• 한국축산식품학회지
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• 제39권1호
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• pp.23-34
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• 2019

Fat reduction in the formulation of cheese emulsion causes problems in its flowability and functional characteristics during spray-dried cheese powder production. In order to eliminate these problems, the potential of using microparticulated whey protein (MWP) in cheese emulsions was examined in this study. Reduced-fat white-brined cheese emulsions (RF) with different dry-matters (DM) (15%, 20%, and 25% excluding emulsifying salt) were produced using various MWP concentrations (0%-20% based on cheese DM of emulsion). Their key characteristics were compared to full-fat cheese emulsion (FF). MWP addition had no influence on prevention of the phase separation observed in the instable group (RF 15). The most notable effect of using MWP was a reduction in apparent viscosity of RF which significantly increased by fat reduction. Moreover, increasing the amount of MWP led to a decrease in the values of consistency index and an increase in the values of flow behavior index. On the other hand, using high amounts of MWP made the emulsion more liquid-like compared to full-fat counterpart. MWP utilization also resulted in similar lightness and yellowness parameters in RF as their full-fat counterparts. MWP in RF increased glossiness and flowability scores, while decreased mouth coating scores in sensory analyses. Fat reduction caused a more compact network, while a porous structure similar to FF was observed with MWP addition to RF. In conclusion, MWP showed a good potential for formulation of reduced-fat cheese emulsions with rheological and sensorial characteristics suitable to be used as the feeding liquid in the spray drying process.

• Journal of Electrochemical Science and Technology
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• 제10권3호
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• pp.335-343
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• 2019

In this study, $Sr_2Ni_{1.8}Mo_{0.2}O_{6-{\delta}}$ (SNM) with a double perovskite structure was investigated as an alternative anode for use in the $CH_4$ fuel in solid oxide fuel cells. SNM demonstrates a double perovskite phase over $600^{\circ}C$ and marginal crystallization at higher temperatures. The Ni nanoparticles were exsolved from the SNM anode during the fabrication process. As the SNM anode demonstrates poor electrochemical and electro-catalytic properties in the $H_2$ and $CH_4$ fuels, it was modified by applying a samarium-doped ceria (SDC) coating on its surface to improve the cell performance. As a result of this SDC modification, the cell performance improved from $39.4mW/cm^2$ to $117.7mW/cm^2$ in $H_2$ and from $15.9mW/cm^2$ to $66.6mW/cm^2$ in $CH_4$ at $850^{\circ}C$. The mixed ionic and electronic conductive property of the SDC provided electrochemical oxidation sites that are beyond the triple boundary phase sites in the SNM anode. In addition, the carbon deposition on the SDC thin layer was minimized due to the SDC's excellent oxygen ion conductivity.

• 한국안전학회지
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• 제33권6호
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• pp.15-21
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• 2018

Ships may collide with reefs or other objects during operation, when arriving or departing ports. The hull plate may be damaged due to the contact with other ships. The total number of domestic powered fishing vessels has decreased, but that of FRP fishing vessels has increased by 0.7% and the ratio of FRP fishing vessels to the total fishing vessels increased to 96%. Recently, fishing vessels has been used as fishing boats for income of non-fishermen as well as fishermen. Therefore, safety management for repair and maintenance is necessary. The penetration of moisture and moisture in the composite material such as FRP may deteriorate the mechanical properties and the salt (NaCl) component of the damaged portion may cause a relatively high deterioration in material strength. The gel coat painting is the final stage of repairs ans maintenance of FRP fishing vessels. The thickness criteria in the domestic and foreign gel coat is 0.3~0.762 mm. The joint specimens, which was immersed in seawater for 120 days, were compared with those without seawater immersion. As a result, the tensile strength was 83 ~ 121.8% and the flexural strength was 83 ~ 113% compared with the specimens without seawater immersion. According to the previous study the tensile strength decreased by more than 29% and the flexural strength decreased by more than 50% when the composite material was immersed in seawater for 1,083 hours without coating. As a result, it was found that the gel coat with 0.5 mm thickness is very effective in preventing the strength decrease of the composite material.

