• Title/Summary/Keyword: Chitosan Treatment

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Physicochemical Characterization of PET Fabrics Treated with Chitosan after Exposure to $O_2$ Low Temperature Plasma - Especially by KES evaluation - (저온 플라즈마 처리한 폴리에스테르 직물의 키토산 처리에 따른 물리화학적 특성변화 -KES평가를 중심으로-)

  • Koo Kang;Kim Sam Soo;Park Young Mi;Yu Jae Yeong;Koo Bon Shik;Yoo Seung Chun
    • Textile Coloration and Finishing
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    • v.17 no.5 s.84
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    • pp.26-36
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    • 2005
  • This study was carried to evaluate mechanical characteristics of Poly(ethylene terephthalate) fabrics (by Kawabata evaluation system(KES)) which was systematically treated with $O_2$ low temperature plasma and chitosan acetate solution. Furthermore, surface structure was investigated by SEM, AFM, air permeability and wettability. Tensile energy(WT), shear rigidity(G) and surface roughness(MIU) properties calculated by KES-FB have increased with increasing plasma treatment time, while bending rigidity(G) and energy of compression(WC) value were decreased compared with those of the untreated. SEM photographs showed the identification of chitosan coating but did not confirm the plasma etching structure. Air permeability was decreased according to plasma treatment time with increasing concentrations of chitosan. The water absorption rate made rapid progress by chitosan treatment.

The Effect of Chitosan Treatment of Fabrics on the Natural Dyeing using Loess (키토산 처리포의 황토염색에 관한 연구)

  • Kwon, Min-Soo;Jeon, Dong-Won;Kim, Jong-Jun
    • Fashion & Textile Research Journal
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    • v.7 no.3
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    • pp.327-332
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    • 2005
  • The purpose of this study is to investigate the effect of chitosan treatment on the dyeing of cotton fabric specimens using loess as colorants. The wet pick up ratio of the chitosan acid solution, as well as the drying condition after the padding of the fabric specimens, was changed in order to study the loess uptake on the fabric. The average particle diameter of the loess was measured. Main components of the loess were $SiO_2$, $Al_2O_3$, and $Fe_2O_3$. By the chitosan treatment, the loess amount on the cotton fabric increased. 80% wet pick up ratio of the chitosan acid solution on the cotton fabric specimen allowed more stable and even adhesion of the loess on the fabric surface, compared to the cases of 100% and 120% wet pick up ratio.

The Use of Chitosan and Mordanting in the Dyeing of Alkali Treated PET Fabrics with Wood of Caesalpinia Sappan (알칼리 처리한 PET 직물의 소목염색에서 키토산 및 매염제의 사용)

  • Koo, Kang;Kim, Sam-Soo;Choe, Jong-Deok;Yu, Jae-Young;Park, Young-Mi
    • Textile Coloration and Finishing
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    • v.18 no.1
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    • pp.1-9
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    • 2006
  • Treatment of PET fabrics with alkali, chitosan and Al-mordanting has been carried out and the role of the chitosan coating in the dyeing process was clarified. The pre-treatment was effectively evaluated differences in dyeing behavior between its treated and untreated PET fabrics using wood of Caesalpinia sappan. The pre-treated on PET fabrics has been examined by SEM and evidence for the presence of chitosan sought using a air permeability test. Similar colour fastness by computer color matching(CCM) obtained on both untreated and pre-treated PET fabrics. The pre-treated PET was found to be of a deeper hue to that of its dyed untreated PET and, despite of its better colour depth, the wash fastness of the pre-treated dyeing was comparable to that of its dyed untreated PR. The application of chitosan or mordanting reveled that pre-treatment imparted to the PET additional functional groups that were available for coordination with the Brazilin.

A Study on the Dyeing of Chitosan treated Cotton and Nylon Fabrics - Caesalpinia sappan, Cochineal, Gardenia jasminoides - (키토산처리(處理) 면포(綿布)와 나일론포(布)의 염색성(染色性)에 관(觀)한 연구(硏究) - 소목(蘇木), 코치닐, 치자(梔子)를 중심(中心)으로 -)

  • Jeon, Dong-Won;Kim, Jong-Jun;Lee, Jung-Min;Shin, Hye-Sun
    • Journal of Fashion Business
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    • v.7 no.2
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    • pp.156-164
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    • 2003
  • It has been known that the natural colorants exhibit good dye-uptake toward cotton, silk, and wool fibers, while they do poorly toward synthetic fibers. This study utilizes the chitosan treatment in order to improve the dye-uptake for the natural fibers and to enable the synthetic fibers, whose dye-uptake levels are low, show better affinity toward the natural colorants. Since chitosan has $-NH_2$ group and -OH group in the structure, the dyeability of the fabric will be improved when the fabric is treated with the chitosan. Cotton fabric as one of the natural fiber fabrics and nylon fabric as one of the synthetic fiber fabrics were selected for this study. 1. In case of cotton fabric, the chiosan treatment takes effect for the Caesalpinia sappan and cochineal, resulting in remarkable ${\Delta}E$ increase after dyeing. Chitosan helps in developing dark shade by increasing the uptake of the Caesalpinia sappan and cochineal. It does not, however, participate in the developing of the specific color as does a metallic mordant. 2. In case of dyeing cotton fabric with Gardenia jasminoides, the effect of the treatment with mordant and chitosan is not very pronounced. It is thought that the Gardenia jasminoides uptake is accomplished in a direct manner in the cellulose chains without the aid of mordant. 3. Air-permeability is decreased when the non-mordanted and non-chitosan treated cotton fabric is dyed with Caesalpinia sappan, cochineal, and Gardenia jasminoides. 4. In case of nylon fabric, premordanting and chitosan treatments are not highly effective in promoting the dye-uptake.

