• Title/Summary/Keyword: Chloride Ion Penetration

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Corrosion-Inhibition and Durability of Polymer-Modified Mortars Using Bisphenol A and F Type Epoxy Resin with Calumite (비스페놀 A 및 F형 에폭시수지와 칼루마이트를 병용한 폴리머 시멘트 모르타르의 방청성 및 내구성)

  • Kim, Joo-Young;Kim, Wan-Ki
    • Journal of the Korea Concrete Institute
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    • v.26 no.4
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    • pp.517-524
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    • 2014
  • Nitrite-Type hydrocalumite (calumite) is a material that can adsorb chloride ions ($Cl^-$) that cause corrosion of reinforce bars and liberate the nitrite ions ($NO_2{^-}$) that inhibit corrosion in reinforced concrete. In this study, polymer-modified mortars using two types of epoxy resin with calumite are prepared with various polymer binder-ratios of 0, 5, 10, 15, 20% and calumite contents of 0, 5%. The specimens are tested for chloride ion penetration, carbonation, drying shrinkage and corrosion inhibition. As a result, the chloride ion penetration and carbonation depth of PMM using epoxy resin somewhat increases with increasing calumite contents, but those remarkably decreases depending on the polymer-binder ratios. The 28-d drying shrinkage shows a tendency to decrease with increasing polymer-binder ratio and calumite content. Unmodified mortars with calumite content of 5% did not satisfy quality requirement by KS. However, it was satisfied with KS requirement by the modification of epoxy resin in cement mortar. On the whole, the carbonation and chloride ion penetration depth of epoxy-modified mortars with calumite is considerably improved with an increase in the polymer-binder ratio regardless of the calumite content, and is remarkably improved over unmodified mortar. And, the replacement of the portland cement with the calumite has a marked effect in the corrosion-inhibiting property of the epoxy-modified mortars.

A Study on the Cause Analysis of Human Error for of Railway Accidents using HEAR Analysis Methods (HEAR 분석방법을 이용한 철도사고의 인적오류 원인분석 연구)

  • Lee, Yong Man;Park, Min Kyu;Shin, Tack Hyun
    • Journal of the Korea Safety Management & Science
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    • v.15 no.4
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    • pp.73-80
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    • 2013
  • Because the damages of corrosion resulting from the chloride ion are very serious, many research studies have been performed to measure the penetration depth of the chloride ion. However, there is a problem with data selection obtained from collection during experiments. In this study, it appears that the collected data are not conformed to a normal distribution. The result of this study will play a very important role, as a first step for the development and construction of a forecasting system to help determine a reliable service lifetime of marine structures.

Development and Application of Low Permeable Concrete for Underground Structures (지하구조물을 위한 수밀콘크리트의 개발 및 실용화)

  • Paik, S.H.;Park, S.S.;Park, J.Y.;Paik, W.J.;Um, T.S.;Choi, L.
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.259-262
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    • 1999
  • In underground reinforced concrete structures, such as drainage structure, water and chloride ion penetrated into concrete through the cracks of concrete and its permeable property, cause the corrosion of reinforcing steel bar, which accelerates the expansive cracks and deterioration of concrete. It is necessary to control those deterioration of underground structure by improving its permeability and durability through the reasonable solutions in design, construction and materials. In the present study, fly ash concrete, which has good material properties in long-term period, was compared and studied with plain concrete using ordinary portland cement in terms of fundamental mechanical properties, permeability, drying shrinkage and durability. Also, the mix design and field test of low permeable concrete using fly ash were performed. From this study, fly ash concrete can control the penetration of water and chloride ion effectively by forming dense micro-structure of concrete. Therefore, fly ash concrete may increase the long-term function, performance and serviceability of underground structures.

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A Study on Chloride ion Diffusion in Cracked Concrete (균열이 발생한 콘크리트에서의 염화물 이온 확산에 관한 연구)

  • 배상운;박상순;변근주;송하원
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.677-682
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    • 2001
  • In this study, a method to evaluate diffusion coefficient of chloride ion in cracked concrete is proposed. For cracked concrete having either anisotropic or isotropic crack network, each crack of saturated concrete is considered as a V shape crack, and an effective diffusion coefficient is expressed with diffusion coefficients of cracked part and noncracked part and a so-called crack spacing factor. A comparison with experimental results shows that the diffusion coefficient for cracked concrete is accurately predicted by the effective diffusion coefficient. Prediction results also show that the cracks in concrete markedly change the diffusion properties and accelerate penetration of drifting species. The method in this paper can be effectively used to consider the effect of cracks on concrete diffusion coefficient of cracked concrete.

