• Title/Summary/Keyword: Co-Evaporation

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Manufacture of Control and Data Acquisition System of Centrifugal Thin Film Evaporator(Centri-Therm, CT-1B) by Computer (컴퓨터를 이용한 원심식 박막증발기의 제어 및 자료 수집 시스템의 제작)

  • Park, Noh-Hyun;Kim, Byeong-Sam;Park, Moo-Hyun;Han, Bong-Ho;Bae, Tae-Jin
    • Korean Journal of Food Science and Technology
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    • v.22 no.4
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    • pp.479-485
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    • 1990
  • For the automation of a evaporation process, computer based evaporation system was built and applied to acquisition of the process variables with an centrifugal thin film evaporator(Centri-Therm, CT-1B). Controls of the process conditions were performed by computer system for pressure, feeding rate, steam, evaporation temperature and flow rate of cooling water. The data acquisitions were also performed by computer system for the changes in the concentration and temperature readings for steam, evaporation and cooling water at the both inlet and outlet. The control and the acquisition variables were collected through the interface device and analyzed by programs using the PASCAL language. To control the feeding rate during the concentration process, inverter was used. The cooling water for the vapor condensation was controlled by the valve controller and should be supplied with the flow rate of 125 kg/h. The maximum vapor condensation rate was 41.7kg/h at the feeding rate of 125 kg/h.

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Different morphologies of three dimensional ZnO structures synthesized by thermal evaporation method without a catalyst (촉매를 사용하지 않는 열 기화법으로 다양한 형태의 ZnO 3차원 구조체 합성)

  • Bang, Sin Young;Tran, Van Khai;Oh, Dong Keun;Maneeratanasarn, Prachuporn;Choi, Bong Geun;Ham, Heon;Kim, Kyoung Hun;Shim, Kwang Bo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.1
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    • pp.8-13
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    • 2013
  • ZnO with different morphologies can be used various application depending on their shapes. Different morphologies of ZnO structures were synthesized by a catalysis-free thermal evaporation process. Their morphologies were dependent on the distance from the source to substrate on the same processing condition; in the result were products morphologies of the hollow, cage and star. Their shapes and crystalinity were evaluated by SEM and XRD, respectively. This work demonstrates what kind of growth factors would be involved in the final structure morphologies.

A study on noise properties of Co films deposited on Si (실리콘 기판에 증착된 코발트 박막의 잡음특성 연구)

  • 조남인;유순재
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.2
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    • pp.122-130
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    • 1996
  • In an effort to learn more about the reaction mechanisms which lead to the compound nucleation at the interface of cobalt and silicon, electrical noise properties has been investigated for cobalt thin films deposited on silicon substrates by the electron beam evaporation and rf sputtering techniques. Microstructural variations at the Co/Si interfaces have been observed by transmission electronmicroscopy. Amorphous structures are observed at the Co/Si interfaces for samples whose cobalt thicknesses are less than 4nm and a polycrystalline compound nucleation has been occurred for thicker films. 1/f noise power same samples, and the spetral density has been normalized. The amplitude of 1/f noise power spectral density shows a gradual increase as the cobalt thickness is increased, and the amplitude has dropped abruptly after the compound nucleation. The variations of the noise parameters areassumed to be an indiction of the phase transformation along the nucleation reaction path, and amplitude has been interpreted as instabilities of the Co/Si interfacial structures.

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Preparation and Oxygen Binding Properties of Ultra-Thin Polymer Films Containing Cobalt(II) meso-Tetraphenylporphyrin via Plasma Polymerization

  • Choe, Youngson
    • Macromolecular Research
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    • v.10 no.5
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    • pp.273-277
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    • 2002
  • Ultra-thin polymer films containing cobalt(II) meso-tetraphenylporphyrin(CoTPP) have been prepared by vacuum codeposition of the metal complex and trans-2-butene as an organic monomer using an inductively coupled RF glow discharge operating at 7-9 Watts. The polymer films were characterized by sorption measurements. Sorption data obtained for polymer films containing CoTPP indicate that the CoTPP molecules are capable of reversibly binding oxygen molecules. It was found that the adjacent CoTPP molecules in the aggregated metal complex phase could irreversibly share the oxygen molecules. A dispersion of the metal complex molecules in the polymer matrix was made to maintain the reversible reactivity of the metal complex molecules with oxygen in the polymer films via vacuum evaporation process. The Henry mode solubility constant, the Langmuir mode capacity constant, the amount of binding oxygen, and the dissociation equilibrium in the dual mode sorption theory were discussed.

