• Environmental Engineering Research
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• v.21 no.2
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• pp.152-163
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• 2016

Present study investigates the potential of cassava peel and rubber tree bark for the removal of Cr (VI) from aqueous solution. Removal efficiency of more than 99% was obtained during the kinetic adsorption experiments with dosage of 3.5 g/L for cassava peel and 8 g/L for rubber tree bark. By comparing popular isotherm models and kinetic models for evaluating the kinetics of mass transfer, it was observed that Redlich-Peterson model and Langmuir model fitted well ($R^2$ > 0.99) resulting in maximum adsorption capacity as 79.37 mg/g and 43.86 mg/g for cassava peel and rubber tree bark respectively. Validation of pseudo-second order model and Elovich model indicated the possibility of chemisorption being the rate limiting step. The multi-linearity in the diffusion model was further addressed using multi-sites models (two-site series interface (TSSI) and two-site parallel interface (TSPI) models). Considering the influence of interface properties on the kinetic nature of sorption, TSSI model resulted in low mass transfer rate (5% for cassava peel and 10% for rubber tree bark) compared to TSPI model. The study highlights the employability of two-site sorption model for simultaneous representation of different stages of kinetic sorption for finding the rate-limiting process, compared to the separate equilibrium and kinetic modeling attempts.

• Journal of the Korean GEO-environmental Society
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• v.20 no.5
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• pp.39-46
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• 2019

Most of the soil used for reclamation is marine clay generated from dredging construction.The soft ground made of dredged clay has high water content and high compressibility, so the bearing capacity of the ground is very weak and it is difficult to enter the ground improvement equipment. Therefore, surface hardening treatment method is used to enter equipment prior to full-scale civil engineering work, and stabilizer is mainly used for cement series. Cement-based stabilizers have the advantage of improving the ground in a short period of time and have excellent economic efficiency, but they are disadvantageous in that they cause environmental problems due to leaching of heavy metals such as hexavalent chromium. In this study, environmental effects evaluation of dredged clay mixed with normal portland cement and environmentally friendly stabilizer was evaluated, and uniaxial compressive strength test and indoor model test were conducted to confirm the bearing capacity characteristics of the solidified layer.

• FLOWER RESEARCH JOURNAL
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• v.17 no.4
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• pp.242-245
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• 2009

In order to investigate the cytotoxic effect of hexavalent chromium ($Cr0_3$) and the protective effect of Nelumbo nucifera GAERTN (NNG) extract, cultured cerebral neuroglial cells (C6 glioma cells) were treated with $4{\sim}55{\mu}M$ concentrations of $Cr0_3$ for 48 hours. Cell viability was measured by XTT assay. The superoxide dismutase (SOD)-like activity for the antioxidant effect was also examined on the extract of NNG stamen. In this study, $Cr0_3$ significantly decreased cell viability dose-dependently. The cytotoxicities of $XTT_{90}$ and $XTT_{50}$ determined with $10{\mu}M$ and $55{\mu}M$ of $Cr0_3$, respectively, showed that the $Cr0_3$ had highly toxic effect on cultured C6 glioma cells by the cytotoxic criteria. In the protective effect of NNG extract, the cell viability was significantly increased by the treatment of NNG extract, and NNG extract increased SOD-like activity. From these results, it is suggested that $Cr0_3$ showed highly toxic effect on cultured C6 glioma cell s and NNG extract was very effective in the protection of $Cr0_3$-mediated cytotoxicity by antioxidative effect in these cultures.

• Journal of the Mineralogical Society of Korea
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• v.21 no.2
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• pp.161-175
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• 2008

The soil developed from volcanic ash in Jeju Island, Korea, were classified as typical Andisols. The soils had acidic pH, high water contents, high organic matters and clay-silty textures. The crystalline minerals of the samples were mainly composed of ferromagnesian minerals such as olivine and pyroxene, and iron oxides such as magnetite and hematite derived from basaltic materials. A large amount of gibbsite was found at the subsurface horizon as a secondary product from the migration of excessive aluminum. In addition, our study has shown that considerable amounts of poorly ordered minerals like allophane and ferrihydrite were present in Jeju soils. The contents of $SiO_2$ were lower than those of other soil orders, but $A1_2O_3$ and $Fe_2O_3$ contents were higher. These results are some of the important chemical properties of Andisols. The contents of heavy metals were in the range of $84{\sim}198$ for Zn, $56{\sim}414$ for Ni, $38{\sim}150$ for Co, $132{\sim}1164\;mg\;kg^{-1}$ for Cr, which are higher than the worldwide values in most of the soils. Some soil samples contained relatively high levels of Cr exceeding 1000 mg/kg. Mean reduction capacity of the Jeju soils was $6.53\;mg\;L^{-1}$ reduced Cr(VI), 5.1 times higher than that of the non-volcanic ash soils from inland of Korea. The soil reduction capacity of the inland soils had a good correlation with total carbon content (R = 0.90). However, in spite of 20 times higher total carbon contents in the Jeju soils, there was a week negative correlation between the reduction capacity and the carbon content (R = -0.469), suggesting that the reduction capacity of Jeju soils is not mainly controlled by the carbon content and affected by other soil properties. Correlations of the reduction capacity with major elements showed that Al and Fe were closely connected with the reduction capacity in Jeju soil (R = 0.793; R = 0.626 respectively). Moreover, the amounts of Ni, Co and Cr had considerable correlations with the reduction capacity (R = 0.538; R = 0.647; R = 0.468 respectively). In particular, in relation to the behavior of redox-sensitive Cr, the oxidation of the trivalent chromium to mobile and toxic hexavalent chromium can be restricted by the high reduction capacity in Jeju soil. The factors controlling the reduction capacity in Jeju soils may have a close relation with the andic soil properties explained by the presence of considerable allophane and ferrihydrite in the soils.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.5
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• pp.524-533
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• 2008

