surface modification for p-type cobalt oxide-based gas sensors. We deposit a thin layer of Ni on the Co oxide film by sputtering process and annealed at $350^{\circ}C$ for 15 min in air, which changes a typical sputtered film surface into one interlaced with a high density of hemispherical nanoparticles. Our in-depth materials characterization using transmission electron microscopy discloses that the microstructure evolution is the result of an extensive inter-diffusion of Co and Ni, and that the nanoparticles are nickel oxide dissolving some Co. Sensor performance measurement unfolds that the surface modification results in a significant sensitivity enhancement, nearly 200% increase for toluene (at $250^{\circ}C$) and CO (at $200^{\circ}C$) gases in comparison with the undoped samples.

• Corrosion Science and Technology
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• 제22권2호
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• pp.90-98
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• 2023

In this study, cobalt oxide (Co₃O₄) and cobalt-doped magnetite (CoFe₂O₄) nanoparticles were synthesized by a hydrothermal method. They were then used as corrosion inhibitors for corrosion protection of AA2024-T3 aluminum alloys. These obtained nanoparticles were characterized by x-ray diffraction, field-emission scanning electron microscopy, and Zeta potential measurements. Corrosion inhibition activities of Co₃O₄ and CoFe₂O₄ nanoparticles were determined by performing electrochemical measurements for bare AA2024-T3 aluminum alloys in 0.05 M NaCl + 0.1 M Na₂SO₄ solution containing Co₃O₄ or CoFe₂O₄ nanoparticles. Corrosion protection for AA2024-T3 aluminum alloys by a water-based epoxy with or without the synthesized Co₃O₄ or CoFe₂O₄ nanoparticles was investigated by electrochemical impedance spectroscopy during immersion in 0.1 M NaCl solution. The corrosion protection of epoxy coating deposited on the AA2024-T3 surface was improved by incorporating Co₃O₄ or CoFe₂O₄ nanoparticles in the coating. The corrosion protection performance of the epoxy coating containing CoFe₂O₄ was higher than that of the epoxy coating containing Co₃O₄.

• 한국재료학회지
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• 제20권11호
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• pp.611-616
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• 2010

A cobalt oxide - tin oxide nanocomposite based gas sensor on an $SiO_2$ substrate was fabricated. Granular thin film of tin oxide was formed by a rheotaxial growth and thermal oxidation method using dc magnetron sputtering of Sn. Nano particles of cobalt oxide were spin-coated on the tin oxide. The cobalt oxide nanoparticles were synthesized by polymer-assisted deposition method, which is a simple cost-effective versatile synthesis method for various metal oxides. The thickness of the film can be controlled over a wide range of thicknesses. The composite structures thus formed were characterized in terms of morphology and gas sensing properties for reduction gas of $H_2$. The composites showed a highest response of 240% at $250^{\circ}C$ upon exposure to 4% $H_2$. This response is higher than those observed in pure $SnO_2$ (90%) and $Co_3O_4$ (70%) thin films. The improved response with the composite structure may be related to the additional formation of electrically active defects at the interfaces. The composite sensor shows a very fast response and good reproducibility.

• 한국전기전자재료학회논문지
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• 제31권5호
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• pp.335-340
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• 2018

Transition metal oxide materials have attracted widespread attention as Li-ion battery electrode materials owing to their high theoretical capacity and good Li storage capability, in addition to various nanostructured materials. Here, we fabricated a CoO Li-ion battery in which Co nanoparticles (NPs) are deposited into a current collector through electrophoretic deposition (EPD) without binding and conductive agents, enabling us to focus on the intrinsic electrochemical properties of CoO during the conversion reaction. Through optimized Co NP synthesis and electrophoretic deposition (EPD), CoO Li-ion battery with 630 mAh/g was fabricated with high cycle stability, which can potentially be used as a test platform for a fundamental understanding of conversion reaction.

• Bulletin of the Korean Chemical Society
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• 제35권8호
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• pp.2367-2370
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• 2014

"Cat's eye"-shaped $[^{57}Co]CoO@SiO_2$ core-shell nanostructure was prepared by the reverse microemulsion method combined with radioisotope technique to investigate a potential imaging agent for a single photon emission computed tomography (SPECT) in nuclear medicine. The core cobalt oxide nanorods were obtained by thermal decomposition of $Co-(oleate)_2$ precursor from radio isotope Co-57 containing cobalt chloride and sodium oleate. The $SiO_2$ coating on the surface of the core cobalt oxide nanorods was produced by hydrolysis and a condensation reaction of tetraethylorthosilicate (TEOS) in the water phase of the reverse microemulsion system. In vivo test, micro SPECT image was acquired with nude mice after 30 min of intravenous injection of $[^{57}Co]CoO@SiO_2$ core-shell nanostructure.

• Bulletin of the Korean Chemical Society
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• 제24권1호
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• pp.32-36
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• 2003

Co nanoparticles were prepared by the reverse micelle technique (NaBH₄reduction of cobalt chloride in a reversed micelle solution of didodecyldimethylammoniumbromide (DDAB)/toluene). The size and the shape of Co nanoparticles could be easily controlled by changing the water contents and micelle concentrations, and the solubility of Co nanoparticles was systematically tuned by choosing appropriate surface capping organic ligand molecules. Furthermore, a novel nanofabrication process was clearly demonstrated, which generated oxide over-coated Co nanorods from Co nanoparticles in organic solution by slow oxidation with an external magnetic field.

• Bulletin of the Korean Chemical Society
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• 제31권10호
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• pp.2830-2834
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• 2010

The degradation efficiencies of phenol in aqueous solution were studied by semi-continuous experiments in the processes of ozone alone, ozone/bulky $Co_3O_4$ and ozone/$Co_3O_4$ nanoparticles. Catalyst samples (bulky $Co_3O_4$ and $Co_3O_4$ nanoparticles) were characterized by X-ray diffraction and transmission electron microscopy. The Brunauer-Emmett-Teller surface area, $pH_{pzc}$ and the density of surface hydroxyl groups of the two catalyst samples were also measured. The catalytic activity of $Co_3O_4$ nanoparticles was investigated for the removal of phenol in aqueous solutions under different reaction temperatures. Tert-butyl alcohol had little effect on the catalytic ozonation processes. Based on these results, the possible catalytic ozonation mechanism of phenol by $Co_3O_4$ nanoparticles was proposed as a reaction process between ozone molecules and pollutants.