• Title/Summary/Keyword: Chlorides

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The Performance and Application of Repair System for the Exterior Wall According to the Durability Improvement in the RC Structure (Part1. Theoretical approach to the repair technic) (내구성 향상을 고려한 R.C조 외벽 보수 시스템의 성능과 그 활용 (제1보 : 열화 요인별 외벽 보수기술))

  • Kwon, Young-Jin;Kim, Chul-Ho;Kwak, Young-Jun;Park, Deuk-Kon;Choi, Long
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.134-138
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    • 1995
  • The reinforced concrcte structure were once belicved to have permanent durability. However, it is now spoiled by durability failure caused by the corrosion of embeded steel reingorcement carbonation. alkali-aggregate reaction and salt attack Recently. salt damage has been also spreading. Salt damage is found in concrete structures built using seasands or certain admixtures containing calcium chlorides and in coastal structures frequently caught in seawater spray or blown by seawind It is the aim of this study to investigate the performance and application of new repair system for the exterior wall according to the durability improvement in the RC structures.

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Probabilistic time-dependent sensitivity analysis of HPC bridge deck exposed to chlorides

  • Ghosh, Pratanu;Konecny, Petr;Lehner, Petr;Tikalsky, Paul J.
    • Computers and Concrete
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    • v.19 no.3
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    • pp.305-313
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    • 2017
  • A robust finite element based reinforced concrete bridge deck corrosion initiation model is applied for time-dependent probabilistic sensitivity analysis. The model is focused on uncertainties in the governing parameters that include variation of high performance concrete (HPC) diffusion coefficients, concrete cover depth, surface chloride concentration, holidays in reinforcements, coatings and critical chloride threshold level in several steel reinforcements. The corrosion initiation risk is expressed in the form of probability over intended life span of the bridge deck. Conducted study shows the time-dependent sensitivity analysis to evaluate the significance of governing parameters on chloride ingress rate, various steel reinforcement protection and the corrosion initiation likelihood. Results from this probabilistic analysis provide better insight into the effect of input parameters variation on the estimate of the corrosion initiation risk for the design of concrete structures in harsh chloride environments.

Synthesis of Novel Pyrazolylquinoxalines (새로운 Pyrazolylquinoxaline류의 합성)

  • Kim, Ho Sik;Kwag, Sam Tag
    • Journal of the Korean Chemical Society
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    • v.44 no.3
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    • pp.229-236
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    • 2000
  • The reaction of 6-chloro-2-hydrazinoquinoxaline 4.oxide(10) with acetylacetone or dibenzoylmethane gave 6-chloro-2-(3,5-disubstituted pyrazol-1-yl)quinoxaline 4-oxides (11) through the intramolecular·cyclization.The chlorination of compound 11 with phosphoryl chloride afforded 3,6-dichloro-2-(3,5-disubstituted pyrazol-1-yl)quinoxalines (12), whose reaction with hydrazine hydrate provided 6-chloro-3-hydrazinodehydes, benzenesulfonyl chloride, substituted benzoyl chlohdes or acyl chlorides gave novel pyrazolylquinoxalines (14-17).

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Synthesis of Several New Isoxazole, Imidazo[1, 2-a]pyridine, Imidazo[1, 2-a]pyrimidine, Benzoxadiazine and Benzothiazine Derivatives from Hydroximoyl Halides

  • Abdelhamid, Abdou O.;Abdou, Sadek E.;Mahgoub, Sayed A.
    • Archives of Pharmacal Research
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    • v.15 no.4
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    • pp.317-321
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    • 1992
  • Furoyldroximoyl chloride 3d reacted with 2-aminopyridine, 2-aminopyrimidine. O-aminophenol, O-phenylenediamine and aminothiophenol to afford imidazo [1, 2-a]pyridine 6. imidazo[1, 2-a]pyrimidine 8, benzoxadiazine 10, nitrosobenzopyrizine 13a and nitrosobenzothiazine 13b, respectively. Isoxazoline 18 and pyrrolidino[3, 4-d]isoxazolin-4, 6-dione derivatives 19a and 19b obtained by the reaction of 3 with acrylonitrile and N-arylmaleimide. Hydroximoyl chloride 3 reacted with thiophenol and sodium benzene-sulfinate to yield furylglyoxaloxime 16a and 16b, respectively. Hydroximoyl chloride 3 reacted also with some active methylene compound to give isoxazole derivatives 20-23, respectively.

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On the Development of Monitoring Technique for Rebar Corrosion in Concrete using Sensor (부식센서를 이용한 콘크리트 철근부식 모니터링 기술 개발 연구)

  • 김용철;장상엽;조용범;이한승;신성우
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.163-168
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    • 2003
  • By introducing corrosion monitoring techniques, steel corrosion in concrete may be evaluated at early stage. The monitoring probes in concrete detect the causes (chlorides and $CO_2$) of steel corrosion by being cast into the concrete or diffusing in from the outside. Various systems for corrosion monitoring in concrete are reviewed in this paper. These techniques are classified according to monitoring purposes such as corrosion potential or corrosion rate of steel and causes for corrosion etc.. Today, special interests are converged in development of corrosion sensor as a monitoring method of new concept.

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Studies on the Treatment of Weight Loss of PET Fibers by Alkyldimethylbenzylammonium Chlorides (알킬디메틸벤질암모늄 클로라이드에 의한 PET섬유의 감량가공에 관한 연구)

  • Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.2
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    • pp.29-33
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    • 1993
  • n-Octyldimethylbenzylammonium chloride, dodecyldimethylbenzylammonium chloride, and octadecyldimethylbenzylammonium chloride were synthesized to be used as the accelerating weight loss agent. These synthesized compounds were used for the weight loss treatment of PET textile with sodium hydroxide. From the treatments, it was found that the lower carbon number of high alkyl group existed in quaternary ammonium salts, the better effect of weight loss was acquired. The proper concentration of accelerating weight loss agent was $8{\sim}10g/l$, the proper treatment time was $60{\sim}90$ minutes, the proper treating bath ratio was 1 : 50. It is proved that n-octyldimethylbenzylammonium chloride and dodecyldimethylbenzylammonium chloride are good accelerating weight loss agent.

Synthesis of N-(disubstituted styryl) Carboxamides (N-(2치환스티릴) 카르복사미드류의 합성)

  • Kim, Soon-Ok;Hong, Sa-Mi;Lee, Seon-Hwa
    • YAKHAK HOEJI
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    • v.36 no.5
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    • pp.433-439
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    • 1992
  • For the synthesis of tuberin derivatives, N-(disubstituted styryl) carboxamides, the series of cinnamic acids were transformed through chlorides, azides to isocyanates. And then isocyanates were reduced separately by Dibal and Grignard reagent. As a result of antimicrobial susceptibility test, N-(3,4-dichlorostyryl) formamide and N-(3,4-dichlorostyrl) acetamide showed comparatively large activity against some bacteria that is, MIC was respectively 50 ppm, $6.25{\sim}50\;ppm$. MIC of other derivatives was similiar to that of tuberin, about 100.

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