• KEPCO Journal on Electric Power and Energy
• /
• v.2 no.3
• /
• pp.437-445
• /
• 2016

This paper discussed the effect of ammonia concentration adsorbed on fly ash for the ammonia emission as AAFA (Ammonia Adsorbed Fly Ash) produced from coal fired plants due to operation of NOx reduction technologies was landfilled with distilled or sea water at closed and open systems, respectively. Ammonia bisulfate and sulfates adsorbed on fly ash is highly water soluble. The pH of ammonium bisulfate and sulfate solution had significant effect on ammonia odor emission. The effect of temperature on ammonia odor emission from mixture was less than pH, the rate of ammonia emission increased with increased temperature when the pH conditions were kept at constant. Since AAFA increases the pH of solution substantially, $NH_3$ in the ash can release the ammonia order unless it is present at low concentration. $NH_4{^+}$ ion is unstable in fly ash and water mixtures of high pH at open system, which is changed to nitrite or nitrate and then released as ammonia gas. The proper conditions for < 20 ppm of ammonia concentration released from the AAFAs landfilled in ash pond were explored using an open system with sea water. It was therefore proposed that optimal operation to collect AAFA of less than 168 ppm ammonia at the electrostatic precipitator were controlled to ammonia slip with less than 5 ppm at SCR/SNCR installations, and, ammonia odor released from mixture of fly ash of 168 ppm ammonia with sea water under open system has about 20 ppm.

• Journal of Energy Engineering
• /
• v.25 no.3
• /
• pp.136-148
• /
• 2016

We analyze economic effects of GHG reduction measures of the generation industry to meet 2030 GHG reduction target using the scenario based approach. We estimate the GHG emission of the Korean power industry in 2030 based on both the $7^{th}$ Electricity Supply & Demand Plan and the GHG emission coefficients issued by IAEA. We set up three scenarios for reduction measures by replacing the coal fired plants with nuclear power, renewable energy and carbon capture and storage. Once and for all, the nuclear power scenario dominates the other energy technologies in terms of GHG reduction quantities and economic effects.

• Plant Journal
• /
• v.15 no.4
• /
• pp.36-42
• /
• 2019

In recent, according to the tightening of environment regulation policy, the height of the site of the power plant is increased and the length of the cooling water pipe is increased. This has a serious impact on the stability of the plant. This study analyzes the transient phenomenon using LIQT 7.2, an unsteady state one-dimensional analysis software, to secure the stability of 1,000 MW high-capacity coal-fired power plant cooling water system with high head. To prevent water hammer, The effects on performance characteristics were predicted by individual and combination application. The surge pressure of the cooling water which occurs when the pump was stopped without installing the anti-surge devices was the largest at the pump outlet side. The most effective and simple way to reduce surge pressure in these cooling water systems is to combine a vacuum breaker with a hydraulic non-return valve, which is an essential device for pump protection.

• KEPCO Journal on Electric Power and Energy
• /
• v.2 no.1
• /
• pp.103-108
• /
• 2016

Carbon Capture and Storage technologies are recognized as key solution to meet greenhouse gas emission standards to avoid climate change. Although MEA (monoethanolamine) is an effective amine solvent in $CO_2$ capture process, the application is limited by high energy consumption, i.e., reduction of 10% of efficiency of coal-fired power plants. Therefore the development of new solvent and improvement of $CO_2$ capture process are positively necessary. In this study, improvement of $CO_2$ capture process was investigated and applied to Test Bed for reducing energy consumption. Previously reported technologies were examined and prospective methods were determined by simulation. Among the prospective methods, four applicable methods were selected for applying to 0.1 MW Test Bed, such as change of packing material in absorption column, installing the Intercooling System to absorption column, installing Rich Amine Heater and remodeling of Amines Heat Exchanger. After the improvement construction of 0.1 MW Test Bed, the effects of each suggested method were evaluated by experimental results.

• Resources Recycling
• /
• v.23 no.6
• /
• pp.3-11
• /
• 2014

Bottom ash from coal fired power plants is not widely used due to a broad range of particle sizes and a high carbon content for producing geopolymers. The effect of mechanical activation on compressive strength of bottom ash- based geopolymers was examined by rod and planetary-ball milling to encourage full-fledged recycling of bottom ash, the main component of pond ash. The amount of amorphous component in the milled ash samples did not change significantly after the mechanical activation. It is presumably because needle-shaped mullite crystals, which is a major crystalline phase and grown in a glassy matrix, possess high strength and toughness, and therefore, they could endure external shocks and remain almost intact. Milling operation, however, decreased the particle size and improved the homogeneity of ash, thereby leading to increase reactivity of milled ash with alkali activators. Rod milling produced a relatively narrow particle size distribution of the milled ash particles; however, it was less effective in reducing the particle size. Nevertheless, it was interesting to observe that rod milling had equal effect on improving the compressive strength of geopolymers up to about 37%, as that of planetary ball milling. Rod milling is believed to be suitable process for enhancing the reactivity of bottom ash for large-scale recycling of bottom ash and producing geopolymers.

