• Title/Summary/Keyword: Chloride Diffusion Coefficient

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Evaluation of Chloride Ion Diffusion Coefficient of Coating Materials based on Halo-philic Bacteria (호염성 박테리아 기반 코팅재의 염소이온 확산계수 평가)

  • Yoon, Hyuun-Sub;Lee, Jae-Wuk;Yang, Keun-Hyeok
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.159-160
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    • 2020
  • This study examined the potentials for developing a biological coating material with high chloride resistance. The bacteria strains isolated were Halomonas alkaliphile, Halomonas venusta, and Sulfidobacter mediterraneus. Test results revealed that the developed approach is very promising in reducing the chloride ion diffusion coefficient of concrete.

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Prediction of the Durability Life for RC Structures through the Analyzing Chloride Diffusion Coefficient of the Establish Data (기존 자료를 통한 염소이온 확산계수 분석 및 철근콘크리트 구조물의 염해 수명예측)

  • Lee, Woo-Jin;Lee, Sung-Bok;Lee, Han-Seung;Ryu, Jae-Jun;Yun, Byung-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.846-849
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    • 2004
  • It is important to decide the precise chloride diffusion coefficient in order to predict the durability plan of concrete structure chloride and prediction of remaining lifetime. However, the inland references are limited to the rapid test in laboratory. The purpose of this study is to examine and analyze the established data, which are restricted by chloride diffusion coefficient, and to examine the prediction of the concrete structure durability by an FEM interpretation and the chloride diffusion coefficient as a variable.

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Characteristic of Chloride ion Diffusion in Mortar According to the Substitution Ratios of the Additive (혼합재 치환율에 따른 모르타르의 염소이온 확산 특성)

  • 양승규;정연식;이웅종;유재상;이종열
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.17-22
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    • 2002
  • Chloride ions have a tendency to penetrate into concrete and proceed the corrosion by depassivating rebar surface. Thus the deteriorated concrete is subject to experience severe degrading of durability under marine environment. Physical properties of mortar, such as, compressive strength and penetration depth of chloride ion were investigated. And to investigate the effect of containing SG, FA in mortar, the diffusion coefficient of chloride was measured through an electro - migration test. The diffusion coefficient of chloride was decreased with the increase of replacement ratio of SG compared with plain specimen.

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Numerical technique for chloride ingress with cover concrete property and time effect

  • Lee, Bang Yeon;Ismail, Mohamed A.;Kim, Hyeok-Jung;Yoo, Sung-Won;Kwon, Seung-Jun
    • Computers and Concrete
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    • v.20 no.2
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    • pp.185-196
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    • 2017
  • Durability problems initiated from steel corrosion are unseen but critical issues, so that many researches are focused on chloride penetration evaluation. Even if RC (Reinforced Concrete) structures are exposed to normal environment, chloride ingress varies with concrete surface conditions and exposed period. This paper presents an analysis technique for chloride behavior evaluation considering time effect on diffusion and surface conditions assumed as double-layered system. For evaluation of deteriorated surface condition, field investigation was performed for concrete pavement exposed to deicing agent for 18 years. In order to consider enhanced surface concrete, chloride profiles in surface-impregnated concretes exposed to chloride attack for 2 years from previous research were investigated. Through reverse analysis, effectively deteriorated/enhanced depth of surface and the related reduced/enlarged diffusion coefficient in the depth are simulated. The proposed analysis technique was evaluated to handle the chloride behavior more accurately considering changes of chloride ingress within surface layer and decreased diffusion coefficient with time. For the concrete surface exposed to deicing agent, the deteriorated depth and enlarged diffusion coefficient are evaluated to be 12.5~15.0 mm and 200% increasing diffusion coefficient, respectively. The results in concrete containing enhanced cover show 10.0~12.5 mm of impregnated depth and 85% reduction of chloride diffusion in tidal and submerged conditions.

A Study on the Chloride Ion Diffusion Coefficient of Concrete by Submergence in Salt Water (침적시험에 의한 콘크리트의 염소이온 확산계수 평가)

  • 김동석;양승규;정연식;유재상;이종열;본간건일
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.297-300
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    • 2003
  • A chloride is an important deteriorating factor which governs the durability of the reinforced-concrete structures under marine environments. Also, the main penetration mechanism of chloride ion into concrete is a diffusion phenomenon. In this study, It is evaluated the diffusion coefficient of chloride ion in non-steady state by Fick's second law. Submergence method in salt water carried out in this experiment. Two types of cement which is different in mineral composition were used. In addition, the effect of mineral admixtures of blast-furnace slag and meta-kaolin was studied. In conclusion, the diffusion coefficient of chloride ion is much affected according to cement type and mineral admixtures, also, it is proved that meta-kaolin as well as blast-furnace slag is effective in preventing penetration of chloride ion.

