• Resources Recycling
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• v.26 no.5
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• pp.61-66
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• 2017

Vanadium Dioxide has been investigated for use as a "spectrally-selective" window coating to block infrared transmission and reduce the loss of building interior heat through windows. The preparation of thermochromic $VO_2$ powder by the reductive reaction with hydrogen was studied. The reductive reaction method has many advantages of easy and mass production of $VO_2$ powder according to controlled reaction without semi-conductor equipments like sputter and beam evaporator. The reaction temperature, time, concentration of reductive gas, post-annealing condition and W addition as dopant would affect the characterization of $VO_2$ powder and its thermochromism. Many applications for electrical device and energy-saving technologies is expected.

• Journal of Industrial and Engineering Chemistry
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• v.68
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• pp.187-195
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• 2018

$Sr_{0.92}Y_{0.08}Ti_{1-x}Ni_xO_{3-{\delta}}$ (SYTN) was investigated in the presence of $H_2S$ containing fuels to assess the feasibility of employing oxide materials as alternative anodes. Aliovalent substitution of $Ni^{2+}$ into $Ti^{4+}$ increased the ionic conductivity of perovskite, leading to improved electrochemical performance of the SYTN anode. The maximum power densities were 32.4 and $45.3mW/cm^2$ in $H_2$ at $900^{\circ}C$ for the SYT anode and the SYTN anode, respectively. However, the maximum power densities in 300 ppm of $H_2S$ decreased by 7% and by 46% in the SYT and the SYTN anodes, respectively. To enhance the sulfur tolerance and to improve the electrochemical properties, the surface of SYTN anode was modified with samarium doped ceria (SDC) using the sol-gel coating method. For the SDC-modified SYTN anode, the cell performance was mostly recovered in the pure $H_2$ condition after 500-ppm $H_2S$ exposure in contrast to the irreversible cell performance degradation exhibited in the unmodified SYTN anode.

• Journal of Industrial and Engineering Chemistry
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• v.68
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• pp.274-281
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• 2018

Experimental studies of the hydrodynamic performance of the draft tube conical spout-fluid bed (DCSF) were conducted using pharmaceutical pellets. The experiments were carried out in a DCSF consisted of two sections: (a) a conical section with the cross section of $120mm{\times}250mm$ and the height of 270 mm, (b) a cylindrical section with the diameter of 250 mm and the height of 600 mm. The flow characteristics of solids were investigated with a high speed camera and a pezoresistive absolute pressure transducer simultaneously. These characteristics revealed different flow regimes in the DCSF: packed bed at low gas velocities, fluidized bed in draft tube at higher gas velocities until minimum spouting, and spouted bed. The stable spouting was identified by the presence of two dominant frequencies of the power spectrum density of pressure fluctuation signature: (i) the frequency band 6-9 Hz and (ii) the frequency band 12-15 Hz. The pressure drops across the draft tube as well as the annulus measured in order to better recognize the flow structure in the DCSF. It was observed that the pressure drop across the draft tube, the pressure drop across the annulus, and the minimum spouting velocity increase with the increase in the height of draft tube and distance of the entrainment zone, but with the decrease in the distributor hole pitch. Finally, this study provided novel insight into the hydrodynamic of DCSF, particularly minimum spouting and stable spouting in the DCSF which contains valuable information for process design and scale-up of spouted bed equipment.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.28 no.3
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• pp.95-102
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• 2016

A boiling heat transfer is used in various industry such as power generation systems, heat exchangers, air-conditioning and refrigerations. In the boiling heat transfer system, the critical heat flux (CHF) is the important factor, and it indicated safety of the system. It has kept up studies on the CHF enhancement. Recently, it is reported the CHF enhancement, when working fluid used the nanofluid with high thermal properties. But it could be occurred nanoflouling phenomenon from nanoparticle deposition, when nanofluid applied the heat transfer system. And, it is reported that the safety and thermal efficiency of heat transfer system could decrease. Therefore, it is compared and analyzed to the CHF and the boiling heat transfer coefficient on effect of artificial nanofouling (coating) in oxidized multi-wall carbon nanotube nanofluids. As the result, the CHF of oxidized multi-wall carbon nanofluids and the CHF of artificial nanofouling in the nanofluids increased to maximum 99.2%, 120.88%, respectively. A boiling heat transfer coefficient in nanofluid increased to maximum 24.29% higher than purewater, but artificial nanofouling decreased to maximum -7.96%.

