• Title/Summary/Keyword: Co-agent

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Deposition behavior of cyanide-free electroless Au plating solution using thiomalic acid as complexing agent and aminoethanethiol as reducing agent and characteristics of plated Au film (티오말산을 착화제로 하고 아미노에탄티올을 환원제로 하는 비시안계 무전해 Au 도금액의 석출 거동 및 도금 특성)

  • Han, Jaeho;Kim, DongHyun
    • Journal of the Korean institute of surface engineering
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    • v.55 no.2
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    • pp.102-119
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    • 2022
  • Gold plating is used as a coating of connecter in printed circuit boards, ceramic integrated circuit packages, semiconductor devices and so on, because the film has excellent electric conductivity, solderability and chemical properties such as durability to acid and other chemicals. As increasing the demand for miniaturization of printed circuit boards and downsizing of electronic devices, several types of electroless gold plating solutions have been developed. Most of these conventional gold plating solutions contain cyanide compounds as a complexing agent. The gold film obtained from such baths usually satisfies the requirements for electronic parts mentioned above. However, cyanide bath is highly toxic and it always has some possibility to cause serious problems in working environment or other administrative aspects. The object of this investigation was to develop a cyanide-free electroless gold plating process that assures the high stability of the solution and gives the excellent solderability of the deposited film. The investigation reported herein is intended to establish plating bath composition and plating conditions for electroless gold plating, with thiomalic acid as a complexing agent. At the same time, we have investigated the solution stability against nickel ion and pull strength of solder ball. Furthermore, by examining the characteristics of the plated Au plating film, the problems of the newly developed electroless Au plating solution were improved and the applicability to various industrial fields was examined. New type electroless gold-plating bath which containing thiomalic acid as a complexing agent showing so good solution stability and film properties as cyanide bath. And this bath shows the excellent stability even if the dissolved nickel ion was added from under coated nickel film, which can be used at the neutral pH range.

Engineering characteristics of reinforced solidified roadbed (친환경 도로조성을 위한 보강형 고화도로노반의 공학적 특성)

  • Koh, Yong-Kook
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.906-909
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    • 2005
  • The purpose of this paper is to study on the construction of roadbed with environmental friendly soil amendment agent and reinforced fiber. The special amendment agent and fiber used in this study has a function of soil-cement-agent solidification and reinforcement. A series of laboratory experiments including unconfined compressive strength, tensile strength, compaction test were carried out to investigate the physical and mechanical characteristics of roadbed treated by solidifying agent and fiber. The results of this research showed that the roadbed using poor soil could be efficiently constructed by treatment of this amendment agent and fiber.

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A Multi-Agent Negotiation System with Negotiation Models Changeable According to the Bargaining Environment

  • Ha, Sung-Ho;Kim, Dong-Sup
    • Journal of Information Technology Applications and Management
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    • v.16 no.1
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    • pp.1-20
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    • 2009
  • Negotiation is a process of reaching an agreement on the terms of a transaction. such as price, quantity, for two or more parties. Negotiation tries to maximize the benefits for all parties concerned. instead of using human-based negotiation. the e-commerce environment provides such an environment as adopting automated negotiation. Thus. choosing agent technology is appropriate for an automatic electronic negotiation platform. since autonomous software agents strive for the best deal on behalf of the human participants. Negotiation agents need a clear-cut definition of negotiation models or strategies. In reality, most bargaining systems embody nearly one negotiation model. In this article. we present a mobile agent negotiation system with reusable negotiation strategies that allows agents to dynamically embody a user's favorite negotiation strategy which can be preinstalled as a component in the system. We develop a prototype system, which is fully implemented in compliance with FIPA specifications, and then. describe the benefits of using the system.

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Gene Expression Analysis of Anticancer Drug Induced Hepatotoxicity Using cDNA Microarray

  • Lee, Gyoung-Jae;Kim, Yang-Suk;Jung, Jin-Wook;Hwang, Seung-Yong;Park, Joon-Suk;Kang, Kyung-Sun;Lee, Yong-Soon;Chon, Man-Suk;Chon, Kum-Jin;Kang, Jong-Soo;Kim, Dong-Hyean;Park, Young-Keun
    • Molecular & Cellular Toxicology
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    • v.2 no.2
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    • pp.141-149
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    • 2006
  • Tamoxifen (TAM), a non-steroidal anti estrogen anticancer drug and chemopreventive agent for breast cancer, have caused cholestasis in liver. The potent hepatocarcinogenicity of this drug has been reported. Methotrexate (MTX) is dihydrofolate reductase inhibitor which interfaces with the synthesis for urine nucleotide and dTMP. And it may cause atrophy, necrosis and steatosis in liver. These two anticancer drug have well-known hepatotoxicity. So, in this study we compare the gene expression pattern of antitumor agent TAM and MTX, using the cDNA microarray. We have used 4.8 K cDNA microarray to identify hepatotoxicity-related genes in 5-week-old male Sprague-Dawley (SD) rats. Confirm the pattern of gene expression, we have used Real time PCR for targeted gene. In the case of MTX, Protease related gene (Ctse, Ctsk) and Protein kinase (Pctk 1) have shown specific expression pattern. And in the case of TAM, apoptosis related gene (Pdcd 8) and signal transduction related gene (kdr) have significantly up regulated during treatment time. Gene related with growth factor, lipid synthesis, chemokins were significantly changed. From the result of this study, the information about influence of TAM and MTX to hepatoxicity will provide.

