• Journal of Environmental Science International
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• v.26 no.11
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• pp.1267-1274
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• 2017

A Controlled Low-Strength Materials (CLSM) is suitable for mine backfilling because it does not require compaction owing to it high fluidity and can be installed quickly. Therefore, a CLSM utilizing $CO_2$-solidified Circulating Fluidzed Bed Combustion (CFBC) coal ash was developed and it's properties were investigated, since. $CO_2$-solidification of CFBC coal ash can inhibit exudation of heavy metals. The chemical composition and specific surface area of Pulverized coal Combustion fly ash and CFBC fly ash were analyzed. The water ratio, compressive strength and length change ratio of CLSM were confirmed. The water ratios differed with the specific surface area of the CLSM. It was confirmed that the porosity of CLSM affected its compressive strength and length change ratio.

• KEPCO Journal on Electric Power and Energy
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• v.3 no.1
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• pp.29-34
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• 2017

Leaching kinetics for extracting yttrium from the coal fly ash was investigated in the presence of sulfuric acid during extraction. The leaching kinetics of yttrium were conducted at reactant densities of 5~1,000 g coal fly ash per L of $1.0{\sim}10.0N\;H_2SO_4$, agitation speed of 250 rpm and temperature ranging from 30 to $90^{\circ}C$. As a result, the leaching kinetic model was determined in a two-step model based on the shrinking core model with spherical particles. The first step was proceeded by chemical reaction at ash surface, and the second step was proceeded by ash layer diffusion because the leaching conversion of yttrium by the first chemical reaction increases with increased the time irrelevant to the temperature whereas it increases with increased the leaching temperature. The activation energy of the first chemical leaching step was determined to be $1.163kJmol^{-1}$. After the first chemical reaction, the activation energy of ash layer diffusion leaching was derived to be $41.540kJmol^{-1}$. The optimum conditions for leaching the yttrium metal of 60 % were found to be the slurry density of 250 g fly ash per L of $H_2SO_4$, solvent concentration of $2.0N\;H_2SO_4$, second step leaching of temperatures of $30^{\circ}C$ for 3 hours and then $90^{\circ}C$ for 3 hours at agitation rate of 250 rpm.

• Geotechnical Engineering
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• v.14 no.1
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• pp.81-92
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• 1998

Coal ash from thermal power plants has been produced in large quantity and discarded uselessly, However, it is possible to supply construction material properly by utilizing the coal ash as construction material. In this study, the applicable model and its applicability for deformation analysis of coal ash fill and reclamation ground are studied. Camflay model gives complete constitutive law which illustrates deformation and pore water pressure while soil is loaded under the various stresses at drained and undrained conditions. The merit of proposed model which is acquired from laboratory tests is that only a few soil parameters are available. The whole parameters of Camflay model are obtained by typical mechanical test and CV triaxial test on the sample with optimum mixing ratio( i.e. fly ash : bottom ash=5:5) Then the results from proposed numerical analysis are compared with laboratory results. The differences between laboratory test and numerical analysis are negligible. Parameters deter mined from laboratory tests are useful as a basic data for deformation analysis of coal ash reclamation ground using Camflay model.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2000.10a
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• pp.458-465
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• 2000

Although Fly ash possess viable engineering properties, an overwhelming majority of the fly ash from coal combustion is still placed in storage or disposal sites. Similarly, sludges generated from various water treatment operations are predominantly subject to the fate of land disposal. To prepare sludges for land disposal typically requires time consuming dewatering schemes, which can become extremely difficult to execute dependent upon the composition of the sludge and its affinity for water. This test was undertaken to reuse of fly ash and sludge with mix. In this paper includes of geotechnical properties of fly ash and fly ash-sludge mixture and results of compaction test, unconfined test, falling head test and CBR test and it was analyzed the effect on mixing fly ash with sludge.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05b
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• pp.373-376
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• 2005

The discharge of fly ash that is produced by coal-fired electric power plants is rapidly increasing in Korea. The utilization of fly ash in the raw materials would contribute to the elimination of an environmental problem and to the development of new high-performance materials. Fly ash consists of a glass phase. As it is produced from high temperature, it is a chemically stable material. Fly ash mostly consists of $SiO_{2}$ and $Al_{2}O_{3}$, and it assumes the form of an oxide in the inside of fly ash. Because this reaction has not broken out by itself, it is need to supply it with additional $OH^{-}$ through alkali activators. We used alkali activators for supplying it with additional $OH^{-}$. This paper concentrated on the strength development according to the kind of chemical activators, the curing temperature, the heat curing time.