• Journal of the Korean institute of surface engineering
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• v.54 no.6
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• pp.365-370
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• 2021

In this research, we proceeded with research on plasma resistance of the cleaning process of APS(Atmospheric Plasma Spray)-Y₂O₃ coated parts used for semiconductor and display plasma process equipment. CF₄, O₂, and Ar mixed gas were used for the plasma environment, and respective alconox, surfactant, and piranha solution was used for the cleaning process. After APS-Y₂O₃ was exposed to CF₄ plasma, the surface changed from Y₂O₃ to YF₃ and a large amount of carbon was deposited. For this reason, the plasma corrosion resistance was lowered and contamination particles were generated. We performed a cleaning process to remove the defect-inducing surface YF₃ layer and carbon layer. Among three cleaning solutions, the piranha cleaning process had the highest detergency and the alconox cleaning process had the lowest detergency. Such results could be confirmed through the etching amount, morphology, composition, and accumulated contamination particle analysis results. Piranha cleaning process showed the highest detergency, but due to the very large thickness reduction, the base metal was exposed and a large number of contaminated particles were generated. In contrast, the surfactant cleaning process exhibit excellent properties in terms of surface detergency, etching amount, and accumulated contamination particle analysis.

• Food Science of Animal Resources
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• v.39 no.1
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• pp.23-34
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• 2019

Fat reduction in the formulation of cheese emulsion causes problems in its flowability and functional characteristics during spray-dried cheese powder production. In order to eliminate these problems, the potential of using microparticulated whey protein (MWP) in cheese emulsions was examined in this study. Reduced-fat white-brined cheese emulsions (RF) with different dry-matters (DM) (15%, 20%, and 25% excluding emulsifying salt) were produced using various MWP concentrations (0%-20% based on cheese DM of emulsion). Their key characteristics were compared to full-fat cheese emulsion (FF). MWP addition had no influence on prevention of the phase separation observed in the instable group (RF 15). The most notable effect of using MWP was a reduction in apparent viscosity of RF which significantly increased by fat reduction. Moreover, increasing the amount of MWP led to a decrease in the values of consistency index and an increase in the values of flow behavior index. On the other hand, using high amounts of MWP made the emulsion more liquid-like compared to full-fat counterpart. MWP utilization also resulted in similar lightness and yellowness parameters in RF as their full-fat counterparts. MWP in RF increased glossiness and flowability scores, while decreased mouth coating scores in sensory analyses. Fat reduction caused a more compact network, while a porous structure similar to FF was observed with MWP addition to RF. In conclusion, MWP showed a good potential for formulation of reduced-fat cheese emulsions with rheological and sensorial characteristics suitable to be used as the feeding liquid in the spray drying process.

• Journal of Electrochemical Science and Technology
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• v.10 no.3
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• pp.335-343
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• 2019

In this study, $Sr_2Ni_{1.8}Mo_{0.2}O_{6-{\delta}}$ (SNM) with a double perovskite structure was investigated as an alternative anode for use in the $CH_4$ fuel in solid oxide fuel cells. SNM demonstrates a double perovskite phase over $600^{\circ}C$ and marginal crystallization at higher temperatures. The Ni nanoparticles were exsolved from the SNM anode during the fabrication process. As the SNM anode demonstrates poor electrochemical and electro-catalytic properties in the $H_2$ and $CH_4$ fuels, it was modified by applying a samarium-doped ceria (SDC) coating on its surface to improve the cell performance. As a result of this SDC modification, the cell performance improved from $39.4mW/cm^2$ to $117.7mW/cm^2$ in $H_2$ and from $15.9mW/cm^2$ to $66.6mW/cm^2$ in $CH_4$ at $850^{\circ}C$. The mixed ionic and electronic conductive property of the SDC provided electrochemical oxidation sites that are beyond the triple boundary phase sites in the SNM anode. In addition, the carbon deposition on the SDC thin layer was minimized due to the SDC's excellent oxygen ion conductivity.