Industrial wastewater generated in the electroplating and metal finishing industries typically contain toxic free and complex metal cyanide with various heavy metals. Alkaline chlorination, the normal treatment method destroys only free cyanide, not complex metal cyanide. A novel treatment method has been developed which destroys both free and complex metal cyanide as compared with Practical Plant(I). Prior to the removal of complex metal cyanide by Fe/Zn coprecipitation and removal of others(Cu, Ni), Chromium is reduced from the hexavalent to the trivalent form by Sodium bisulfite(NaHSO$_3$), followed by alkaline-chlorination for the cyanide destruction. The maximum removal efficiency of chromium by reduction was found to be 99.92% under pH 2.0, ORP 250 mV for 0.5 hours. The removal efficiency of complex metal cyanide was max. 98.24%(residual CN: 4.50 mg/L) in pH 9.5, 240 rpm with 3.0 $\times$ 10$^{-4}$ mol of FeSO$_4$/ZnCl$_2$ for 0.5 hours. The removal efficiency of Cu, Ni using both hydroxide and sulfide precipitation was found to be max. 99.9% as Cu in 3.0 mol of Na$_2$S and 93.86% as Ni in 4.0 mol of Na$_2$S under pH 9.0$\sim$10.0, 240 rpm for 0.5 hours. The concentration of residual CN by alkaline-chlorination was 0.21 mg/L(removal efficiencies: 95.33%) under the following conditions; 1st Oxidation : pH 10.0, ORP 350 mV, reaction time 0.5 hours, 2nd Oxidation : pH 8.0, ORP 650 mV, reaction time 0.5 hours. It is important to note that the removal of free and complex metal cyanide from the electroplating wastewater should be employed by chromium reduction, Fe/Zn coprecipitation and, sulfide precipitation, followed by alkaline-chlorination for the Korean permissible limit of wastewater discharge, where the better results could be found as compared to the preceding paper as indicated in practical treatment(I).

• Journal of the Korean Geosynthetics Society
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• v.17 no.1
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• pp.1-10
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• 2018

We conducted research to develop a solidification agent for the ground surface reinforcement method in which activator is fused by recycling pig iron slag, which is a byproduct generated in the steel making process. The purpose of this research is to solve the problems of surface soil by improving the strength and durability of foundation soil such as soil loss, settlement, sinkhole, etc. by recycling pig iron slag from disused or landfilled steelworks. For this purpose, the possibility of using pig iron slag as a solidification soil was evaluated by the compressive strength, elution test of harmful materials, permeability coefficient test. As a result of the compressive strength test, the values of the strength of the curing 28 days of the solidified soil having the solidification agent mixing ratio of 12% were found to be 0.93, 0.96 and 1.3 MPa, respectively, satisfying the required strength value of 1 MPa, In the case of permeability coefficients, the minimum values were $4.1{\times}10^{-8}$, $7.0{\times}10^{-7}$, and $1.7{\times}10^{-7}cm/sec$, respectively, at the solidification agent mixing rate of 12%. In addition, as a result of the elution test of harmful materials, a small amount was detected in the item of hexavalent chromium but satisfied the inclusion criteria, and in the remaining items, heavy metals were not eluted.

• Journal of Soil and Groundwater Environment
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• v.17 no.3
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• pp.1-9
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• 2012

