• Title/Summary/Keyword: Co-Evaporation

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Composting of Food Waste by Non-Stirrer Sealed Fermenter and Change of NaCl content in Soil during the Pepper Cultivation (무교반 밀폐형 발효조를 이용한 음식물류폐기물 퇴비화 및 작물재배 중 염분의 함량 변화)

  • Hong, Sung Gil;Chang, Ki Woon;Kwon, Hyuk Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.13 no.3
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    • pp.82-88
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    • 2005
  • This study was carried out to investigate on the change of NaCl content during the food waste composting and on the safety of food waste compost(FWC) manufactured by the non-stirrer sealed fermenter. Plant culture test with pepper crop was also performed to see the effect of FWC, which was produced by the G co. ltd., on the growth of peper and migration of NaCl in soil. The culture test was performed at the farmland in Chungnam National University. The results were as follows; the NaCl content was gradually accumulated during food waste composting process, probably through water evaporation. Sodium concentration was, however, remarkably decreased at the final stage due to the desalting effect by water which was concentrated on the ceil of the fermentor. The analysis of chemical properties and humidity parameters on the food waste compost revealed that the product is quite a good qualified one. More than 0.5 tons of FWC application on red pepper cultivation caused diminished effect on the yield and the accumulation of salts on soil.

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Extraction of organic carbon from the condensate of food waste dry feed process (음식물류폐기물의 건식사료화 공정에서 발생되는 응축수로부터 유기탄소 추출)

  • Kim, Min-Kyung;Kwon, Ki-Wook;Mo, Kyung;Cui, Feng-Hao;Park, Se-Yong;Kim, Moon-Il
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.2
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    • pp.41-48
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    • 2020
  • In this study, organic carbon was extracted from the condensed water of food waste drying process to estimate the applicability as external organic carbon sources. The COD, TN, TP and TS of condensed water were 21,374 mg/L, 148 mg/L, 4.19 mg/L, and 455.7 mg/L, respectively. In addition, the content of biodegradable organics in condensed water was 47%. The fractional distillation and the vacuum evaporation were employed for extracting organic carbon. There were 8 extraction conditions, but 4 conditions were available for extraction. They were 1) 0mmHg, 110℃ 2) -600mmHg, 70℃ 3) -500mmHg, 80℃ 4) -600mmHg, 80℃. All 4 conditions showed the highest organic concentration and the highest quantity of organics when extracted 10% of initial volume. It was estimated that optimum conditions were 80℃, -600mmHg and 10% extraction. Then, extraction concentration, extraction quantity, extraction efficiency, extraction time, BOD/TCOD ratio, TVFAs/TCOD ratio and NH3-N were 174,200 mg/L, 8,710 mg, 46%, 10 min, 0.97, 0.74 and 75.5 mg/L respectively. Therefore, the extracted organic carbon can be utilized as external organic carbon sources.

The Combustion Characteristics of Residual Fuel oil Blended with Fuel Additives (잔사유용 연료첨가제 함유 선박 연료유의 연소특성 연구)

  • Jang, Se-Hyun;Lee, Kyoung-Woo;Kim, Jeong-Ryul;Kim, Jong-Ho;Yoon, Seok-Hun;Cho, Ik-Soon;Choi, Jae-Hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.5
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    • pp.554-563
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    • 2016
  • Ships are capable of operating on residual fuel oil. Recently, various attempts have been made to meet environmental regulations and with ships operating on residual fuel oil. One way of fulfilling these requirements is by using fuel additives. Dispersants and fuel combustion improvers will have a positive effect on improving the combustion characteristics of the residual fuel oil. As such, this study examines fuel oils blended with additives by using fuel combustion analysis (FIA/FCA) and thermogravimetric analysis (TGA). The results of FIA/FCA focuse only on the amount of work done by the fuel oil. Therefore, it is recommended in this study that a new method to evaluate the combustion efficiency via FIA/FCA processes be developed. The analysis with ROHR curve gained by FIA/FCA brought similar results with pressure trace curve therefore it can be said that new analysis method can be reliable. The TGA, analysis process is very sensitive to the evaporation of fuel, for example, which could be addressed. In the performance-related findings of this study, blended samples with additives containing iron compounds showed a greater improvement in early combustion characteristics than samples without additives.