• Journal of the Korean Society of Safety
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• v.33 no.6
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• pp.15-21
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• 2018

Ships may collide with reefs or other objects during operation, when arriving or departing ports. The hull plate may be damaged due to the contact with other ships. The total number of domestic powered fishing vessels has decreased, but that of FRP fishing vessels has increased by 0.7% and the ratio of FRP fishing vessels to the total fishing vessels increased to 96%. Recently, fishing vessels has been used as fishing boats for income of non-fishermen as well as fishermen. Therefore, safety management for repair and maintenance is necessary. The penetration of moisture and moisture in the composite material such as FRP may deteriorate the mechanical properties and the salt (NaCl) component of the damaged portion may cause a relatively high deterioration in material strength. The gel coat painting is the final stage of repairs ans maintenance of FRP fishing vessels. The thickness criteria in the domestic and foreign gel coat is 0.3~0.762 mm. The joint specimens, which was immersed in seawater for 120 days, were compared with those without seawater immersion. As a result, the tensile strength was 83 ~ 121.8% and the flexural strength was 83 ~ 113% compared with the specimens without seawater immersion. According to the previous study the tensile strength decreased by more than 29% and the flexural strength decreased by more than 50% when the composite material was immersed in seawater for 1,083 hours without coating. As a result, it was found that the gel coat with 0.5 mm thickness is very effective in preventing the strength decrease of the composite material.

• Korean Chemical Engineering Research
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• v.59 no.3
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• pp.410-416
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• 2021

To improve the capacity and stability of natural graphite, the electrochemical performances were investigated by using the prepared natural graphite coated with petroleum pitch for anode materials. The pitch coated natural graphite was prepared using a dry speed mixer by adjusting the rotation speed of the mixer, time, composition of graphite and softening point of the pitch. The physical properties of the anode material were analyzed using SEM, TEM, and PSD. The electrochemical performances were investigated by cycle, C-rate, EIS and CV test. When the pitch coated natural graphite was tested in the condition of 9000 RPM, 10 wt%, 2 h, and softening point of 150 ℃, it showed the highest capacity of 324.5 mAh/g at 0.1 C and a capacity retention rate of 98.9% after 50 cycles. In the test for evaluating rate performance, the capacity retention rate (5 C/0.1 C) was 80.3% and was improved by about 1.7 times over the pristine natural graphite.

• Tribology and Lubricants
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• v.37 no.5
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• pp.189-194
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• 2021

A straightforward, yet effective surface modification method of stainless steel mesh and its interesting anti-wetting characteristics are reported in this study. The stainless steel mesh is electrochemically etched, and the specimen has both micro and nano-scale structures on its surface. This process transforms the two types of mesh specimens known as the regular and dense specimens into hydrophobic specimens without applying any hydrophobic chemical coating process. The fundamental wettability of the modified mesh is analyzed through a dedicatedly designed experiment to investigate the waterproof characteristics, for instance, the penetration threshold. The waterproof characteristics are evaluated in a manner that the modified mesh resists as high as approximately 2.7 times the pressure compared with the bare mesh, i.e., the non-modified mesh. The results show that the penetration threshold depends primarily on the advancing contact angles, and the penetration stop behaviors are affected by the contact angle hysteresis on the surfaces. The findings further confirm that the inexpensive waterproof meshes created using the proposed straightforward electrochemical etching process are effective and can be adapted along with appropriate designs for various practical applications, such as underwater devices, passive valves, and transducers. In general, , additional chemical coatings are applied using hydrophobic materials on the surfaces for the applications that require water-repelling capabilities. Although these chemical coatings can often cause aging, the process proposed in this study is not only cost-effective, but also durable implying that it does not lose its waterproof properties over time.