• Journal of the Korean Society of Food Science and Nutrition
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• v.40 no.2
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• pp.245-252
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• 2011

The combined effects of 10 kJ/$m^2$ ultraviolet-C (UV-C) with 50 ppm aqueous chlorine dioxide ($ClO_2$) on the qualities of red chicory and pak choi were examined. After the treatment, the samples were stored at $4{\pm}1^{\circ}C$ for 7 days. The combined treatment of $ClO_2$/UV-C reduced the initial populations of total aerobic bacteria in the red chicory and pak choi by 2.64 and 2.55 log CFU/g, respectively, compared to those of the control. Also, the populations of yeast and molds in the red chicory and pak choi by combined treatment were reduced by 2.41 and 2.00 log CFU/g, respectively. In addition, after 7 days of storage the total aerobic bacteria populations in the red chicory and pak choi were reduced to 3.71 and 3.93 log CFU/g, compared to 6.31 and 6.62 log CFU/g for the control, resulting in a significant decrease. Hunter L, a, and b values of red chicory and pak choi were not significantly different among the treatments. Non-thermal treatment caused a negligible change in sensory evaluation. These results suggest that the combined treatment of 50 ppm $ClO_2$ with 10 kJ/$m^2$ UV-C can be useful for maintaining the qualities of red chicory and pak choi.

• Korean Journal of Food Science and Technology
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• v.51 no.4
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• pp.404-409
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• 2019

This study was performed to determine the optimum conditions for the production of gaseous chlorine dioxide ($ClO_2$) from aqueous $ClO_2$ (HCl+$NaClO_2$). When 1 N HCl was reacted with various concentrations of $NaClO_2$ (50,000-500,000 mg/mL), the highest concentration (695 mg/L) of gaseous $ClO_2$ was obtained from the aqueous $ClO_2$ containing $100,000{\mu}g/mL$ $NaClO_2$. Next, the effects of relative humidity (RH; 43, 85, and 100%) and temperature (4, 12, and $25^{\circ}C$) on the production of gaseous $ClO_2$ were investigated. It was observed that the concentration of gaseous $ClO_2$ was increased as RH was decreased, or the temperature was increased. Finally, it was confirmed that the amount of gaseous $ClO_2$ was highly correlated ($R^2=0.9546-0.9992$) with the volume of aqueous $ClO_2$. The results of this study provide useful information for designing a sanitization program using gaseous $ClO_2$ under various environmental conditions.

• Computers and Concrete
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• v.20 no.2
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• pp.205-214
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• 2017

The Hydraulically driven test system and ${\Phi}100mm$ split Hopkinson pressure bar(SHPB) test device were employed to research the quasi-static and dynamic mechanical properties of concrete specimens which has been immersed for 60 days in sodium sulfate (group S1) and sodium chloride (group S2) solution, the evolution of their mass during corrosive period was explored at the same time, and the mechanism of performances lost was analyzed from the microscopic level by using scanning electron microscope. Results of the experimental indicated that: their law of mass both presents the trend of continuous rising during corrosive period, and it increases rapidly on the early days, the mass growth of group S1 and group S2 in first 7 days are 76.78% and 82.82% of their total increment respectively; during the corrosive period, the quasi-static compressive strength of specimens in two groups are significantly decreased, both of which present the trend of increase first and then decrease, the maximum growth rate of group S1 and group S2 are 7.52% and 12.71% respectively, but they are only 76.23% and 82.84% of specimens which under normal environment (group N) on day 60; after immersed for 60 days, there were different decrease to dynamic compressive strength and specific energy absorption, and so as their strain rate sensitivities. So the high salinity environment has a significant effect of weaken the quasi-static and dynamic mechanical performance of concrete.