Study on Recovery of Separated Hydrofluoric Acid, Nitric Acid and Acetic Acid Respectively from Mixed Waste Acid Produced during Semiconductor Wafer Process (반도체 웨이퍼 제조공정(製造工程) 중 발생혼합폐산(發生混合廢酸)으로부터 불산, 질산 및 초산의 각 산 회수(回收)에 관한 연구(硏究))

  • Kim, Ju-Yup;Kim, Hyun-Sang;Bae, Woo-Keun
    • Resources Recycling
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    • v.18 no.4
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    • pp.62-69
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    • 2009
  • We researched separation of mixed waste acids with HF, $CH_3COOH$, $HNO_3$ that were produced during a semiconductor wafer process to recycle these acids. At first, we manufactured the fluoride compound in form of $Na_2SiF_6$ by precipitating HF using $NaNO_3$ and Si powder. The concentration of HF was reduced from the initial concentration of 127 g/L to 0.5 g/L with an HF recovery ratio of 99.5%. After the manufacture of $Na_2SiF_6$, the concentration of $HNO_3$ and $CH_3COOH$ demonstrated 502 g/L and 117 g/L respectively. Following these findings we added NaOH in this $CH_3COOH/HNO_3$ mixed acid in order to obtain pH=4. Next we separated the $CH_3COOH$ and recoverd it through the use of vaccum evaporation at -440 mmHg, $95^{\circ}C$. The concentration of the recovered $CH_3COOH$ was approximately 15% and the recovery ratio of $CH_3COOH$ was over 85%. We precipitated the $NaNO_3$ by cooling the concentrated solution to $20^{\circ}C$ with a $HNO_3$ recovery ratio of over 93%. We confirmed that only $Na_2SiF_6$ and $NaNO_3$ were manufactured by XRD analysis after drying these precipitants at $90^{\circ}C$. The precipitants demonstrated a purity of approximately 97% and 98% respectively. Therefore, the purity of the precipitants proved to be similar to that of commercial products.

Treatment of Organic Wastes and Reuse of Bio-energy from the Anaerobic Digestion - Thermophilic Oxic Precess (혐기성 소화-고온 호기법에 의한 유기성폐기물의 처리와 생성열의 재활용 검토)

  • Yang, Jae-Kyung;Choi, Kyung-Min
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.1
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    • pp.79-89
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    • 2001
  • Anaerobic Digestion - Thermophilic Oxic Process(ADTOP) has been known to be one way reducing and composting of organic wastes without draining or forming excess sludge. It could be completely performed by the evaporation of water using the bio-energy from the microbial degradation of organic. In the present study the complete treatment of Chinese restaurant wastes was conducted and utility of bio-energy produced from the ADTOP was estimated. Base on results, it could be concluded as follows; 1) chinese restaurant wastes could be completely treated using the TOP without draining or excess sludge. Maximum volumetric loading rate was determined as $55.0kg-garbage/m^3$. Input water was almostly evaporated and 90.5% of carboneous organic wastes was conversed to carbondioxide. 2)The optimum volumetric loading rate which is acceptable to maintain over $55^{\circ}C$ in the anaerobic digester was determined as $45kg-garbage/m^3{\cdot}d$. 3) The optimum HRT was at least over 10 days in order to maintain about $50^{\circ}C$ in the anaerobic digester using bio-energy produced from TOP. Therefore the utilization of bio-energy produced from TOP could be used in the process which had long HRT such as the anaerobic digestion. 4) The efficiency of anaerobic digester rate were over 90% by the ADTOP under the organic loading rate of $1.1kg-COD/m^3{\cdot}d$, 50kg-Chinese restaurant garbage and $250{\ell}/m^3{\cdot}min$ of the aeration rate.

