• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 2009년 추계학술발표대회
• /
• pp.217-220
• /
• 2009

Conductive adhesives have been investigated for use in microelectronics packaging as a lead-free solder substitute due to their advantages, such as low bonding temperature. However, high resistivity and poor mechanical behavior may be the limiting factors for the development of conductive adhesives. The metal fillers and the polymer resins provide electrical and mechanical interconnections between surface mount device components and a substrate. As metal fillers used in conductive adhesives, silver is the most commonly used due to its high conductivity and the stability. However the cost of conductive adhesives with silver fillers is much higher than usual lead-free solders and silver has poor electro-migration performance. So, copper can be a promising candidate for conductive filler metal due to its low resistivity and low cost, but oxidation causes this metal to lose its conductivity. In this study, electrically conductive adhesives (ECAs) using surface modified copper fillers were developed. Especially, in order to overcome the problem associated with the oxidation of copper, copper particles were coated with silver, and the silver-coated copper was tested as a filler metal. Especially the effect of silver coating on the electrical resistance just after curing and after aging was investigated. As a result, it was found that the electrical resistance of ECA with silver-coated copper filler was clearly lower and more stable than that of ECA with pure copper filler after curing process. And, during high temperature storage test, the degradation rate of electrical resistance for ECA with silver coated copper filler was quite slower than that for ECA with pure copper filler.

• Composites Research
• /
• 제30권2호
• /
• pp.116-125
• /
• 2017

본 연구의 목적은 고온 산화성 분위기하에서 기계적물성이 우수한 탄화규소섬유(SiC Fiber)를 파일롯-규모로의 생산 제조공정을 개발하는 것이다. 프리세라믹 전구체로서 폴리카보실란(PCS)을 사용하여 탄화규소섬유를 제조하였다. 연속성의 PCS 섬유는 $300{\sim}350^{\circ}C$에서 PCS를 용융한 후에 용융방사로부터 얻었다. 열처리 전에 섬유의 불융화를 위하여 공기 분위기하에서 경화를하였다. 경화 전, 후에 측정한 FT-IR 스펙트라 피크로 부터 경화도를 계산하였다. 탄화규소섬유의 물성은 경화도에 따라 크게 영향을 받았다. 본 개발에서 열처리 중 섬유의 장력 조절로 우수한 물성을 갖는 탄화규소섬유를 얻었다. 탄화규소섬유의 화학조성과 기계적물성은 안정화섬유의 열처리시의 이송속도에 영향을 받았다. 탄화규소섬유를 공기분위기하 $1000^{\circ}C$에서 1분부터 50시간까지 노출한 후에 인장시험을 수행하였다. 그 결과 인장강도는 약 60%까지 감소함을 보여주었다. 장시간 노출시험시 낮은 인장 강도값을 나타내는 섬유는 화학성분 분석시 섬유의 표면에 많은 탄소량을 함유하고 있었다.

• 한국건설순환자원학회논문집
• /
• 제11권1호
• /
• pp.9-15
• /
• 2023

시멘트는 대표적인 이산화 탄소 배출 산업이다. 에너지 소비와 CO₂ 배출 저감을 위해 제조 공정 개선 및 대체 재료의 사용확대가 필요하다. 따라서 본 연구는 CO₂ 흡착형 재료인 CAF을 저온 소성하여 시멘트에 적용하여 시멘트 수화의 기본 특성을 확인하였다. 합성 CAF의 수화 생성물에 대한 결정상 분석과 공극 분포, 그리고 구조 이미지를 확인하고, 압축강도를 측정하였다. SCAF는 치환율은 10, 20, 100 %으로 하였으며, 치환율의 증가에 따라 압축강도는 저하되는 경향을 보인다. 또한, SCAF 치환율 100%인 경우, 초기 재령의 수화 생성물은 calcium aluminum oxide hydrate (Ca₃Al₂O₆·xH₂O)와 calcium iron hydroxide (Ca₃Fe(OH)₁₂)이며, 치환율 10, 20 %에서는 일반적인 시멘트 수화물 외에 CAF 화합물인 Brownmillerite가 관찰되었다. 또한, 공극율은 치환율의 증가에 따라 공극 크기가 크고 공극율이 높았다. 본 연구 결과 저온 소성으로 제조된 CAF는 CO₂ 흡착형 재료로 활용을 위해 단독 사용 및 일반 양생은 어려울 것으로 보인다.