• Journal of Environmental Health Sciences
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• v.18 no.2
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• pp.82-91
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• 1992

The examination of the pollutants originated from domestic sewage, industrial and agricutural activities the existences of some toxic heavy metals, organic matters and pathogenic microorganisms. A recent report of WHO brought out that such pollutants are in existence with above roughly 2,000 kinds of chemical substances and amongst them about 750 chemicals have been indentified by drinking water. And above 600 kinds of them are organic pollutants and in addition these include carcinogenic mutagenic and poisonous substances. This is not intended to embody a study of broad confined to various approaches on organic materials, and therefore will be THM produced on injection of chlorine at water filtration plant. To specify the relations between THM and factors having an effect upon THM such as TOC, Cl$_{2}$, Temperature, pH and reaction time, first of all the recovery ratio for analytical methods of THM (Head sapce, purge and trap, Liquid/ Liquid Extraction methods) was investigated. Provided that by using it,the correction coefficients are obtained, the accuracy of data might be able to be enhanced through analysis.The result of the experiments are given in the followings. 1) Among three kinds of analytical methods, recovery rate was higher in order of purge and trap Liquid/Liquid Extraction, Head space. There is no great difference in recovery rate among three methods. 2) The higher the concentration of TOC, the more the amount of THM. 3) The higher the reaction temperature, the more the amount of THM. 4) The longer the reaction time, the more the amount of THM. 5) The higher the pH, the more the amount of THM. 6) The higher the concectration of chlorine, the more the amount of THM.

• Korean Journal of Materials Research
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• v.28 no.1
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• pp.6-11
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• 2018

There are various manufacturing processes for pure $SiO_2$ that is used as abrasives, chemicals, filters, and glasses, and in metallurgy and optical industries. In the optical fiber industry, to produce $SiO_2$ preform, $SiCl_4$ is utilized as a raw material. However, the combustion reaction of $SiCl_4$ has caused critical environmental issues, such as ozone deficiency by chlorine compounds, the greenhouse effect by carbon dioxide and corrosive gas such as hydrochloric acid. Thus, finding an alternative source that does not have those environmental issues is important for the future. Octamethylcyclotetrasiloxane (OMCTS or D4) as a chlorine free source is recently promising candidate for the $SiO_2$ preform formation. In this study, we first conducted a vaporizer design to vaporize the OMCTS. The vaporizer for the OMCTS vaporization was produced on the basis of the results of the vaporizer design. The size of the primary particle of the $SiO_2$ formed by OMCTS was less than 100 nm. X-ray diffraction patterns of the $SiO_2$ indicated an amorphous phase. Fourier-transform infrared spectroscopy analysis revealed the Si-O-Si bond without the -OH group.

• Fire Science and Engineering
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• v.17 no.3
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• pp.61-73
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• 2003

Most of the accidents occurred from the chemical plants are related to the catastrophic gas release events when the large amount of toxic materials is leaked from its storage tank or transmitting pipe lines. In this case, the greatest concerns are how the spreading behaviors of leakages are depended on the ambient conditions such as air stability and other environmental factors. Hence, we have focused on the risk assessments and consequential analysis for chlorine as an illustrative example. As appeared in the result, Fire & Explosion Index depicted it a bit dangerous with presenting the comprehensive degrees of hazard 90.7. And as a result of Phast6.0/ALOHA, the trends of each scenario appeared considerably identical although there are some differences in the resulting effects according to the input data for the Gas Model. The consequence analysis is performed numerically based on the dense gas mode. In the future, using more correct input data, material properties, and topographical configuration, the method of this research will be useful for the guideline of the risk assessment when the release of toxicants breaks out.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.3
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• pp.143-152
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• 2014

In this study, the sensor response and sensitivity is experimented and analyzed quantitatively by the line numbers of chlorine ion reaction type corrosion sensor that is developed. The sensor response of the developed corrosion sensor is verified with properties of chlorine ion. The multilineal sensor is shown a large resistance change more than the single line sensor by damage of the sensor. And, the resistance change of sensor is as large as high concentration of NaCl aqueous solution, the sensitivity of multilineal sensor is higher than single line sensor's, and the depth of sensor's location is as large as the increasing of resistance change time (cycle). These results suggest that, the developed corrosion sensor could sense corrosion reaction, sensor sensitivity and change of resistance for chloride ion. Especially, It was judged that 7 line sensor was the most superior for monitoring chloride ion immigration into concrete.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.12
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• pp.685-688
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• 2017