• Clean Technology
• /
• v.26 no.3
• /
• pp.177-185
• /
• 2020

All coal ash, generated from coal-fired power plants, is entirely dumped onto a landfill site. As coal ash contains 80% fly ash, a clean floating process was developed in this study to recover useful components from coal ash and to use them as high value-added industrial materials. When the unburned carbon (UC) was recovered from the fly ash, soybean oil, an eco-friendly vegetable oil, was used as collector instead of a non-ionic kerosene collector to prevent the occurrence of odor from the kerosene. After the UC was separated by flotation, particulate ceramic microsphere (CM) was recovered, without generating acidic wastewater, through hydro-cyclone instead of sulfuric acid solution in order to separate ceramic microsphere (CM) and cleaned ash (CA) from the residue. By utilizing soybean oil as a collector, the recovery rate of UC turned high at 85.8% due to the increased adsorption of UC, the high viscosity of soybean oil, and the increase in floating properties caused by the linoleic acid contained in soybean oil. All of the combustible components contained in the recovered UC were carbon components, with the carbon content registering high when soybean oil was used. The recovered UC had many pores with a rough surface; thus, it could be easily ground and then used as an industrial material for its fine particles. The CM and CA recovered by the clean separation process using hydro-cyclone had a spherical shape, and the particles were clearly separated without clumping together. The average diameter (D₅₀) of the particles was 5 ㎛, so it was possible to realize the atomization of CM through a process change.

• Resources Recycling
• /
• v.27 no.3
• /
• pp.39-47
• /
• 2018

According to Vietnam government establishes additional coal-fired power plants to secure generation capacity, emission of ashes is accelerating and processing them is urgent issue. This study targeted utilize fly ashes that occurred in circulating fluidized bed combusion (CFBC) power plant to use ground solidification materials. CFBC fly ashes are used to make solidification with ground granulated blast furnace slag (GGBFS), gypsum and cement. Then produced specimens by mixing with soft ground soil to confirm mixing effect of fly ash in solidification. As a result it was possible to find mixture design that is satisfied 3 MPa compressive strength in age 28 days and reduce weight loss rate over 50% in acid immersion test than plain specimens that using only ordinary portland cement.

• Journal of Energy Engineering
• /
• v.18 no.2
• /
• pp.114-124
• /
• 2009

The Ministry of Knowledge and Economy (MKE) establishes the Basic Plan for Long-Term Electricity Supply and Demand(BPE) biannually, a governmental plan for the stable electricity supply. This study investigated the effects of the electric demand forecast on the energy mix. A simplified simulation model was developed, which replaces the WASP program developed by the KPX and verified by comparing both results. Three different electric demand scenarios were devised based upon the 2005 electric demand forecast: Proper, 5 % higher, and 5% lower. The simplified model calculates the energy mix for each scenario of the year 2005. Then it calculates the energy mix for the proper electric demand forecast of the year 2007 using the energy mixes of the three scenarios as the initial conditions, so that it reveals the effect of electric demand forecast of the previous BPE on the energy mix of the next BPE. As the proper electric demand forecasts of the year 2005 and 2007 are the same, there is no change in the previous and the next BPEs. However when the electric demand forecasts were 5% higher in the previous BPE and proper in the next BPE, some of the planned power plant construction in the previous BPE had to be canceled. Similarly, when the electric demand forecasts were 5% lower in the previous BPE and proper in the next BPE, power plant construction should be urgently increased to meet the increased electric demand. As expected the LNG power plants were affected as their construction periods are shorter than coal fired or nuclear power plants. This study concludes that the electric demand forecast is very important and that it has the risk of long term energy mix.

• Resources Recycling
• /
• v.16 no.2 s.76
• /
• pp.48-55
• /
• 2007

A low-priced catalyst for pyrolysis of LDPE has been synthesized. Fly ash, which is waste material generated from coal-fired power plants was used as silica and alumna sources for solid acid catalyst. Amorphous silica-alumina catalysts (FSAs) were pre-pared by dissolution of silica and alumina from fly ash, followed by co-precipitation of the dissoluted ions. A series of LDPE pyrolysis were carried out in a thermogravimetric analyzer to investigate the effects of synthesis conditions such as NaOH/fly ash weight ratio and activation time one catalytic performance of FSAs. The physical properties of FSAs were examined and related to their catalytic performances. FSA(1.2-8) synthesized with NaOH/fly ash weight ratio of 1.2 and the activation time of 8 hours showed the best catalytic performance. The catalytic performance of FSA(1.2-8) was comparable with that of commercial catalysts and it was concluded that the FSA could be a good candidate for catalytic use in the recycling of waste polyolefins.

• Journal of Energy Engineering
• /
• v.23 no.2
• /
• pp.125-148
• /
• 2014

This paper performs a historical analysis on the various factors contributing to the current carbon lock-in of Korean electricity industry by using techo-institutional complex. The possibilities of the industry's carbon lock-out toward more sustainable development are also investigated. It turns out that market, firm, consumer, and government factors are all responsible for the development of the carbon lock-in of Korean power industry; the Korean government consistently favoring large power plants based on the economy of scale; below-cost electricity tariff; inflation policy to suppress increases in power price; rapid demand growth in summer and winter seasons; rigidities of electricity tariff; and expansion of gas-fired and imported coal-fired large power plants. On the other hand, except for nuclear power generation and smart grid, environment laws and new and renewable energy laws are the other remaining factors contributing to the carbon lock-out. Considering three key points that Korea is an export-oriented economy, the generation mix is the most critical factor to decide the amounts of carbon emission in the power industry, and the share of industry and commercial power consumption is over 85%, it is unlikely that Korea will achieve the carbon lock-out of power industry in the near future. Therefore, there are needs for more integrated approaches from market, firm, consumer, and government all together in order to achieve the carbon lock-out in the electricity industry. Firstly, from the market perspective, it is necessary to persue more active new and renewable energy penetration and to guarantee consumer choices by mitigating the incumbent's monopoly power as in the OECD countries. Secondly, from the firm perspective, the promotion of distributed energy system is urgent, which includes new and renewable resources and demand resources. Thirdly, from the consumer perspective, more green choices in the power tariff and customer awareness on the carbon lock-out are needed. Lastly, the government shall urgently improve power planning frameworks to include the various externalities that were not properly reflected in the past such as environmental and social conflict costs.