• Proceedings of the Korean Geotechical Society Conference
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• 2008.03a
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• pp.1051-1060
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• 2008

The use of the coal ash for surcharge material, in a view of the environmental aspect, can decrease amount of the reclamation through recycling waste materials as well as prevent a destruction of the ecosystem attributed to sand picking. In addition, it can reduce both unit cost of material and construction expenses. In this study, new construction material as alternative surcharge material using coal ash, which is by-product from thermoelectric power plant, were developed. Mixing ratios of fly ash and bottom ash derived from the coal ash in Samchunpo thermoelectric power plants were determined. Furthermore, mixing conditions depending on the ratios of the cement and gypsum used for chemical additive were determined too. Uniaxial compression strength tests were conducted at different mixing conditions and Design graph of optimum mixing ratio at each required strength for economic efficiency is indicated in this paper.

• Advances in concrete construction
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• v.5 no.3
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• pp.289-301
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• 2017

The synergistic interactions of supplementary cementitious materials (SCMs) with ordinary portland cement (OPC) in multi-blended systems could enhance the mechanical and durability properties of concrete and increase the amount of cement that can be replaced. In this study, the characteristics of the hydration products as well as paste microstructure of blended cement containing 20% coal fly ash, 10% rice hull ash and 10% sugar mill lime sludge in quaternary blended system was investigated. Portlandite content, hydration products, compressive strength, pore size distribution and microstructural architecture of hydrated blended cement pastes were examined. The quaternary blended cement paste showed lower compressive strength, reduced amount of Portlandite phases, and higher porosity compared to plain hardened cement paste. The interaction of SCMs with OPC influenced the hydration products, resulting to the formation of ettringite and monocarboaluminate phases. The blended cement paste also showed extensive calcium silicate hydrates and calcium aluminate silicate hydrates but unrefined compared to plain cement paste. In overall, the expected synergistic reaction was significantly hindered due to the low quality of supplementary cementitious materials used. Hence, pre-treatments of SCMs must be considered to enhance their reactivity as good quality SCMs can become limited in the future.

• Journal of Environmental Science International
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• v.20 no.12
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• pp.1607-1615
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• 2011

The adsorption performance of cupper and zinc ions($Cu^{2+}$ and $Zn^{2+}$) in aqueous solution was investigated by an adsorption process on reagent grade Na-A zeolite(Z-WK) and Na-A zeolite (Z-C1) prepared from coal fly ash. Z-C1 was synthesized by a fusion method with coal fly ash from a thermal power plant. Batch adsorption experiment with Z-C1 was employed to study the kinetics and equilibrium parameters such as initial metal ions concentration and adsorption time of the solution on the adsorption process. Adsorption rate of metal ions occurred rapidly and adsorption equilibrium reached at less than 120 minutes. The kinetics data of $Cu^{2+}$ and $Zn^{2+}$ ions were well fitted by a pseudo-second-order kinetics model more than a pseudo-first-order kinetics model. The equilibrium data were well fitted by a Langmuir model and this result showed $Cu^{2+}$ and $Zn^{2+}$ adsorption on Z-C1 would be occupied by a monolayer adsorption. The maximum adsorption capacity($q_{max}$) by the Langmuir model was determined as $Cu^{2+}$ 99.8 mg/g and $Zn^{2+}$ 108.3 mg/g, respectively. It appeared that the synthetic zeolite, Z-C1, has potential application as absorbents in metal ion recovery and mining wastewater.

• Journal of Ocean Engineering and Technology
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• v.14 no.1
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• pp.74-79
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• 2000

The purpose of this paper is to recycle coal ash as structural backfill materials from electric power plants. Two million tons of coal ash are produced annually. The laboratory test was executed for the basic compatibility as substitution for structural backfill materials and the optimal mixture ratio(fly ash : bottom ash) was decided. In addition the model test was performed using medium scale earth pressure model with small size earth pressure cells model box data logger and some other apparatuses. Mixed coal ash and excellent backfill materials(coheisonless soil SW) were compared in the view of lateral earth pressure variation depending on wall displacement. The reduction of earth pressure when coal ash was used as a bockfill material was monitored comparing to that of cohesionless soil. the cost and environmental pollutants by treating coal ash can be reduced through developing the recycling technology.

• Resources Recycling
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• v.10 no.3
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• pp.14-22
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• 2001

For the recycle of coal fly ash generated from power stations, we developed an electrocyclone system which can separate unburned carbon form coal fly ash, based on the fact that coarse fly ash particles contain higher amount of unburned carbon and unburned carbon particles are charged positively, and pure ash particles are charged negatively on contacting each other. Additionally, guide vanes were installed in the cyclone to control the cut size. Two types of electrode, stick and grid type, were designed to investigate the effect of electrode type. Results show that by introducing an electric field inside the cyclone, the yield increases by 5 to 15e1o. But the content of unburned carbon in the clean ash does not change significantly.