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The Assessment of Chliride Attack of Concrete Structure in Marine Environment (해양환경하에 있는 콘크리트 구조물의 염해에 대한 고찰)

  • 문한영;김성수;류재석;김성섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.04a
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    • pp.83-88
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    • 1996
  • Reinforced-concrete structures built on the seashore or in seawater are damaged from flying-salt of chloride ion in the seawater. Recently many bridges are being constructed under marine enviornment and there are many serious problems of chlofide attack owing to penetration of chloride ion. And up to now it has not only so little a seatch about damage from flying-salt and seawater but also little systematic study outcome about steel corrosion. In this study we investigate the concrete deterioration and steel corrosion of RC bridges on the seashore. Environmental conditions are investigated, and compressive strength, carbonation depth and steel-corrosion degree are measured.

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Validation on Reliability of Data for Development of Forecasting System of Service Lifetime in Marine Structures (해양구조물 수명예측 시스템 구축을 위한 데이터 신뢰성 검증)

  • Leem, Young-Moon;Yang, Eun-Ik;Hwang, Young-Seob
    • Journal of the Korea Safety Management & Science
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    • v.9 no.2
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    • pp.85-95
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    • 2007
  • Because the damages of corrosion resulting from the chloride ion are very serious, many research studies have been performed to measure the penetration depth of the chloride ion. However, there is a problem with data selection obtained from collection during experiments. After careful study, it appears that the collected data are not conformed to a normal distribution. The result of this study will play a very important role, as a first step for the development and construction of a forecasting system to help determine a reliable service lifetime of marine structures.

Improvement of bond strength and durability of concrete incorporating high volumes of class F fly ash

  • Wu, Chung-Hao;Chen, Chien-Jung;Lin, Yu-Feng;Lin, Shu-Ken
    • Advances in concrete construction
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    • v.12 no.5
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    • pp.367-375
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    • 2021
  • This study experimentally investigated the improvement of bond strength and durability of concrete containing high volume fly ash. Concrete mixtures made with 0%, 25% and 60% replacement of cement with class F fly ash were prepared. Water-binder ratios ranged from 0.28 to 0.72. The compressive, flexural and pullout bond strength, the resistance to chloride-ion penetration, and the water permeability of concrete were measured and presented. Test results indicate that except for the concretes at early ages, the mechanical properties, bond strength, and the durability-related chloride-ion permeability and water permeability of concrete containing high volume (60% cement replacement) fly ash were obviously superior to the concrete without fly ash at later ages of beyond 56 days. The enhanced bond strength for the high volume fly-ash concrete either with or without steel confinement is a significant finding which might be valuable for the structural application.

An Experimental Study on the Diffusion of Chloride Ion in Mortar using Mineral Admixtures (혼화재 사용 모르터의 염분 확산에 대한 실험적 연구)

  • 문한영;김성수;류재석
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.04a
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    • pp.181-186
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    • 1994
  • The steel in concrete structures under the environment of seawater easily corrode as the seawater penetrate into concrete. The purpose of this study is to analysis the properties of chloride diffusion in mortar using mineral admixtures, as a part of study to examine the chloride penetration of concrete. The results show that the chloride diffusion in mortar increased with higher water-cement ratio. In the case of mortar using mineral admixtures the scope of diffusion coefficient$(\times10^{-8}cm^2/sec)$increased SF20(0.9), SG60(3.3), FA20(3.9), and OC(6.1) in order at the same water-cement ratio 50%.

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Chloride Diffusion in Mortars - Effect of the Use of Limestone Sand Part I: Migration Test

  • Akrout, Khaoula;Ltifi, Mounir;Ouezdou, Mongi Ben
    • International Journal of Concrete Structures and Materials
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    • v.4 no.2
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    • pp.105-108
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    • 2010
  • In order to determine the effect of the use of limestone sand on chloride ion ingress in mortar, specimens were cast with two different sands: siliceous sand (used as reference) and limestone crushed sand (used for this study). To compare and assess the resistance of this mortar to chloride penetration, two different diffusions tests were employed: slow migration and rapid migration (AASHTO test). In this study, calculation of the effective diffusion coefficient is proposed using a model based on Nernst. Planck equation. The diffusion coefficients from each sample were compared. The results for all tests show that the diffusion coefficients for siliceous sand mortar are larger than those obtained with limestone sand. It appears also that the diffusion coefficient varies as a function of the W/C ratio.

Investigation on the Properties of Mortar U sing Chloride Attack Protection Agent (염해방지제 사용에 따른 모르타르의 특성 검토)

  • Bae, Jun-Young;Kim, Jong-Back;Lee, Keon-Ho;Cho, Sung-Hyun;Kim, Kyoung-Min;Park, Sang-Joon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.297-298
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    • 2009
  • In this paper, it was to investigate different types of mortar properties using a chloride attack protection agent by evaluating mixing ratio of this particular agent, including 3% increments. The results showed that the compressive strength and chloride ion penetration resistance of mortar by using chloride attack protection agent were improved than non-added mortar.

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