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High Temperature Oxidation Behavior of Fe-14Cr Ferritic Oxide Dispersion Strengthened Steels Manufactured by Mechanical Alloying Process (기계적 합금화 공정으로 제조된 Fe-14Cr Ferritic 산화물 분산 강화(ODS) 합금 강의 고온 산화 거동)

  • Kim, Young-Kyun;Park, Jong-Kwan;Kim, Hwi-Jun;Kong, Man-Sik;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.24 no.2
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    • pp.133-140
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    • 2017
  • This study investigates the oxidation properties of Fe-14Cr ferritic oxide-dispersion-strengthened (ODS) steel at various high temperatures (900, 1000, and $1100^{\circ}C$ for 24 h). The initial microstructure shows that no clear structural change occurs even under high-temperature heat treatment, and the average measured grain size is 0.4 and $1.1{\mu}m$ for the as-fabricated and heat-treated specimens, respectively. Y-Ti-O nanoclusters 10-50 nm in size are observed. High-temperature oxidation results show that the weight increases by 0.27 and $0.29mg/cm^2$ for the as-fabricated and heat-treated ($900^{\circ}C$) specimens, and by 0.47 and $0.50mg/cm^2$ for the as-fabricated and heat-treated ($1000^{\circ}C$) specimens, respectively. Further, after 24 h oxidation tests, the weight increases by 56.50 and $100.60mg/cm^2$ for the as-fabricated and heat-treated ($1100^{\circ}C$) specimens, respectively; the latter increase is approximately 100 times higher than that at $1000^{\circ}C$. Observation of the surface after the oxidation test shows that $Cr_2O_3$ is the main oxide on a specimen tested at $1000^{\circ}C$, whereas $Fe_2O_3$ and $Fe_3O_4$ phases also form on a specimen tested at $1100^{\circ}C$, where the weight increases rapidly. The high-temperature oxidation behavior of Fe-14Cr ODS steel is confirmed to be dominated by changes in the $Cr_2O_3$ layer and generation of Fe-based oxides through evaporation.

Effect of commercial Makgeolli on tumor growth in tumor xenograft mice (종양이식 모델 쥐에서 동결건조 시판 막걸리가 종양성장에 미치는 영향)

  • Shin, Eun-Ju;Kim, JaeHo;Seong, Ki-Seung;Yum, Sung-Kwan;Hwang, Jin-Taek
    • Food Science and Preservation
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    • v.23 no.1
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    • pp.104-109
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    • 2016
  • The purpose of this study was to evaluate the inhibitory effect of commercial Makgeolli on tumor growth in human gastric adenocarcinoma cells (AGS) in a xenograft cancer model, transplanted with AGS cells. Commercial Makgeolli was first dealcoholized by evaporation and used as the test sample. We detected a significant increase in the volume and weight of tumor in nude mice (induction) that were transplanted with AGS cells. Administration of $100mg/kg{\cdot}day$ group (ML), and $500mg/kg{\cdot}day$ group (MH) dealcoholized commercial Makgeolli significantly decreased tumor growth. In this study, 5-FU $18mg/kg{\cdot}day$ was used as a positive control for tumor growth inhibition. Additionally, determination of the body weight of both the groups revealed no side effects after the administration of dealcoholized commercial Makgeolli. Using the cell culture system, we also evaluated the effect of dealcoholized commercial Makgeolli on caspase-3/7 activity in the AGS cells. Treatment with dealcoholized commercial Makgeolli increased the activation of caspase-3/7 and the apoptotic markers in AGS cells in a dose-dependent manner. Therefore, dealcoholized commercial Makgeolli can be used for cancer prevention.

Fabrication of wide-bandgap β-Cu(In,Ga)3Se5 thin films and their application to solar cells

