• Bulletin of the Korean Chemical Society
• /
• v.35 no.5
• /
• pp.1323-1328
• /
• 2014

Molecular structures of the various conformational stereoisomers of 2,8,14,20-cyanophenyl pyrogallol[4]arenes 1 were optimized using the mPW1PW91 (hybrid Hartree-Fock density functional) calculation method. The total electronic and Gibbs free energies and the normal vibrational frequencies of the different structures from three major conformations (CHAIR, TABLE, and 1,2-Alternate) of the four stereoisomers [1(rccc), 1(rcct), 1(rctt), and 1(rtct)] were analyzed. The mPW1PW91/6-31G(d,p) calculations suggested that $1(rcct)_{1,2-A}$, 1(rctt)CHAIR, and $1(rtct)_{CHAIR}$ were the more stable conformations of the respective stereoisomers. Hydrogen bonding is the primary factor for the relative stabilities of the various conformational isomers, and maximizing the ${\pi}-{\pi}$ interaction between the cyanophenyl rings is the secondary factor. The calculated IR spectra of the more stable conformers [$1(rctt)_{CHAIR}$, $1(rcct)_{1,2-A}$, $1(rtct)_{CHAIR}$] were compared with the experimental IR spectrum of $1(rtct)_{CHAIR}$.

• Proceedings of the KIEE Conference
• /
• 2005.10a
• /
• pp.136-138
• /
• 2005

The conventional self-tuning methods have the speed control problem of nonlinear BLDC motor which can't adapt against any kinds of noise or operation circumstances. In this paper, supposed to solve these problem to PI parameters controller algorithm using ANN. In the proposed algorithm, the parameters of the controller were adjusted to reduce by on-line system the error of the speed of BLDC motor. In this process, EBPA NN was constituted to an output error value of a BLDC motor and conspired an input and output. The performance of the self-tuning controller is compared with that of the PI controller tuned by conventional method(Z&N). The effectiveness of the proposed control method IS verified thought the Matlab Simulink.

• Proceedings of the KIEE Conference
• /
• 2009.04b
• /
• pp.225-227
• /
• 2009

The conventional fixed gain PI controller is very sensitive to step change of command speed, parameter variation and load disturbances. The precise speed control of interior permanent magnet synchronous motor(IPMSM) drive becomes a complex issue due to nonlinear coupling among its winding currents and the rotor speed as well as the nonlinear electromagnetic developed torque. Therefore, there exists a need to tune the PI controller parameters on-line to ensure optimum drive performance over a wide range of operating conditions. This paper is proposed artificial intelligent-PI(AIPI) controller of IPMSM drive using adaptive learning mechanism(ALM) and fuzzy neural network(FNN). The proposed controller is developed to ensure accurate speed control of IPMSM drive under system disturbances and estimation of speed using artificial neural network(ANN) controller. The PI controller parameters are optimized by ALM-FNN at all possible operating condition in a closed loop vector control scheme. The validity of the proposed controller is verified by results at different dynamic operating conditions.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.19 no.8
• /
• pp.48-55
• /
• 2005

This paper presents a new speed control scheme of the spindle induction motor(IM) using fuzzy controller(FC) in field weakening region. The implementation of the proposed FC based spindle Induction Motor(IM) is compared to those obtained from the conventional PI controller based drive system. The simulation and experimental results show that the FC is the high performance more than the conventional PI speed controller in the spindle drive systems.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
• /
• 2009.05a
• /
• pp.420-423
• /
• 2009

The conventional fixed gain PI controller is very sensitive to step change of command speed, parameter variation and load disturbances. The precise speed control of interior permanent magnet synchronous motor(IPMSM) drive becomes a complex issue due to nonlinear coupling among its winding currents and the rotor speed as well as the nonlinear electromagnetic developed torque. Therefore, there exists a need to tune the PI controller parameters on-line to ensure optimum drive performance over a wide range of operating conditions. This paper is proposed hybrid intelligent-PI(HIPI) controller of IPMSM drive using adaptive learning mechanism(ALM) and fuzzy neural network(FNN). The proposed controller is developed to ensure accurate speed control of IPMSM drive under system disturbances and estimation of speed using artificial neural network(ANN) controller. The PI controller parameters are optimized by ALM-FNN at all possible operating condition in a closed loop vector control scheme. The validity of the proposed controller is verified by results at different dynamic operating conditions.

• Proceedings of the KIEE Conference
• /
• 2005.07b
• /
• pp.1453-1455
• /
• 2005

This paper presents self tuning PI controller of IPMSM drive using neural network. Self tuning PI controller is developed to minimize overshoot, rise time and settling time following sudden parameter changes such as speed, load torque and inertia. Also, this paper is proposed speed control of IPMSM using neural network and estimation of speed using artificial neural network(ANN) controller. The results on a speed controller of IPMSM are presented to show the effectiveness of the proposed gain tuner. And this controller is better than the fixed gains one in terms of robustness, even under great variations of operating conditions and load disturbance.