Synthesis and Biological Activity of Indazole-Derived HMG-CoA Reductase Inhibitors

  • Kim, Jin-Il;Jahng, Yurng-Dong
    • Archives of Pharmacal Research
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    • v.18 no.3
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    • pp.206-212
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    • 1995
  • New hypolipaemic agents, in which substituted indazole nucleus is connected to tetrahydro-4-hydroxy-2H-pyran-2-one by a two-carbon bridge, were designed and synthesized to show significant inhibitory activity against microsomal HMG-CoA reductase in rat liver.

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Reductive Leaching of $LiCoO_2$in a Sulfuric Acid Solution (황산용액서 $LiCoO_2$의 환원침출)

  • 이철경;김낙형
    • Resources Recycling
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    • v.10 no.6
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    • pp.9-14
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    • 2001
  • A sulfuric acid leaching of $LiCoO_2$as cathodic active materials of lithium ion secondary batteries was investigated in terms of reaction variables. In the absence of a reducing agent, the extraction of cobalt was less than 40% in 2 M sulfuric acid at $75^{\circ}C$ instead of that of lithium could be almost 100% in the same conditions. To improve the Co extraction, hydrogen peroxide was used as a reducing agent in the range 2~20 vol%. When over 10vo1% hydrogen peroxide was added, the extractions of both metals were improved to about 95%. It seems to be due to the reduction of Co(III) to Co(II) that can be readily dissolved. The extractions of Co and Li were increased with increasing $H_2$$SO_4$concentration and temperature, and amount of hydrogen peroxide and with decreasing of pulp density. The optimum leaching conditions were determined at $2 M H_2$$SO_4$concentration, $75^{\circ}C$ operating temperature, 100 g/L. initial pulp density, 20 vol% $H_2$$O_2$addition and 30 min.

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A Study on the Methodology of Calculating Greenhouse Gas Emission Reduction by HFCs Reduction - Focusing on the Foam Industry - (HFCs 감축에 따른 온실가스 감축량 산정방법론 연구 - 발포산업을 중심으로 -)

  • Choi, Ji Won;Kim, Jung Man;Ahn, Jun Kwan
    • Journal of Climate Change Research
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    • v.9 no.4
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    • pp.399-406
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    • 2018
  • The purpose of this study is to propose a methodology for estimating greenhouse gas emission reduction through HFCs used in the foam industry. This study investigated characteristics of HFCs and greenhouse gas emissions from production processes in the foam industry, which uses HFCs as a blowing agent. Also, we investigated fluorinated gas removal technology to determine a proper technology for the foam industry. And we confirmed the criteria and characteristics of External Project for methodology development. According to criteria of External Project and foam industrial process emission, a methodology for calculating the amount of greenhouse gas emission reduction in foam industry was developed. Lastly, we analyzed the amount of greenhouse gas emission reduction and KOC (Korea Of Offset) in the foam industry based on the domestic government's plan to reduce HCFCs and imported amount of HFCs used as a blowing agent. The results of this study demonstrate that linking greenhouse gas reduction in the foam industry and the domestic greenhouse gas reduction system can contribute to achieve the domestic greenhouse gas reduction goal.

Ammoniacal Leaching for Recovery of Valuable Metals from Spent Lithium-ion Battery Materials (폐리튬이온전지로부터 유가금속을 회수하기 위한 암모니아 침출법)

  • Ku, Heesuk;Jung, Yeojin;Kang, Ga-hee;Kim, Songlee;Kim, Sookyung;Yang, Donghyo;Rhee, Kangin;Sohn, Jeongsoo;Kwon, Kyungjung
    • Resources Recycling
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    • v.24 no.3
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    • pp.44-50
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    • 2015
  • Recycling technologies would be required in consideration of increasing demand in lithium ion batteries (LIBs). In this study, the leaching behavior of Ni, Co and Mn is investigated with ammoniacal medium for spent cathode active materials, which are separated from a commercial LIB pack in hybrid electric vehicles. The leaching behavior of each metal is analyzed in the presence of reducing agent and pH buffering agent. The existence of reducing agent is necessary to increase the leaching efficiency of Ni and Co. The leaching of Mn is insignificant even with the existence of reducing agent in contrast to Ni and Co. The most conspicuous difference between acid and ammoniacal leaching would be the selective leaching behavior between Ni/Co and Mn. The ammoniacal leaching can reduce the cost of basic reagent that makes the pH of leachate higher for the precipitation of leached metals in the acid leaching.