Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Nucleophilic Displacement at Sulfur Center (II). Solvolysis of Benzenesulfonyl Chloride in Acetone-Water Mixtures

유황의 친핵치환반응 (제2보). 아세톤-물 혼합용매에서의 염화벤젠슬포닐의 가용매반응

  • Wang Ki Kim (Department of Chemistry, College of Liberal Arts and Sciences,Chonnam National University) ;
  • Ik Choon Lee (Department of Chemistry, College of Science, Inha University)
  • 김왕기 (전남대학교 문리과대학 화학과) ;
  • 이익춘 (전남대학교 문리과대학 화학과)
  • Published : 1973.06.30
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Abstract

Kinetic studies of p-substituted benzenesulfonyl chlorides have been carried out in 10~50 wt. % water-acetone mixtures. Results show that $S_N2$

10~50wt. %아세톤-물 혼합 용매 속에서의 benzenesulfonyl chloride 치환체들의 가용매반응을 속도론적으로 연구한 결과 $S_N2$ 성격이 지배적이었으며 general base-catalyzed반응이 일어나고 있음을 알았다.

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References

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