• Korean Chemical Engineering Research
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• 제59권3호
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• pp.410-416
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• 2021

본 연구에서는 천연 흑연의 용량과 안정성을 개선하기 위해 석유계 피치로 코팅된 천연 흑연을 제조하여 전기화학적 성능을 평가하였다. 천연흑연과 피치를 건식 스피드 믹서를 이용해 코팅하였으며, 믹서의 회전 속도, 시간, 흑연과 피치의 조성, 피치의 연화점을 변화시키면서 음극 활물질을 제조하였다. 제조된 음극 활물질의 물리적 특성은 SEM, TEM, PSD를 이용해 분석하였으며, 전기화학적 성능은 사이클, 율속, 임피던스, 순환전압 전류 테스트를 통해 조사하였다. 9000 RPM, 10 wt%, 2 h, 연화점 150 ℃ 조건에서 코팅된 천연 흑연을 0.1 C에서 전기화학적 특성을 테스트 하였을 때, 324.5 mAh/g 의 가장 높은 용량과 50 사이클 이후 98.9%의 용량 유지율을 보였다. 고속 충·방전을 위한 테스트에서는 5 C/0.1 C 용량 유지율은 80.3%로 나타났으며, 코팅되지 않은 천연흑연보다 약 1.7 배로 향상된 용량 유지율을 확인할 수 있었다.

• Tribology and Lubricants
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• 제37권5호
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• pp.189-194
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• 2021

A straightforward, yet effective surface modification method of stainless steel mesh and its interesting anti-wetting characteristics are reported in this study. The stainless steel mesh is electrochemically etched, and the specimen has both micro and nano-scale structures on its surface. This process transforms the two types of mesh specimens known as the regular and dense specimens into hydrophobic specimens without applying any hydrophobic chemical coating process. The fundamental wettability of the modified mesh is analyzed through a dedicatedly designed experiment to investigate the waterproof characteristics, for instance, the penetration threshold. The waterproof characteristics are evaluated in a manner that the modified mesh resists as high as approximately 2.7 times the pressure compared with the bare mesh, i.e., the non-modified mesh. The results show that the penetration threshold depends primarily on the advancing contact angles, and the penetration stop behaviors are affected by the contact angle hysteresis on the surfaces. The findings further confirm that the inexpensive waterproof meshes created using the proposed straightforward electrochemical etching process are effective and can be adapted along with appropriate designs for various practical applications, such as underwater devices, passive valves, and transducers. In general, , additional chemical coatings are applied using hydrophobic materials on the surfaces for the applications that require water-repelling capabilities. Although these chemical coatings can often cause aging, the process proposed in this study is not only cost-effective, but also durable implying that it does not lose its waterproof properties over time.

• 한국지반환경공학회 논문집
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• 제20권11호
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• pp.5-10
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• 2019

본 연구에서는 장파장에서 감응하는 광촉매를 개발하기 위하여 상용화된 $TiO_2$에 Ag를 도핑하여 제조하였으며 광촉매 효율을 향상시키기 위하여 귀금속의 분산을 증대시키는 마이크로에멀젼 방법을 이용하였다. 제조된 $Ag/TiO_2$의 물리적 특성은 SEM(Scanning Electron Microscopy), FE-TEM(Field Emission Transmission Electron Microscopy), DRS(Diffuse Reflectance Spectroscopy)를 통해 분석하였다. RO 16(Reactive Orange 16)에 대한 광촉매의 제거 효율은 25ppm의 RO 16을 대상으로 UV-A 영역(365nm)에서 수행하였다. Ag의 도핑방법에 의한 광촉매 효율을 비교하기 위해 볼밀링 및 딥코팅 방법으로 제조하여 광촉매 효율을 분석하였으며 광촉매 효율에 대한 Ag 및 계면활성제 함량에 대한 최적화를 진행하였다. 도핑방법에 따른 RO 16 제거효율 분석 결과, 마이크로에멀젼 방법으로 제조한 $Ag/TiO_2$의 RO 16 제거효율이 가장 높았으며 Ag 함량 2wt%, 계면활성제 0.5g에서 가장 높은 제거효율을 보였다.

• 대한건축학회논문집:구조계
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• 제35권12호
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• pp.149-156
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• 2019

Recently, skyscraper building and apartment fires, which were rapidly spread out from a low floor to a rooftop, have become a frequent occurrence in mass media. This fire problems have a fatal disadvantage that the exterior wall finish of the building emits toxic gas in case of fire by using dry bit method or organic insulating material. Therefore, in order to remedy these problems, many exterior wall finishing construction methods have been proposed, but the current trend is to use existing construction methods due to problems such as economy, weight, and durability. On the other hand, in countries such as Germany and Japan, ceramic sidings are used as exterior finishing material for buildings, which is environmentally friendly, excellent natural beauty, long life, easy maintenance and high-quality exterior materials. However, those ceramic sidings have still the problems such as manufacturing cost and weight problem because of boosting the sintering temperature up to 1,350℃ or more. Also, conventional CRC, MgO, FRP sidings which are composed of pulp, glass fiber and organic materials, have been reports of deformation due to ultraviolet rays, discoloration, corrosion and scattering, surface rupture, lifting and peeling. Therefore, in this study as an alternative to solve this problem, halosite nano kaolin produced in Sancheong in Korea and frit flux were used to satisfy the required properties as ceramic siding using low temperature sintering (below 1,000℃) and lightweight materials such as pearlite. This study aims to design the optimal formulation and process of materials and to study the characteristics of nano-coated ceramic siding material development and to present relevant basic data. The findings show that ceramic siding for nanocoated building materials is excellent as a natural ceramic siding building material. The fire resistance of natural minerals and nano particle refining technology satisfy the bending strength of 80kgf / cm2, the volume ratio of 2.0 and the absorption rate of less than 10.0%.