Analysis of Sticking Coefficient in BSCCO Superconductor Thin Film Fabricated by Co-deposition (공증착법으로 제작한 BSCCO 초전도 박막의 부착계수 해석)

  • An, In-Soon;Chun, Min-Woo;Park, Yong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.300-303
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    • 2001
  • BSCCO thin films are fabricated via a co-deposition process by an ion beam sputtering with an ultra-low growth rate, and sticking coefficients of the respective elements are evaluated. The sticking coefficient of Bi element exhibits a characteristic temperature dependence : almost a constant value of 0.49 below $730^{\circ}C$ and decreases linearly with temperature over $730^{\circ}C$. This temperature dependence can be elucidated from the evaporation and sublimation rates of bismuth oxide, $Bi_{2}O_{3}$, from the film surface. It is considered that the liquid phase of the bismuth oxide plays an important role in the Bi 2212 phase formation in the co-deposition process.

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Evaluation of Sticking Coefficient in BSCCO Thin Film Fabricated by Co-sputtering

  • Lee, Hee-Kab;Park, Yong-Pil;Lee, Kwon-Hyun;Lee, Joon-Ung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.1
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    • pp.80-84
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    • 2000
  • BSCCO thin films are fabricated via a co-deposition process by an ion beam sputtering with an ultra-low growth rate, and sticking coefficients of the respective elements are evaluated. The sticking coeffi-cient of Bi element exhibits a characteristic temperature dependence : almost a constant value of 0.49 below 73$0^{\circ}C$ and decreases linearly with temperature over 73$0^{\circ}C$. This temperature dependence can be elucidated from the evaporation and sublimation rates of bismuth oxide, Bi\ulcornerO\ulcorner, from the film surface. It is considered that the liquid phase of the bismuth oxide plays an important role in the Bi(2212) phase formation in the co-deposition process.

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Analysis of Sticking Coefficient in BSCCO Superconductor Thin Film Fabricated by Co-deposition (공증착법으로 제작한 BSCCO 초전도 박막의 부착계수 해석)

  • 안인순;천민우;박용필
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.300-303
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    • 2001
  • BSCCO thin films are fabricated via a co-deposition process by an ion beam sputtering with an ultra-low growth rate, and sticking coefficients of the respective elements are evaluated. The sticking coefficient of Bi element exhibits a characteristic temperature dependence : almost a constant value of 0.49 below 730$^{\circ}C$ and decreases linearly with temperature over 730$^{\circ}C$. This temperature dependence can be elucidated from the evaporation and sublimation rates of bismuth oxide, Bi$_2$O$_3$, from the film surface. It is considered that the liquid phase of the bismuth oxide plays an important role in the Bi 2212 phase formation in the co-deposition process.

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A Study on the Antiferromagnetism and Exchange Anisotropy for Co/Pd Multilayered Thin Films by the Analysis of the Hall Effect (Hall 이력곡선 분해에 의한 Co/Pd 다층박막에서의 Antiferromagnetism 및 Exchange Anisotropy 분석)