  • Kim, Ji Hye;Shin, Young Min;Kim, Seung Tae;Kwon, HyukSang;Ahn, Byung Tae
    • Current Photovoltaic Research
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    • v.1 no.1
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    • pp.38-43
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    • 2013
  • $Cu(In,Ga)_3Se_5$ is a candidate material for the top cell of $Cu(In,Ga)Se_2$ tandem cells. This phase is often found at the surface of the $Cu(In,Ga)Se_2$ film during $Cu(In,Ga)Se_2$ cell fabrication, and plays a positive role in $Cu(In,Ga)Se_2$ cell performance. However, the exact properties of the $Cu(In,Ga)_3Se_5$ film have not been extensively studied yet. In this work, $Cu(In,Ga)_3Se_5$ films were fabricated on Mo-coated soda-lime glass substrates by a three-stage co-evaporation process. The Cu content in the film was controlled by varying the deposition time of each stage. X-ray diffraction and Raman spectroscopy analyses showed that, even though the stoichiometric Cu/(In+Ga) ratio is 0.25, $Cu(In,Ga)_3Se_5$ is easily formed in a wide range of Cu content as long as the Cu/(In+Ga) ratio is held below 0.5. The optical band gap of $Cu_{0.3}(In_{0.65}Ga_{0.35})_3Se_5$ composition was found to be 1.35eV. As the Cu/(In+Ga) ratio was decreased further below 0.5, the grain size became smaller and the band gap increased. Unlike the $Cu(In,Ga)Se_2$ solar cell, an external supply of Na with $Na_2S$ deposition further increased the cell efficiency of the $Cu(In,Ga)_3Se_5$ solar cell, indicating that more Na is necessary, in addition to the Na supply from the soda lime glass, to suppress deep level defects in the $Cu(In,Ga)_3Se_5$ film. The cell efficiency of $CdS/Cu(In,Ga)_3Se_5$ was improved from 8.8 to 11.2% by incorporating Na with $Na_2S$ deposition on the CIGS film. The fill factor was significantly improved by the Na incorporation, due to a decrease of deep-level defects.

Preparation and Characteristics of Ipriflavone-Loaded PLGA Microspheres (이프리플라본을 함유한 생분해성 미립구의 제조와 특성분석)

  • 이진수;강길선;이종문;신준현;정제교;이해방
    • Polymer(Korea)
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    • v.27 no.1
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    • pp.9-16
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    • 2003
  • Ipriflavone (IP) stimulates proliferation and differentiation of osteoblast and also enhances calcitonin secretion in the presence of estrogen. Poly(lactide-co-glycolide) (PLCA) due to its controllable biodegradability and relatively good biocompatibility is one of the most significant candidates for the study of drug controlled release system. In this study, IP-loaded PLGA microspheres (MSs) was prepared by using conventional O/W solvent evaporation method. The size of MSs was in the range of 5~200 $mu extrm{m}$. The morphology of MSs was characterized by SEM. And, in vitro release amounts of IP were analyzed by HPLC. The highest encapsulation efficiency were obtained by using gelatin and polyvinyl alcohol (PVA) as emulsifiers. The morphology, size distribution, and in vitro release pattern of MSs were changed by several preparation parameters such as molecular weights (8, 20, 33 and 90 kg/mol), polymer concentrations (2.5, 5, 10 and 20%), emulsifier types (PVA, gelatin and Tween 80), initial drug loading amount (5, 10, 20 and 30%) and stirring speed (250, 500 and 1000 rpm). The release of IP in vitro was more prolonged over 30 days, with close to zero-order pattern by controlling the preparation parameters. The physicochemical properties of IP-loaded PLGA MSs were investigated by XRD and DSC.

A Study on the Life Time Prediction and Acid-Heat aging Property of NBR Rubber for Fuel Cell Gasket (연료전지 카스켓용 NBR 고무의 산-열 노화 특성과 수명예측에 관한 연구)

  • Kim, Mi-Suk;Kim, Jin-Hak;Kim, Seok-Jin;Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.42 no.1
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    • pp.20-31
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    • 2007
  • Material characteristics and lifetime evaluation are very important in design procedure to assure the safety and reliability of the rubber components. In this paper, the NBR compound was prepared by sulfur-cure system, and was used in predicting the lifetime of rubber gasket made by the compound. The accelerated material aging was investigated at different temperatures at 120, 140 and $160^{\circ}C$ and aging time from 3 hours to 600 hours at 5, 6, 7 vol %. of $H_2SO_4$ concentrations The rubber strips were placed in acid solution using pyrex g1ass tube. Both ends of pyrex g1ass tube were sealed to avoid evaporation of solution during heating at given time. The material test and accelerated acid-heat aging test were carried out to predict the useful life of NBR rubber gasket for a fuel cell stack. In order to investigate the effects of acid-heat aging on the properties of the NBR, tensile strength, elongation at break, hardness and crosslink-density were measured. The tensile strength decreases as the $H_2SO_4$ concentrations and temperature increase. Results were evaluated using Arrhenius equation.