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Accelerated Chloride Diffusion Properties of Portland Cement Concrete (포틀랜드계 시멘트 콘크리트의 촉진 염화물 확산 특성)

  • 김진철;이찬영;이용은
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.775-778
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    • 1999
  • Accelerated chloride diffusion tests were carried out to estimate the chloride diffusion coefficient of concrete using ordinary portland cement, low heat belite-rich portland cement, and sulphate resistant portland cement. Concrete using low heat belite-rich portland cement showed a high diffusion coefficient due to delayed hydration of low heat belite rich portland cement, while the diffusion coefficients of concrete using sulphate resistant portland cement and ordinary portland cement were low.

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Diffusion of Chloride Ions in Limestone Powder Concrete

  • Moon Han-Young;Jung Ho-Seop;Kim Jong-Pil
    • Journal of the Korea Concrete Institute
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    • v.16 no.6 s.84
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    • pp.859-865
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    • 2004
  • In this study, the diffusion of chloride ions in cement concrete made with and without the limestone powder was investigated. In order to study the effect of the limestone powder, all mixtures were prepared at a fixed water-cementitious ratio (0.45). From the experimental results, the setting time of limestone powder concrete is faster than that of control concrete, and compressive strength of all specimens decreased with increasing replacement ratio of limestone powders. The diffusion properties of limestone powder concretes indicated a trend increasing with curing period. LSA10 and LSA20 concretes, the diffusion coefficient was smaller than that of control concrete. The addition of $10-20\%$ limestone powder reduces the diffusion coefficient of chloride ions, irrespective of fineness levels of limestone powder.

Chloride Diffusion in Mortars - Effect of the Use of Limestone Sand Part I: Migration Test

  • Akrout, Khaoula;Ltifi, Mounir;Ouezdou, Mongi Ben
    • International Journal of Concrete Structures and Materials
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    • v.4 no.2
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    • pp.105-108
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    • 2010
  • In order to determine the effect of the use of limestone sand on chloride ion ingress in mortar, specimens were cast with two different sands: siliceous sand (used as reference) and limestone crushed sand (used for this study). To compare and assess the resistance of this mortar to chloride penetration, two different diffusions tests were employed: slow migration and rapid migration (AASHTO test). In this study, calculation of the effective diffusion coefficient is proposed using a model based on Nernst. Planck equation. The diffusion coefficients from each sample were compared. The results for all tests show that the diffusion coefficients for siliceous sand mortar are larger than those obtained with limestone sand. It appears also that the diffusion coefficient varies as a function of the W/C ratio.

Chloride Diffusion Coefficient Model Considering the Initiation Time of Exposure to Chloride Environment (염소이온 노출개시시기를 고려한 기존 확산계수 모델 수정제안)

  • Kim, Ki-Hyun;Cha, Soo-Won
    • Journal of the Korea Concrete Institute
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    • v.21 no.3
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    • pp.377-386
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    • 2009
  • A reference diffusion coefficient model from ACI life-365 is drawn from test results by NT build 443. This test method gives a time-averaged diffusion coefficient during immersion period, thus the ACI model uses the time-averaged diffusion coefficient as a reference value. ACI model needs to be revised, considering the difference between the time-average value and reference value at specified time. In this study, firstly the analytic solutions of diffusion equation are derived considering the initiation time and period of exposure to chloride, and secondly the time-averaged diffusion coefficient from NT build 443 is converted into the diffusion coefficient at reference time. From this study, the reference diffusion coefficient of ACI model should be modified to be about 10% larger values than those of present ACI model. For convenient design of service life, previous relationship between the chloride diffusion coefficient from NT build 443 and that from NT build 492 is also modified. To compare the chloride diffusion coefficients of ACI and JCI models, the reference chloride diffusion coefficient with respect to the JCI model is drawn in the similar form of ACI model's, and service life prediction by ACI life-365 method is confirmed to give a conservative result.

On Probability Distribution of Chloride Diffusion Coefficient for Recycled Aggregate Concrete

  • Ying, Jingwei;Xiao, Jianzhuang;Meng, Qiujiang
    • International Journal of Concrete Structures and Materials
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    • v.10 no.1
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    • pp.61-73
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    • 2016
  • In predicating the probability distribution of chloride diffusion coefficient of recycled aggregate concrete ($D_{RAC}$), the morphological characteristics of three phases, i.e., the old attached mortar, the natural aggregate and the new mortar, should all be taken into account. The present paper attempts to develop a probability density evolution method (PDEM) to achieve this. After verifying the derived PDEM results with experimental results, the effects of old attached mortar to the $D_{RAC}$ are examined in a quantitative manner. It is found that (1) the variation of the attached mortar content is much sensitive to $D_{RAC}$; (2) given the probability distribution of the content and chloride diffusion coefficient of old mortar, the probability distribution of DRAC can be analysed based on the PDEM; and (3) the critical chloride diffusion coefficient at a certain assurance rate can be obtained by the PDEM. The analysis results of this investigation will be valuable to the durability design for RAC.