• 제목/요약/키워드: Chemistry Data

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감시시험 결과를 이용한 국내원전 압력용기 재료의 Chemistry Factor 및 RTPTS 평가여유도 분석 (Analysis of Chemistry Factor and RTPTS Margin for Domestic Reactor Pressure Vessel Materials by using the Surveillance Data)

  • 이호진;윤지현;최권재;이봉상
    • 한국압력기기공학회 논문집
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    • 제7권3호
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    • pp.15-22
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    • 2011
  • The chemistry factor and RTPTS margin for domestic reactor pressure vessel materials were analyzed by using the surveillance data which have been obtained from 8 nuclear power plants in Korea. The surveillance data have been used to assess the integrity of the pressure vessel under the pressurized thermal shock (PTS) event. The chemistry factor, which is determined by the Cu and Ni contents of vessel materials, is considered a proper tool to assess the $RT_{PTS}$. The chemistry factors, which were obtained from the surveillance data of domestic reactor pressure vessels, were investigated and compared with those of Regulatory Guide 1.99 in this study. Regressions for ${\Delta}RT_{NDT}$ were performed to expect the chemistry factor as a function of Cu and Ni, and to estimate $RT_{PTS}$ margin. The margin analysis was performed by comparing the regression graphs and standard deviations with those of Regulatory Guide 1.99. The standard deviations calculated by using the domestic surveillance data for base metal and welds are almost same as the standard deviations which are suggested on Regulatory Guide 1.99, Rev.2.

A Study on Emergency Monitoring Robot System by Back-Propagation Algorithm

  • Yoo, Sowol;Kim, Miae;Lee, Kwangok;Bae, Sanghyun
    • 통합자연과학논문집
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    • 제7권1호
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    • pp.62-66
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    • 2014
  • This study aims to implement the emergency monitoring robot system which predicts the current state of the patients without visiting the medical institutions by measuring the basic health status of the user's blood pressure, heartbeat, and basic health status of body temperature in the disaster emergency situation based on the Smart Grid. By arranging a large number of sensor(blood pressure, heartbeat, body temperature sensor) and measuring the bio signs, so the attached wireless XBee sensor can be stored in DB of robot, and it aims to draw the current state of the patients by analysis of stored bio data. Among 300 data obtained from the sensor, 1st data to 100th data were used for learning, and from 101st data to 300th data were used for assessment. 12 results were different among the total 300 assessment data, so it shows about 96% accuracy.

Utilization of EPRI ChemWorks tools for PWR shutdown chemistry evolution modeling

  • Jinsoo Choi;Cho-Rong Kim;Yong-Sang Cho;Hyuk-chul Kwon;Kyu-Min Song
    • Nuclear Engineering and Technology
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    • 제55권10호
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    • pp.3543-3548
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    • 2023
  • Shutdown chemistry evolution is performed in nuclear power plants at each refueling outage (RFO) to establish safe conditions to open system and minimize inventory of corrosion products in the reactor coolant system (RCS). After hydrogen peroxide is added to RCS during shutdown chemistry evolution, corrosion products are released and are removed by filters and ion exchange resins in the chemical volume control system (CVCS). Shutdown chemistry evolution including RCS clean-up time to remove released corrosion products impacts the critical path schedule during RFOs. The estimation of clean-up time prior to RFO can provide more reliable actions for RCS clean-up operations and transients to operators during shutdown chemistry. Electric Power Research Institute (EPRI) shutdown calculator (SDC) enables to provide clean-up time by Co-58 peak activity through operational data from nuclear power plants (NPPs). In this study, we have investigated the results of EPRI SDC by shutdown chemistry data of Co-58 activity using NPP data from previous cycles and modeled the estimated clean-up time by EPRI SDC using average Co-58 activity of the NPP. We selected two RFO data from the NPP to evaluate EPRI SDC results using the purification time to reach to 1.3 mCi/cc of Co-58 after hydrogen peroxide addition. Comparing two RFO data, the similar purification time between actual and computed data by EPRI SDC, 0.92 and 1.74 h respectively, was observed with the deviation of 3.7-7.2%. As the modeling the estimated clean-up time, we calculated average Co-58 peak concentration for normal cycles after cycle 10 and applied two-sigma (2σ, 95.4%) for predicted Co-58 peak concentration as upper and lower values compared to the average data. For the verification of modeling, shutdown chemistry data for RFO 17 was used. Predicted RCS clean-up time with lower and upper values was between 21.05 and 27.58 h, and clean-up time for RFO 17 was 24.75 h, within the predicted time band. Therefore, our calculated modeling band was validated. This approach can be identified that the advantage of the modeling for clean-up time with SDC is that the primary prediction of shutdown chemistry plans can be performed more reliably during shutdown chemistry. This research can contribute to improving the efficiency and safety of shutdown chemistry evolution in nuclear power plants.