• Fibers and Polymers
• /
• 제4권4호
• /
• pp.182-187
• /
• 2003

Low molecular weight copolymers of maleic anhydride and vinyl acetate were prepared to develop formaldehyde free cross-linking agents. Since lower molecular weight is favorable for efficient penetration of the finishing agent into the cotton fibers in the padding process, the concentration of the initiator, chain transfer agent and the monomer ratios were varied to obtain copolymers of low molecular weights. The prepared polymers were characterized by GPC, $^1{H-NMR}$, FTIR, DSC and TGA. Copolymers of molecular weights of 2 000 to 10 000 were obtained and it was found that the most efficient method of controlling the molecular weight was by varying the monomer ratios. Poly(maleic anhydride-co-vinyl acetate) did not dissolve in water, but the maleic anhydride residue hydrolyzed within a few minutes to form poly(maleic acid-co-vinyl acetate) and dissolved in water. However, the maleic acid units undergo dehydration to form anhydride groups on heating above ${160}^{\circ}C$ to some extent even in the absence of catalysts. The possibility of using the copolymers as durable press finishing agent for cotton fabric was investigated. Lower molecular weight poly(maleic anhydride-co-vinyl acetate) copolymers were more efficient in introducing crease resistance, which appears to be due to the more efficient penetration of the cross-linking agent into cotton fabrics. The wrinkle recovery angles of cotton fabrics treated with poly(maleic anhydride-co-vinyl acetate) copolymers were slightly lower than those treated with DMDHEU and were higher when higher curing temperatures or higher concentrations of copolymer were used, and when catalyst, $NaH_2$$PO_2$, was added. The strength retention of the poly(maleic anhydride-co-vinyl acetate) treated cotton fabrics was excellent.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2000년도 추계학술발표대회 논문집
• /
• pp.84-87
• /
• 2000

Square tubes used for vehicle structure components have an important role on keeping its stiffness and preserving occupant safety in vehicle collision and rollover in which it experience axial collapse, bending collapse or both. Bending collapse, which absorbs kinetic energy of the impact and retains a survival space for the occupant, is a dominant failure mode in oblique collision and rollover. Thus, in this paper, the bending collapse characteristics such as the maximum bending moment and energy absorption capacity of the square tube replaced by light-weight material were evaluated and presented. The bending test of cantilever tubes which were fabricated with aluminum, GFRP and aluminum/ GFRP hybrid by co-curing process was performed. Then the maximum bending moment and the energy absorption capacity from the moment-angle curve were evaluated. Based on the test results, it was found that aluminum/ GFRP hybrid tube can show better specific energy absorption capacity compared to the pure aluminum or GFRP tube and can convert unstable collapse mode which may occur in pure GFRP tube to stable collapse mode like a aluminum tube in which plastic hinge is developed.

• 한국산학기술학회:학술대회논문집
• /
• 한국산학기술학회 2006년도 추계학술발표논문집
• /
• pp.269-271
• /
• 2006

Pyromellitic anhydride(PMDA)와 4,4-Oxydianiline(ODA)로부터 Polyimide의 전구체인 Poly(amic acid)(PAA)를 합성하고, 이를 열을 가하여 Polyimide되는 반응을 적외선 분광법을 이용하여 추적하였다. 이미드화 반응은 $175^{\circ}C$에서 1시간, $185^{\circ}C$에서 1시간, $195^{\circ}C$에서 1시간, $215^{\circ}C$에서 1시간, $235^{\circ}C$에서 1시간 경화시킴으로 완결됨을 확인하였다.

