• Title/Summary/Keyword: Co-based films

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$CO_2$ Sensing Characteristics of PLD NASICON Thin Films (PLD법에 의해 제작된 NASICON 박막의 $CO_2$ 감지특성)

  • Min, Nam-Ki;Jin, Joon-Hyung;Lee, Sang-Yeol;Hong, Suk-In
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1657-1659
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    • 1999
  • Our $CO_2$ sensor is based on an electrochemical reaction involving NASICON, Ba-Stabilized $Na_2CO_3$, two Pt electrodes, $O_2$, and $CO_2$.. NASICON thin films were deposited by pulsed laser deposition(PLD). The sensitive electrode made of Ba-stabilized sodium carbonate was magnetron sputtered. An emf between two Pt electrodes was proportional to the logarism of the concentration of $CO_2$ in the ambient. This sensor has a sensitivity of 3.82mV/decade and does not show any saturation for $CO_2$ concentration as high as 200,000 ppm.

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SUBMICRON-RESOLUTION DOMAIN REVERSAL STUDY OF Co-BASED MULTILAYERS USING MAGNETO-OPTICAL MICROSCOPE MAGNETOMETER (MOMM)

  • Shin, Sung-Chul;Choe, Sug-Bong
    • Proceedings of the Korean Magnestics Society Conference
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    • 2000.09a
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    • pp.121-146
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    • 2000
  • A novel system of magneto-optical microscope magnetometer (MOMM), capable of simultaneous local problems of magnetic properties as well as real-time magnetic domain evolution imaging of ferromagnetic thin films with 400-nm spatial resolution, New findings in domain reveral dynamics of Co-based multilayers: The reversal ratio of V/R is a governing physical parameter. The activation volumes of wall-motion and nucleation processes are generally unequal. Submicron-scale local coercivity variation determines domain reversal dynamics. A thermally activated relaxation process during domain reversal is existed on the submicron-scale in realistic films. Local variation of magnetic properties should be considered for a realistic simulation. The fantastic capabilities of the MOMM can open many possibilities to broaden and deepen our understanding of domain reversal phenomena in ferromagnetic thin films.

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Effects of Co-doping on Densification of Gd-doped CeO2 Ceramics and Adhesion Characteristics on a Yttrium Stabilized Zirconia Substrate

  • Lee, Ho-Young;Kang, Bo-Kyung;Lee, Ho-Chang;Heo, Young-Woo;Kim, Jeong-Joo;Lee, Joon-Hyung
    • Journal of the Korean Ceramic Society
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    • v.55 no.6
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    • pp.576-580
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    • 2018
  • In this study, a small amount of CoO was added to commercial Gd-doped $CeO_2$ (GDC) powder. The CoO addition greatly enhanced sinterability at low temperatures, i.e., more than 98% of relative density was achieved at $1,000^{\circ}C$. When GDC/8YSZ (8 mol% yttrium stabilized zirconia) bilayers were sintered, Co-doped GDC showed excellent adhesion to the YSZ electrolyte. Transmission electron microscope (TEM) analysis showed that there were no traces of liquid films at the grain boundaries of GDC, whereas liquid films were observed in the Co-doped GDC sample. Because liquid films facilitate particle rearrangement and migration during sintering, mechanical stresses at the interface of a bilayer, which are developed based on different densification rates between the layers, might be reduced. In spite of $Co^{2+}$ doping in GDC, the electrical conductivity was not significantly changed, relative to GDC.

Volatile Organic Compounds(VOCs) Sensing Properties of Thin Films Based on Copper phthalocyanine and Dilithium phthalocyanine Compounds (Copper phthalocyanine과 Dilithium phthalocyanine 화합물 박막의 휘발성 유기화합물(VOCs) 센서 특성)

  • Kim, Dong Hyun;Kang, Young Goo;Kang, Young Jin
    • Journal of the Korean Society of Safety
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    • v.28 no.2
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    • pp.37-41
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    • 2013
  • In this work, we report the effect on the volatole organic compounds(VOCs) sensing properties of Copper phthalocyanine(CoPc) and Dilithium phthalocyanine(DiLiPc) thin films onto alumina substrates. Use evaporation method and the spin-coated method for sensing device. The materials of metallophthalocyanine macrocyclic compound solutions blended with N,N'-diphenyl-N,N'-bis(1-naphthyl)-1,1'-biphenyl-4,4"-diamine and/or Poly[2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylenevinylene] solutions. The influence of the blended in with metallophthalocyanine macrocyclic compounds on the resistance have been measured and analyzed in five different volatole organic compounds. The following results were obtained: The AFM 3D image of thin films deposited on metallophthalocyanine macrocyclic compound shows that the surfaces roughness were about CuPc 4.1~14.3 nm(7.5~8.1%), DiLiPc 10.3~22.2 nm(7.9~11.5%). The resistances decreases upon increasing the concentration of vapor organic compounds to CuPc and DiLiPc thin films. That thin films blended Copper phthalocyanine(CoPc) and Dilithium phthalocyanine(DiLiPc) with N,N'-diphenyl-N,N'-bis(1-naphthyl)-1,1'-biphenyl-4,4"-diamine and/or Poly[2-methoxy--5-(2'-ethylhexyloxy)-1,4-phenylenevinylene]. The resistances of blended thin films with N,N'-diphenyl-N,N'-bis(1-naphthyl)-1,1'-biphenyl-4,4"-diamine and/or Poly[2-methoxy--5-(2'-ethylhexyloxy)-1,4-phenylenevinylene] decreases upon increasing the concentration of volatole organic compounds(VOCs) on DiLiPc than CuPc compound thin films.

