• 제목/요약/키워드: Chemistry I

검색결과 3,311건 처리시간 0.033초

Gossypiline, a New Lignan from Jatropha gossypifolia

  • Das, R.;Das, B.;Kashinatham, A.
    • Natural Product Sciences
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    • 제4권4호
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    • pp.238-240
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    • 1998
  • A new lignan, gossypiline (1) has been isolated from the aerial parts of Jatropha gossypifolia. The structure of 1 was established from its spectral data. The conversion of isogadain, a known lignan, to 1 confirmed the structure as well as the stereochemistry of 1.

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Novel Thallium(I)-Selective Membrane Electrode Based on a Podal Ligand

  • Ganjali, Mohammad Reza;Pourjavid, Mohammad Reza;Mouradzadegun, Arash;Hosseini, Morteza;Mizani, Farhang
    • Bulletin of the Korean Chemical Society
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    • 제24권11호
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    • pp.1585-1589
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    • 2003
  • A PVC-based membrane electrode for thallium(I) ions based on 1,21,23,25-tetramethyl-2,20: 3,19-dimetheno-[H, 2] H, 23H, 25H-bis-[1,3] dioxocino[5,4-i:5',4'-i] benzo [1,2-d: 5.4-d'] bis [1,3] benzodioxocin(II) has been prepared. The electrode displays a linear dynamic range of $1.0{\times}10^{-1}-1.0{\times}10^{-5}$ M, with a Nernstian slope of $59.8{\pm}0.2\;mV\;{decad^-1}$, and a detection limit $5.0{\times}10^{-6}$ M. It has a very fast response time of<10 s and can be used for at least ten weeks without a considerable divergence in potentials. This electrode revealed comparatively good selectivity with respect to alkali, alkaline earth, and some transition and heavy metal ions and was effective in a pH range of 2.0-10.0. It was used as an indicator electrode in potentiometric titration of thallium ion with sulfide ion.

한국에 분포되어 있는 토착대두 근류균의 질산 환원 특성 (Dissimilatory Nitrate Reduction Characteristics of Indigenous Soybean Rhizobia Distributed in Korea Soils)

  • 최영주;최용락;윤한대;유진창;이상규;조무제
    • Applied Biological Chemistry
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    • 제29권2호
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    • pp.175-181
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    • 1986
  • 연속적으로 대두를 재배한 토양과 신개간지 토양에서 재배한 대두 품종 단엽의 근류로부터 토착대두 근류근 87종을 분리하고 이들을 생장속도에 따라 Bradyrhizobium japonicum (slow-grower) 및 Rhizobium fredii (fast-grower)로 분류한 결과 전자가 55종, 후자가 32종이었다. 이두그룹의 대두 근류균을 질산염 환원특성에 따라 denitrifying fast-grower(F-1), nitrate respiring fast-grower(F-II), denitrifying slow-grower(S-I), 및 nitrate respiring slow-grower (S-II)로 세분 되었으며, 분리균주 총 87종중 S-I, S-II, F-I 및 F-II의 수는 각각 10, 22, 48 및 7종이었다. 이들 각 group 대두 근류균의 균체단백질의 전기영동 pattern상의의 차이를 1차 및 2차원 전기영동으로 분석한 결과 slow 및 fast-grower간에는 현저한 차이를 관찰할 수 있었으나 동일 생장속도를 가진 것 중 denitrifer와 nitrate repirer간에는 큰 차이가 없었다.

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One New and Two Rare Alkamides from Two Samples of the Fruits of Piper longum

  • Das, Biswanath;Kashinatham, A.;Madhusudhan, P.
    • Natural Product Sciences
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    • 제4권1호
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    • pp.23-25
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    • 1998
  • Two samples of the fruits of Piper longum have been chemically investigated. From one sample a new alkamide, pergumidiene and from other sample two rare alkamides, brachystamide B and piperderdine have been isolated. The known compounds, piperine, piperlonguminine, pellitorine, (+)-sesamine and 3-(3', 4', 5'-trimethoxyphenyl)-propionic acid were the common constituents of both the samples.

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Synthesis of Some Novel Thiazolyl - Azetidinone Hybrids

  • Ahn, Chuljin;Hegde, Hemant;Shetty, Nitinkumar S.
    • 대한화학회지
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    • 제60권2호
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    • pp.107-110
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    • 2016
  • A new series of hydrazino thiazolyl-2-azetidinone 4(a-i) derivatives were synthesized efficiently using benzylidene hydrazinyl thiazole derivatives 3(a-i). The precursors, benzylidene hydrazinyl thiazoles were prepared by reacting 4-fluoro phenacyl bromide with thiosemicarbazones 2(a-i). All the structures of the synthesized compounds were ascertained by IR, NMR and mass spectral analysis.