Effects of Chitosan on Wound Healing in Monkeys (원숭이에서 피부 창상 치유에 대한 키토산의 효과)

  • Byun, Hong-Seob;Lee, Soo-Jin;Lee, Jae-Il;Kim, Moo-Kang;Shin, Nam-Shik;Kim, Myung-Cheol
    • Journal of Veterinary Clinics
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    • v.30 no.4
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    • pp.241-246
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    • 2013
  • The objective of this study was to investigate the effects of implanted chitosan applied to surgically created wound in Japanese Macaque monkeys. 4 healthy Japanese Macaque monkeys were used. A 4 cm straight skin incision was made and undermined skin ($4{\times}4cm$) over on the 2 monkeys both sides of the dorsal midline, and a 4 cm circular skin incision was made on 2 monkeys both sides of the dorsal midline. One wound (left side) was implanted 1 mg (straight incision) and daily 0.2 mg (circular incision) of cotton type chitosan and the other wounds were treated with normal saline (3 ml) in monkeys. Each straight wound was closed with two interrupted sutures of 2-0 sutures. The monkey's circular skin incision is opened. At 14 days after initial wounding, each wound was taken for histological observations in monkeys. The inflammatory cells in the chitosan group are observed less than the control group, the collagen and the fibrin in the chitosan are observed more than the control group in monkeys. So the wound healing is moderately enhanced for chitosan treatment. The fibroblasts and the capillaries increased for chitosan treatment. The treatment of chitosan in wound is to promote healing.

STUDY ON THERMOSENSITIVITY OF CHITOSAN SCAFFOLD AND ON ITS EFFECTS ON FIBROBLAST PROLIFERATION IN CELL THERAPY FOR SOFT TISSUE AUGMENTATION (연조직 증강을 위한 세포치료 시 비계로서 키토산의 온도 감응성 및 섬유모세포의 증식에 미치는 영향에 관한 연구)

  • Kim, Jung-Ho;Choi, Jin-Young
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.35 no.3
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    • pp.146-152
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    • 2009
  • Traditional surgical method or injection using filler is performed for soft tissue augmentation. Surgical methods have disadvantage of surgical morbidity. Commercially available injectable materials have the disadvantages such as resorption, short-term effect. repeated application and hypersensitivity. Significant shortcoming of cell therapy using autologous fibroblasts is delay of treatment effect. Chitosan/${\beta}$-glycerol phosphate (GP) solution has thermosensitive property and allows sol-gel transition at physiologic pH and temperature. These properties may resolve the delay of treatment effect. The purposes of this study are to evaluate the viscosity and pH changes of chitosan/${\beta}$-GP solutions and to evaluate the effect of chitosan/${\beta}$-GP solution on fibroblast proliferation and production of collagen. We measured the viscosity and pH as function of temperature, of the solution containing 1:0.7, 1:0.75, 1:0.8 chitosan (1, 10, 100, 700 kDa) /${\beta}$-GP. Fibroblasts from ears of 5 rats were cultured in chitosan/${\beta}$-GP solutions for 3 weeks. Cell proliferation and collagen contents were measured every week with WST (water-soluble tetrazolium salt) assay and Collagen assay respectively. The Results are 1) Chitosan(100 kDa<)/${\beta}$-GP solution (1:0.75) showed sol-gel transition at physiologic pH and body temperature and injectable properties. It will enable to resolve the delay in treatment effect 2) Cell proliferation and total collagen contents of the control group were increased with time. However, these decreased after the 1st week in experimental group 3) Collagen contents in the experimental group are higher than that of control group. Chitosan/${\beta}$-GP solution may provide favorable conditions for cell function

Cochineal Printing Using Pretreated Fabrics with Chitosan (키토산이 전처리된 직물을 이용한 코치닐 날염)

  • Kim, Kyung-Sun;Jeon, Dong-Won
    • Journal of the Korean Society of Clothing and Textiles
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    • v.33 no.10
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    • pp.1644-1654
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    • 2009
  • The concentration of dye uptake and the fastness improved when cotton and silk fabrics were treated with chitosan, a natural polymer. In this study, the effect of chitosan treatment was reviewed after the printing of cotton and silk fabrics padded with chitosan. When the change of physical and mechanical properties of printed fabrics was reviewed (as the concentration of chitosan increased) the thickness and weight increased a little, and the air permeability increased significantly than those untreated with chitosan. The dye uptake increased, accompanying a darker color shade, and the wash fastness increased 1/2-1 grade. The analysis results of enlarged images of printed patterns indicated that the width and area deformations were minimal as the concentration of chitosan increased when compared to untreated fabrics. Therefore, the dyeability and pattern quality were excellent after printing the chitosan-treated cotton and silk fabrics with cochineal dyestuff.