Initial Magnetization and Coercivity Mechanism in Amorphous TbxCo1-x Thin Films with Perpendicular Anisotropy

  • Kim, Tae-Wan;Lee, Ha-Na;Lee, Hyun-Yong;Lee, Kyoung-Il
    • Journal of Magnetics
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    • v.15 no.4
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    • pp.169-172
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    • 2010
  • The coercivity mechanism in permanent magnets was analyzed according to the effects of domain nucleation and domain wall pinning. The coercivity mechanism of a TbCo thin film with high perpendicular magnetic anisotropy was considered in terms of the local inhomogeneity in the thin film. The initial magnetization curves of the TbCo thin films demonstrated domain wall pinning to be the main contributor to the coercivity mechanism than domain nucleation. Based on the coercivity model proposed by Kronmuller et al., the inhomogeneity size acting as a domain wall pinning site was determined. Using the measured values of perpendicular anisotropy constant ($K_u$), saturation magnetization ($M_s$), and coercivity ($H_c$), the inhomogeneity size estimated in a TbCo thin film with high coercivity was approximately 9 nm.

IN SITU STRESS MEASUREMENTS OF Co-BASED MULTILAYER FILMS

  • Kim, Young-Suk;Shin, Sung-Chul
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.470-473
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    • 1995
  • We have constructed an apparatus for in sity measurement of stress of the film prepared by sputtering using an optical noncontact displacement detector. A Change of the gap distance between the detector and the substrate, caused by stress of a deposited film, was detected by a corresponding change of the reflectivity. The sensitivity of the displacement detector was $5.9\;{\mu}V/{\AA}$ and thus, it was turned out to be good enough to detect stress caused by deposition of a monoatomic layer. The apparatus was applied to in situ stress measurements of Co/X(X=Pd or Pt) multilayer thin films prepared on the glass substrates by dc magnetron sputtering. At the very beginning of the deposition, both Co and X sublayers have subjected to their own intrinsic stresses. However, when the film was thicker than about $100{\AA}$, constant tensile stress in the Co sublayer and compressive stress in the X sublayer were observed, which is believed to be related to a lattice mismatch between the matching planes of Co and X.

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Preparation and Characterization of PBAT/OTPS Blend Films with Epoxidized Soybean Oil (ESO) for Eco-friendly Packaging Application

  • Jina Song;Sangwoo Kwon;Su-il Park
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.29 no.1
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    • pp.9-14
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    • 2023
  • The application of starch-based films is limited by the poor water vapor barrier and mechanical properties. In this study, plasticized octenyl-succinated corn starch (OTPS) was mixed into Poly (butylene adipate-co-terephthalate) (PBAT) with various concentration (0/0.25/0.5/0.75 wt%) of epoxidized soybean oil (ESO) to enhance the mechanical properties and the hydrophobicity of blends. Tensile Strength and elongation at break of PBAT/OTPS film was slightly strengthened as the added ratio of ESO raised to 0.5 wt%, yet lessened again in 0.75 wt% sample. The yield strength and elastic modulus were highest in 0.25wt% of ESO added. In thermal properties, the melting temperature (Tm) and crystallization temperature (Tc) were highest at ESO 0.25 and the maximum degradation temperature (Tmax) of components of the films were developed as ESO added. Also, it has been proved that the addition of hydrophobic substances reduces the hydrophilicity of the film by contact angle. This suggests the use of epoxidized oil for preparing films based on high TPS content allows obtaining enhanced interfacial adhesion. This study confirmed that ESO acts as a compatibilizer between OTPS and PBAT to improve the mechanical properties and hydrophobicity of the sample. The sample containing 0.5wt% of ESO was the most suitable for packaging application.

Wetting Properties of Biopolyester Films Prepared by Thermo-Compression Method

  • Rhim, Jong-Whan;Hong, Seok-In
    • Food Science and Biotechnology
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    • v.16 no.2
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    • pp.234-237
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    • 2007
  • Water resistance of three biopolyester films, such as poly-L-lactate (PLA), poly-hydroxybutyrate-co-valerate (PHBV), and Ecoflex, and low density polyethylene (LDPE) film was investigated by measuring contact angle of various probe liquids on the films. The properties measured were initial contact angle of water, dynamic change of the water contact angle with time, and the critical surface energy of the films. Water contact angle of the biopolyester films ($57.62-68.76^{\circ}$) was lower than that of LDPE film ($85.19^{\circ}$) indicating biopolyester films are less hydrophobic. The result of dynamic change of water contact angle also showed that the biopolyester films are less water resistant than LDPE film, but much more water resistant than cellulose-based packaging materials. Apparent critical surface energy for the biopolyester films (35.15-38.55 mN/m) was higher than that of LDPE film (28.59 mN/m) indicating LDPE film is more hydrophobic.

Chitin Nanofibers Characterization for Flexible/Transparent Films (유연/투명 필름을 위한 키틴 나노파이버 특성)

  • Hwang, Joong-Kook;Seo, Eung-soo;Chang, Sang-Mok;Shin, Hoon-Kyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.12
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    • pp.797-801
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    • 2015
  • In this study ensuring a filming technology is attempted through dispersion technologies and mixing polymer scaffolds in order to produce films based on the nanowaires obtained from chitin. In addition this study proposes technologies in measuring and improving characteristics of films produced using nanowires and for applying electric conductivity to the films as a chemical and physical manner. Also, a possibility in applications of mass productive films or substrates to producing flexible and transparent films is proposed. In the experiment implemented in this study, it is verified that developments of high strength, high transparency, and high flexibility films can be developed through combining it with producing flexible and transparent films.