  • 정진덕;이행기;김상록;이성래
    • Journal of the Korean Magnetics Society
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    • v.3 no.4
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    • pp.269-276
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    • 1993
  • Co/Pd multilayered thin films with various ratios of Co sublayers to Pd sublayers(nCo/nPd = 1/4, 2/4, 3/4, 5/4) were fabricated at different substrate temperatures($R.\;T.,\;100,\;150,\;200\;^{\circ}C$) with the conventional vacuum evaporation method, and their Hall voltage hysteresis curves were measured. These Hall curves were decomposed on the basis of the superpose of the transverse Hall effect term from the magnetizations of Co and Pd sublayers and the magnetoresistivity term, by the optimal fitting method. In the results, both of the ferromagnetic and anti ferromagnetic states coexisted through whole samples, and the uniaxial or unidirectional easy axis type Hall hysteresis curves occured were dependent upon the effects of the exchange anisotropy between both magnetic states and the domain wall pinning by the antiferromagnet inclusions.

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Study on the performance characteristics of a new CO2 auto-cascade heat pump system (새로운 CO2 오토 캐스케이드 열펌프 시스템의 성능특성 연구)

  • Yun, Sang-Kook
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.3
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    • pp.191-196
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    • 2017
  • Owing to the harmful environmental effects of HCFC and CFC refrigerants discovered in the late 20th century, the need for environmentally friendly refrigerants such as $CO_2$ in cooling systems has increased. Air-source $CO_2$ heat pumps that utilize ambient heat in cold winter are less efficient because of a higher evaporation temperature, and it is difficult to manufacture the components of the heat pump owing to a super critical pressure of over 130 bar. This research aims to overcome these disadvantages and improve energy efficiency by introducing a new lower-pressure $CO_2$ auto-cascade heat pump system. $CO_2$-R32 zeotropic refrigerants were considered for two-stage expansion and effective cooling heat exchanging system configurations of the new auto-cascade heat pump. The results indicated that the efficiency of the two-stage expansion system was higher than that of the original one-stage expansion system. Furthermore, the two-stage expansion system showed significant performance improvements when the two-stage expansion stage from highest pressure of 70bar, intermediate expansion pressure of 25bar, and final low pressure of 10bar is applied. The COP of the new two-stage auto-cascade system (2.332) was 43.15% higher than that of the present simple auto-cascade system (1.629). Refrigerants having an evaporation temperature of $-10^{\circ}C$ or lower can be obtained that can be easily evaporated in an evaporator even at a low temperature.

Effects of Sm:Ba:Cu Composition Ratio on the Superconducting Properties of SmBCO Coated Conductor Prepared by using a Composition Gradient Method (SmBCO 초전도 선재 특성에 대한 Sm:Ba:Cu 조성비의 영향)

  • Kim, H.S.;Oh, S.S.;Jang, S.H.;Min, C.H.;Ha, H.S.;Ha, D.W.;Ko, R.K.;Youm, D.J.;Moon, S.H.;Chung, K.C.
    • Progress in Superconductivity
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    • v.13 no.1
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    • pp.7-11
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    • 2011
  • The effects of Sm:Ba:Cu composition ratio in SmBCO coated conductor on their superconducting properties were investigated. The SmBCO coated conductors were fabricated by reactive co-evaporation method using EDDC(Evaporation using Drum in Dual Chamber) system. In this system, we could obtain various samples with different composition ratios in a batch by the technique providing composition gradient at deposition zone. From the specimens prepared by EDDC system, we found that composition ratio is uniform parallel to the drum axis, but gradient along the circumferential direction of the drum. We installed a shield having parallelogram open area between the deposition chamber and the evaporation chamber in EDDC system, and attached a 30 cm long template, which is parallel to drum axis, onto the drum surface. In this configuration, we could obtain SmBCO coated conductors having a gradient composition along the length of template. We measured the composition ratios and surface morphologies with periodic interval by SEM and EDAX, and confirmed the profile of composition ratio. We also measured critical current using non-contact Hall probe critical current measurement system and thereby could plot composition ratio vs. critical current. The maximum critical current was obtained, and the surface morphology with the shape of roof tile was observed at the corresponding composition ratio of Sm:Ba:Cu = 1.01:1.99:4.87. It was also found that composition ratio had an effect on not only critical current but also surface morphology.