Using ALOHA and PHAST Program, it was modeled assuming the leakage accident scenarios of chlorine which is designated as accident preparation chemical in chemical control act. End-point distances corresponding to ERPG-2 concentrations were calculated while varying annual mean temperature, wind speed, humidity, and atmospheric stability. The calculated endpoint distance values were compared and the correlation with each meteorological factor was analyzed. And we also investigated strengths and weaknesses of ALOHA and PHAST. The results show that ALOHA has little or no correlation with annual average temperature, humidity and it has a large correlation with wind speed and atmospheric stability. In the case of PHAST, the end-point distances were correlated with all the meteorological factors such as average annual temperature, wind speed, humidity, and atmospheric stability, Among them, the effect of atmospheric stability were the largest.

• Journal of Power System Engineering
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• v.22 no.1
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• pp.79-86
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• 2018

Many countries have conducted extensive studies for biomass co-firing to enhance the durability of reactor on high-temperature corrosion. However, due to the complicated mechanisms of biomass co-firing, there have been limitations in accurately determining the current state of corrosion and predicting the potential risk of corrosion of power plant. In order to solve this issue, this study introduced Lab-scale corrosion system to analyze the corrosion characteristics of the A213 T91 material under the biomass co-firing conditions. The corrosion status of the samples was characterized using SEM/EDS analysis and mass loss measurement according to various biomass co-firing conditions such as corrosion temperature, $SO_2$ concentration, and corrosion time. As a result, the corrosion severity of A213 T91 material was gradually increased with the increase of $SO_2$ concentration in the reactor. When $SO_2$ concentration was changed from 0 ppm to 500 ppm, both corrosion severity and oxide layer thickness were proportionally increased by 15% and 130%, respectively. The minimum corrosion was observed when the corrosion temperature was $450^{\circ}C$. As the temperature was increased up to $650^{\circ}C$, the faster corrosion behavior of A213 T91 was observed. A213 T91 was observed to be more severely corroded by the effect of chlorine, resulting in faster corrosion rate and thicker oxide layer. Interestingly, corrosion resistance of A213 T91 tended to gradually decrease rather than increases as the oxide layer was formed. The results of this study is expected to provide necessary research data on boiler corrosion in biomass co-firing power plants.

• Korean Journal of Agricultural Science
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• v.47 no.3
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• pp.415-424
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• 2020

This study investigated the effects of an ethylene scrubber (ES) with a micro-perforated polypropylene (MP-PP, 30 ㎛) or a high density polyethylene (MP-HDPE, 30 ㎛) film liner for the export carton packaging box in 'Campbell Early' grapes. Rachis browning was highest in the untreated group, followed by MP-PP and MP-HDPE for 14 days of simulated marketing at 20℃. The combination treatment of ES with the film liners showed a partial inhibition of the rachis browning regardless of the film liners. The effects of an alcohol releaser (AR) sachet or chlorine dioxide (CD) diffuser co-packaging were also investigated in the 'Campbell Early' grapes packed with the MP-HDPE (40 × 99 pin hole·m^-2) film liner. The CD 1 g treatment showed a very limited weight loss of 1.1%, which was significantly lower than the 4.7% of the untreated control after 14 days of simulation marketing at 20℃. The berry shatter was 0.7% for the MP-HDPE + CD 1 g treatment and 1.8% for the MP-HDPE + CD 5 g treatment on the 10th day of the simulated marketing, which was significantly lower than the 8.9% of the control. The stem browning was significant suppressed until the 10th day of the simulated marketing. In particular, the CD 1 g treatment in combination with the MP-HDPE showed a low rachis and pedicel browning index of 2.0, which is 50% and 40% lower than that of the untreated control and the MP-HDPE single treatment, respectively. In addition, the CD 1 g treatment group showed a higher decay reduction effect than the CD 5 g treatment group, which caused high concentration damage.