According to the agreement on WTO/TBT, we are under the situation to adopt international standard (ISO standard) as a national standard if it exists. However, in case of environmental area, it is a domestic legal obligation to use Korean environmental standard method(KESM) for analyzing various contaminants. Therefore it is necessary to assess the comparability between KEM and ISO standard prior to apply ISO standard to soil conservation law in Korea. The main purpose of this study is to assess the comparability of both methods for analyzing heavy metals in soil. We looked over various aspects like pre-treatment, calibration curve range, detection wavelength, soil organic matter content and so on. Apparently, the procedure of both methods is almost same. However in details, both methods are different in stationary time before aqua-regia extraction using reflux system, calibration curve range for Cu, Pb, Ni and measuring wavelength for Pb. According to the results of comparison test, the results were significantly different when the different calibration range was used. In case that all the extracts independent of methods were reanalyzed with the same calibration range of each method, both methods showed statistically same results. Other conditions like different stationary time, measuring wavelength of AAS and soil organic matter content did not have any influence on the analytical result. Therefore, we suggest to extend the calibration curve range to 0~8 mg/L which is used in KS I ISO standard(Korean standard related with environment which is translation version of ISO standard without any technical change). In case of $Cr^{6+}$, the results showed no significant differences between two methods even though the pretreatment, instrumentation and other analysis conditions were different. In addition to UV/Visble spectrometry of KESM for soil contamination, we suggest to adopt ion chromatography of ISO 15192(US EPA method 7199) for analyzing $Cr^{6+}$ with the consideration of laboratory work efficiency.

• Journal of the Korean GEO-environmental Society
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• v.11 no.3
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• pp.5-16
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• 2010

Groundwater quality monitoring wells, which is over 2,000 in South Korea, were managed to observe groundwater quality since the early 1990s. Groundwater was sampled and analyzed biannually from 781 monitoring wells located in the areas with a high possibility of pollution. The average concentrations of cyanide, mercury, phenols, hexavalent chromium, trichloroethylene, tetrachloroethylen, and 1.1.1-trichloroethane for 12 years' data of detected cases were above the groundwater quality standard, but the average concentrations of the general quality items such as pH, electric conductivity, nitrate-nitrogen, and chloride, are below the standard. To compare a quality trend for each land-use type of the monitoring site, Sen's method is used for four quality items; chloride, nitrate-nitrogen, pH, and electric conductivity. The upward trend for these items is remarkable in urbideareas and industrial complexes and this trend continues still strongly after 2001. The deviation in a trend slopes of monitoring wells becomes bigger in the mid-2000s. In conclusion, trend analysis using existing monitoring data cidebe effective to forecast the future water quality condition and the solid action to protect groundwater quality should be done in advance using a result of trend analysis.

• Journal of Korean Society of Forest Science
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• v.106 no.1
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• pp.70-76
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• 2017

Among the forest road pavement methods, the majority of current constructions utilize concrete pavements but it has disadvantages as follows: many cracked concrete pavements generated by the erosion of underlying soil layers, could not be used as forest roads in steep slope during winter, and cement contains hazardous chemicals (hexavalent chromium, etc.). In order to supplement the limitations of the use of concrete pavement, this study was conducted to investigate the operation process and cost, the strength and compaction of the experimental forest road pavement(85 m) utilizing eco-friendly solidification material at Goryeong-gun, Gyeongsangbuk-do. The work elements of experimental forest road paving were classified into: preparation, Roadbed excavation, Roadbed grading, subgrade compaction, form work, collection and selection of site soil, mixing site soil and eco-friendly solidification material, paving by eco-friendly solidification material, compaction by vibrating roller and curing. The result of economic analysis using construction cost shows that for concrete costs total to $38,681won/m^3$ while for the eco-friendly paving material it is $38,245won/m^3$. Thus the construction costs for concrete and the eco-friendly paving material are similar. And the results of the Schmidt Hammer test for strength analysis by curing period are 10.5-13.5 MPa for 7 days, 18.1-22.7 MPa for 14 days, and 20.8-23.0 MPa for 28 days.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.5
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• pp.727-733
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• 2011

A new Korean standard for the determination of Cr(VI) in soils has been officially published as ES 07408.1 in 2009. This analytical method is based on the hot alkaline digestion and colorimetric detection prescribed by U.S. EPA method 3060A and 7196A. The hot alkaline digestion accomplished using 0.28 M $Na_2CO_3$ and 0.5 M NaOH solution (pH 13.4) at $90{\sim}95^{\circ}C$ determines total Cr(VI) in soils extracting all forms of Cr(VI), including water-soluble, adsorbed, precipitated, and mineral-bound chromates. This aggressive alkaline digestion, however, proved to be problematic for certain soils which contain large amounts of soluble humic substances or active manganese oxides. Cr(III) could be oxidized to Cr(VI) by manganese oxides during the strong alkaline extraction, resulting in overestimation (positive error) of Cr(VI). In contrast, Cr(VI) reduction by dissolved humic matter or Fe(II) could occur during the neutralization and acidic colorimetric detection procedure, resulting in underestimation (negative error) of Cr(VI). Futhermore, dissolved humic matter hampered the colorimetric detection of Cr(VI) using UV/Vis spectrophotometer due to the strong coloration of the filtrate, resulting in overestimation (positive error) of Cr(VI). Without understanding the mechanisms of Cr(VI) and Cr(III) transformation during the analysis it could be difficult to operate the experiment in laboratory and to evaluate the Cr(VI) results. For this reason, in this paper we described the theoretical principles and limitations of Cr(VI) analysis and provided useful guidelines for laboratory work and Cr(VI) data analysis.