• 한국세라믹학회지
• /
• 제47권3호
• /
• pp.216-222
• /
• 2010

Portland cement has been restricted in applications to ecological area because of its environmental harmfulness and the $CO_2$ emission during a production process. Geopolymer materials attract some attention as an inorganic binder due to their superior mechanical and eco-friendly properties. In this study, geopolymer-based cement was prepared by using aluminosilicate minerals (flyash, meta-kaolin) with alkaline-activators and its compressive strength with concentration of alkaline-activators was investigated. Aluminosilicate-based geopolymers were obtained by mixing aluminosilicate minerals, alkaline solution (NaOH or KOH with different concentration) and water-glass under the vigorous stirring for 20 min. Compressive strength after curing at $30^{\circ}C$ for 3 days increased with the concentration of alkaline-activator due to the enhanced polymerization of the aluminosilicate materials and dense microstructure. Aluminosilicate-based geopolymer cement using KOH as an alkaline-activator showed high compressive strength compared with NaOH activator. In addition, geopolymer cement using fly-ash as a raw material showed higher compressive strength than that of meta-kaolin.

• Corrosion Science and Technology
• /
• 제12권6호
• /
• pp.295-303
• /
• 2013

Silane surface treatments have been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. The silane performance is comparable to, or in some cases better than, that of chromate layers. Based on the tetra-ethylorthosilicate(TEOS) and methlyl trieethoxysilane(MTES), inorganic sol was synthesized and formed hybrid networks with $SiO_2$ nano particle and polypropylene glycol(PPG) on Zn alloyed steel surface. According to SST results, addition of 10nm and 50nm $SiO_2$ nanoparticle in synthesized solution improved anti-corrosion property by its shear stress relaxation effect during curing process. Also, SST results were shown that anti-corrosive property was affected by the amounts of organic compounds.

• 한국지반공학회:학술대회논문집
• /
• 한국지반공학회 2009년도 춘계 학술발표회
• /
• pp.368-375
• /
• 2009

This paper describes field installation and load test results performed for three types of micropiles in the process of developing a new micropiling method. Field tests were performed for two conventional types(i.e., micropile reinforced with steel bar and gravity grouting, micropile reinforced with steel bar and steel casing and gravity grouting) and a proposed type(i.e., micropile reinforced with hollow steel pipe wrapped with geotextile-pack and pressurized grouting). The load test results subjected to axial compression and tension and lateral loading conditions are described in this paper. The micropiles were exposed in the air in order to verify the installation quality and curing condition of grouting material via ground excavation. Axial compression and tension test results indicate that the new micropile type provide at least 40% higher bearing capacity than that of conventional types. Based on the examination of exposed piles, it is induced that the proposed method, packed micropile, provides better interlocking between grouts and surrounding soils and increases higher frictional resistance comparing to conventional types.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2000년도 제18회 학술발표회 논문개요집
• /
• pp.213-213
• /
• 2000

Direct laser vaporization of transition-metal(Co, Ni)/graphite composite pellet produced single wall carbon naotubes(SWNT) in the condensing vapor in a heated flow cylinder-type tube furnace, Transition metal/graphite composite pellet target was made by mixing graphite, Co, and Ni in 98:1:1 atomic weight ratios, pressing the mixed powder, and curing it. The target was placed in a tube furnace maintained at 1200$^{\circ}C$ and Ar inert collision gas continuously flowed into the tube. The 2nd harmonic, 532nm wavelength light from Nd-YAG laser was used to vaporize the tube. The carbon nanotubes produced by the laser vaporization were accumulated on quartz tube wall. The raw carbon nanotube materials were purified with surfactants(Triton X-100) in a ultrasonicator. These carbon nanotubes were analyzed using SEM, XRD, and Raman spectroscopic method. The carbon nanotube growth on the Ni-patterned Si substrate was investigated by the CVD process. Transition-metal, Ni and CH4 gas were used as a catalyst and a reactant gas, respectively. The structure and the phonon frequencies of the carbon nanotubes formed on the patterned Si substrate were measured by SEM and Raman spectrometer.