Effects of Chitosan on the Normal and Cyclophosphamide-suppressed Primary Humoral Immune Response in Mice (Chitosan이 마우스의 정상 및 cyclophosphamide로 억제된 일차 체액성 면역반응에 미치는 영향)

  • 표명윤;곽영희
    • YAKHAK HOEJI
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    • v.46 no.2
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    • pp.120-123
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    • 2002
  • In order to investigate the effects of chitosan on the normal and cyclophosphamide (CY)-suppressed primary humoral immune response in mice, chitosan was orally administered alone (single dose of 62.5, 250 mg/kg) or with CY (20 mg/kg, i.p.) to female ICR mice on the 2nd day before or after immunization with SRBC-antigen. When chitosan alone was administered before antigenic challenge, splenic IgM plaque forming cells (PFC) and splenic cellularity were slightly increased and serum IgM was not changed when compared with control group. However, chitosan significantly enhanced PFC, serum IgM and splenic cellularity when administered after antigenic challenge. The PFC numbers, serum IgM and splenic cellularity were significantly decreased by the treatment of CY, whereas those values were slightly increased by the concomitant treament of CY and chitosan when compared with CY alone-administration. These results indicate that chitosan is able to increase normal humoral immunity (HI) and to slightly inhibit the suppressive effects of CY on HI.

Cochineal natural dyeing of alkali-treated PET (II) - Color, Washfastness, Abrasion Resistance, Static Electricity Characteristics - (알칼리 감량(減量) PET의 코치닐 염색(染色) (II) - 색상(色相), 세탁견뢰도(洗濯堅牢度), 마찰견뢰도(摩擦堅牢度), 마찰대전압(摩擦帶電壓)을 중심(中心)으로 -)

  • Kim, Hyun-Su;Jeon, Dong-Won
    • Journal of Fashion Business
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    • v.9 no.5
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    • pp.122-135
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    • 2005
  • It has been reported that natural dyeing is impossible without pre-treatment with metal mordanting agents. However, pre-treatment with chitosan, which has high affinity to natural dyes, could result in an excellent dyeing with various natural dyes. In this study, three treatment methods were employed; 1) Using PET without any pre-treatment (Method 1) 2) Using PET with chitosan acid solution pre-treatment (Method 2) 3) Using PET with chitosan pre-treatment and subsequent crosslinking using citric acid (Method 3) Method 2 and 3 enhanced the Cochineal dyeability remarkably compared to Mehod 1. Washfastness was also enhanced, and moisture content, static property, abrasion resistance, and fabric hand changes were investigated.

Effects of Preheating Treatment and Chitosan Addition on the Textural Properties of Korean Radish during Salting (무의 염장과정 중 조직감의 변화에 대한 예열처리 및 Chitosan 첨가효과)

  • Rhee, Hee-Seoup;Lee, Gui-Ju
    • Journal of the Korean Society of Food Culture
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    • v.9 no.1
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    • pp.53-59
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    • 1994
  • This study was attempted to investigate the effects of preheating treatment and chitosan addition on the textural properties of Korean radish during salting. For this study, we determined the changes in textural properties by compression, puncture, cutting tests respectively and the changes in pectin fractions were also determined. Sensory parameters such as hardness, crispness and toughness were evaluated by sensory analysis and their results were correlated with those by Instron. The results were as follows. The compression force of nonpreheated Korean radish was increased by chitosan addition, whereas that of preheated one was decreased during salting. The puncture force from all the samples of Korean radish decreased, however, chitosan addition showed higher puncture force. The cutting force of nonpreheated Korean radish increased during salting and those from nonpreheated and preheated ones were increased by chitosan addition. During salting hot water soluble pectin(HWSP) of nonpreheated Korean radish increased and 0.4% Na-hexametaphosphate soluble pectin(HXSP) and 0.05 N-HCl soluble pectin(HCISP) decreased respectively. However, HXSP was decreased by preheating treatment. On the contrary, the results were reversed by chitosan addition. Hardness and crispness of nonpreheated Korean radish decreased and toughness increased respectively during salting. However, toughness was decreased by preheating treatment and hardness was increased by chitosan addition. Compression and puncture forces were highly correlated with sensory parameters such as hardness and crispness, whereas cutting force was more correlated with toughness. From these results, it seems that the textural properties were improved by chitosan addition in both nonpreheated and preheated Korean radish. The preheating treatment was effective in the early stage of salting. However, combination of both treatments showed little effect during salting.

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