• 공업화학
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• 제22권2호
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• pp.230-234
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• 2011

반도체산업은 고집적화된 회로를 요구하면서 미세 패턴을 형성하기 위해 계속해서 발전해가고 있다. 이에 반도체 산업에서 미세 패턴을 형성하기 위하여 하드마스크를 도입하여 사용되고 있다. 일반적으로 하드마스크는 화학증기증착법(CVD) 공정을 이용하여 다층구조로 제작된다. 이에 본 연구에서는 스핀공정이 가능하고 단층의 하드마스크용 조성물을 제조하기 위하여 유-무기 하이브리드 중합체를 이용하여 그 특성에 대하여 연구하였다. Silanol로 처리된 siloxane 화합물과 acetonide 그룹을 가지는 propionic acid를 에스터화 반응을 통하여 얻은 유-무기 하이브리드 중합체에 가교제 및 첨가제들의 첨가로 광학적, 열적, 그리고 표면 특성이 조절된 하드마스크 막을 제조하였다. 또한 하드마스크 막과 감광층의 식각비를 비교하여 유-무기 소재의 하이브리드 중합체에 대해 미세패턴을 형성시킬 수 있는 하드마스크 막으로써의 유용성을 확인하였다.

• 한국재료학회지
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• 제31권7호
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• pp.392-396
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• 2021

Expensive PCBN or ceramic cutting tools are used for processing of difficult-to-cut materials such as Ti and Ni alloy materials. These tools have the problem of breaking easily due to their high hardness but low fracture toughness. To solve these problems, cutting tools that form various coating layers are used in low-cost WC-Co hard material tools, and research on various tool materials is being conducted. In this study, binderless-WC, WC-6 wt%Co, WC-6 wt%Co-1 wt% Mo₂C, and WC-6 wt%Co-2.5 wt% Mo₂C hard materials are densified using horizontal ball milled WC-Co, WC-Co-Mo₂C powders, and spark plasma sintering process (SPS process). Each SPSed Binderless-WC, WC-6 wt%Co-1 wt% Mo₂C, and WC-6 wt%Co-2.5 wt% Mo₂C hard materials are almost completely dense, with relative density of up to 99.5 % after the simultaneous application of pressure of 60 MPa and almost no significant change in grain size. The average grain sizes of WC for Binderless-WC, WC-6 wt%Co-1 wt% Mo₂C, and WC-6 wt%Co-2.5 wt% Mo₂C hard materials are about 0.37, 0.6, 0.54, and 0.43 ㎛, respectively. Mechanical properties, microstructure, and phase analysis of SPSed Binderless-WC, WC-6 wt%Co-1 wt% Mo₂C, and WC-6 wt%Co-2.5 wt% Mo₂C hard materials are investigated.

• Composites Research
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• 제33권6호
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• pp.395-400
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• 2020

본 연구에서는 카본나노튜브(CNT) 면상발열체에 preceramic polymer 중 하나인 실세스퀴아잔을 코팅하여 고온에서 안정적인 발열이 가능한 CNT/SiCN 복합체 시트를 제조하였다. 제조된 복합체 필름은 FE-SEM을 통해 실세스퀴아잔이 CNT 면상발열체의 표면을 모두 코팅한 것을 확인하였다. 또한 800℃의 열처리를 통해 실세 스퀴아잔이 SiCN 세라믹으로 전환되어도 표면의 결함이 발견되지 않고 온전한 구조를 유지하는 것을 확인하였다. CNT/SiCN 복합체 시트는 질소와 공기 분위기 모두에서 기존의 CNT 시트보다도 높은 열적 안정성을 확보할 수 있었다. 마지막으로 제조된 CNT/SiCN 복합체 필름은 대기 중에서 700℃ 이상의 온도로 발열이 가능하였고 발열 후 온도를 식히고 재발열 또한 성공적으로 이루어졌다.