• KOREAN JOURNAL OF CROP SCIENCE
• /
• v.45 no.4
• /
• pp.261-266
• /
• 2000

This study was to investigate antioxidative activity of rice grain using 1, 1-Diphenyl-2-picrylhydrazyl(DPPH) and thiobarbituric acid (TBA) method and germination ability for screening rice varieties with high antioxidative activities on korean native and foreign rice varieties harvested in 1998 and 1999. The average antioxidative activity of foreign rice varieties (DPPH 63.5% and TBA 55.2%) was significantly higher than that of native rice varieties (DPPH 47.2% and TBA 45.6%) on varieties harvested in 1999. The promptness index (PI) of native rice varieties was higher in stored rices for three months (mean PI=160.7) than that of stored rices for a year (mean PI=141.6). On the other hand, the PI of foreign rice varieties was higher in stored rices stored for a year (mean PI=176.7) than that of stored rices for three months (mean PI=157.5). Varieties with high redness of hulled rice (a-value) showed significant lipid peroxidation inhibitory activity to DPPH in a stored rices for a year (r=${0.5744}^**$) and stored rices for three months (r=${0.5630}^**$) . These results indicate that the pigments of hulled rice varieties may play important antioxidative roles and colored rice varieties with higher antioxidative potentials can be developed and also may provide information with rice breeder to breed rice variety with a high antioxidative activity for a rapid screening of a small amounts of a large number of samples using color value.

• Journal of the Korean Society of Food Science and Nutrition
• /
• v.28 no.3
• /
• pp.698-704
• /
• 1999

In this study, we evaluated the radioprotective effects of Kuei Pi Tang and its ingredients, as a prescription of traditional Oriental medicine. The jejunal crypt survival, endogenous spleen colony formation, and apoptosis in jejunal crypt cells were investigated in mice irradiated with high and low dose of ${\gamma}$ rays. In the mice administered with Kuei Pi Tang extract before irradiation, the jejunal crypts were protected significantly(p<0.005) and the frequency of radiation induced apoptosis was reduced(p<0.05). In the experiment on the effects of the ingredients of Kuei Pi Tang, the results indicated that the extract of Dangui(Angelica sinensis), Suanzaoren(Zizyphus valgaris), Rensan (Panax ginseng), Fuling(Poria cocos) and Muxiang(Saussurea lappa) might have a major radioprotective effect. Although the mechanisms of this inhibitory effect remain to be elucidated, these results indi cated that Kuei Pi Tang might be a useful radioprotector, especially since it is a relatively nontoxic natural product.

• Journal of the Korean Geotechnical Society
• /
• v.21 no.1
• /
• pp.5-14
• /
• 2005

Based on the field measuring data obtained from excavation sections in Inchon International Airport project, the relationships between the horizontal displacement of sheet-pile walls and the deformations of soft ground around the excavation were investigated. The horizontal displacements of walls according to supporting method occur, and the displacements were found to become larger in the order of anchors, anchors with struts, and struts. The depths of maximum horizontal displacement are varied with supporting systems. If the stability number shows lower than ${\pi}$, the maximum horizontal displacement and the velocity of maximum horizontal displacement are respectively developed less than $1\%$ of excavation depth and 1mm/day. When the stability number shows lower than ${\pi}+2$, the maximum horizontal displacement and the velocity are respectively developed less than $2.5\%$ of excavation depth and 2mm/day. Also, when the stability number shows more than ${\pi}+2$, the maximum horizontal displacement and the velocity rapidly increase. Also, the maximum horizontal displacement is found to increase rapidly when N value is less than 10. The maximum horizontal displacement increases with decreasing the factor of safety against basal heave (Terzaghi, 1943), and the maximum horizontal displacement is found to increase rapidly when the factor of safety against basal heave is greater than 2.0. This value can be proposed as the criterion for the factor of safety against basal heave in Korea.

• Microbiology and Biotechnology Letters
• /
• v.16 no.6
• /
• pp.517-521
• /
• 1988

This study focused on the psychrotrophic post-pasteurization contamination of fluid milk pro-ducts which were processed by HTST system. Pasteurized line samples and container samples of each fluid milk product (whole milk and skim milk) were taken in a large fluid milk plant. tine samples were collected through nine and five different sampling locations for whole milk and skim milk products, respectively. Each sample was subjected to preliminary incubation (PI) at 21$^{\circ}C$ for 16h followed by standard plate count (SPC) and crystal violet tetrazolium agar count (CVT). Flavor, SPC, and psychrotrophic bacteria count (PBC) were determined after 7 d at 7.2$^{\circ}C$. In addition, ten sequential container samples (packaged in 1000ml paperboard containers) were taken from a filler at the beginning of each product run. These samples were used for PI followed by SPC and CVT. In addition, flavor evaluations, SPC and PBC tests were conducted after 7,10, and 14 d at 7.2$^{\circ}C$. The mean PI-CVT values for the line samples showed differences depending on the location. There was major contamination between pasteurized storage tank and the filler. The PI-CVT counts for each container sample were negatively correlated with flayer scores at 10 and 140. There were good correlations among PI-CVT values of line samples and the percentage of total container samples with acceptable flavor after 10d.