NMR Spectroscopic Study of Quinolone Carboxylic Acid Derivatives

  • Dongsoo Koh;Lee, Inwon;Park, Jongmin;Lee, Hyeseung;Yoongho Lim
    • 한국자기공명학회논문지
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    • 제3권1호
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    • pp.52-59
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    • 1999
  • Authors synthesized common intermediates which are applicable for potential antibiotics. Their complete 13C and 1H NMR chemical shift data as well as carbon-and proton-fluorine coupling constants are reported. The knowledge of proton and carbon-fluorine coupling constants may help one assign the NMR data of the fluorinated quinolone derivatives. These results agree with the data published previously.

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Noise Suppression of NMR Signal by Piecewise Polynomial Truncated Singular Value Decomposition

  • Kim, Daesung;Youngdo Won;Hoshik Won
    • 한국자기공명학회논문지
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    • 제4권2호
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    • pp.116-124
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    • 2000
  • Singular value decomposition (SVD) has been used during past few decades in the advanced NMR data processing and in many applicable areas. A new modified SVD, piecewise polynomial truncated SVD (PPTSVD) was developed far the large solvent peak suppression and noise elimination in U signal processing. PPTSVD consists of two algorithms of truncated SVD (TSVD) and L$_1$ problems. In TSVD, some unwanted large solvent peaks and noises are suppressed with a certain son threshold value while signal and noise in raw data are resolved and eliminated out in L$_1$ problem routine. The advantage of the current PPTSVD method compared to many SVD methods is to give the better S/N ratio in spectrum, and less time consuming job that can be applicable to multidimensional NMR data processing.

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표면 플라스몬 공명 센서의 제작 (Surface plasmon resonance sensor)

  • 한원식;정규진;이상원;홍석영;이영훈;홍태기
    • 분석과학
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    • 제19권1호
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    • pp.9-17
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    • 2006
  • 생체 물질의 농도, 두께 및 특정 생체 물질의 분석을 위한 반응 속도론적 자료를 검출하는 능력 그리고 antigen/antibody, ligand/receptor, protein/protein 및 DNA/DNA 상호작용을 포함하는 다양한 생체물질간의 상호작용에 대한 분석에 적용되고, 자연 환경중 오염물질의 분석 등 다양하게 적용되는 표면 플라즈몬 공명 센서를 제작하였다. 또한 표면 플라즈몬 공명 센서를 제어하고 검출기로부터의 데이타(data)를 personal computer로 받아들이기 위해 data acquisition board를 이용하여 LabVIEW program을 만들었다.

Reduction of Ambiguity in Phosphorylation-site Localization in Large-scale Phosphopeptide Profiling by Data Filter using Unique Mass Class Information

  • Madar, Inamul Hasan;Back, Seunghoon;Mun, Dong-Gi;Kim, Hokeun;Jung, Jae Hun;Kim, Kwang Pyo;Lee, Sang-Won
    • Bulletin of the Korean Chemical Society
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    • 제35권3호
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    • pp.845-850
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    • 2014
  • The rapid development of shotgun proteomics is paving the way for extensive proteome profiling, while providing extensive information on various post translational modifications (PTMs) that occur to a proteome of interest. For example, the current phosphoproteomic methods can yield more than 10,000 phosphopeptides identified from a proteome sample. Despite these developments, it remains a challenging issue to pinpoint the true phosphorylation sites, especially when multiple sites are possible for phosphorylation in the peptides. We developed the Phospho-UMC filter, which is a simple method of localizing the site of phosphorylation using unique mass classes (UMCs) information to differentiate phosphopeptides with different phosphorylation sites and increase the confidence in phosphorylation site localization. The method was applied to large scale phosphopeptide profiling data and was demonstrated to be effective in the reducing ambiguity associated with the tandem mass spectrometric data analysis of phosphopeptides.

Two New Flavanones from the Leaves of Flemingia lineata (L.) Aiton

  • Tanjung, Mulyadi;Tjahjandarie, Tjitjik Srie;Mardhiyyah, Shola;Rahman, Ghinsha Zakatina;Aldin, Muhammad Fajar;Saputri, Ratih Dewi;Ahmat, Norizan
    • Natural Product Sciences
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    • 제28권2호
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    • pp.58-61
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    • 2022
  • Three isoprenylated flavanones were isolated from the leaves of Flemingia lineata (L.) Aiton. Among them are two new flavanones, flemilineatins A and B (1-2), along with 6-isoprenyl eridioctyol (3). Their structures were determined using HRESIMS data and NMR spectra. Flavanones 1 - 3 were assayed in the HeLa cancer cells. Compound 1 showed moderate activity with an IC50 value of 11.2 μM.

Two New Flavanones from the Leaves of Flemingia lineata (L.) Aiton

  • Tanjung, Mulyadi;Tjahjandarie, Tjitjik Srie;Mardhiyyah, Shola;Rahman, Ghinsha Zakatina;Aldin, Muhammad Fajar;Saputri, Ratih Dewi;Ahmat, Norizan
    • Natural Product Sciences
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    • 제28권1호
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    • pp.40-43
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    • 2022
  • Three isoprenylated flavanones were isolated from the leaves of Flemingia lineata (L.) Aiton. Among them are two new flavanones, flemilineatins A and B (1-2), along with 6-isoprenyl eridioctyol (3). Their structures were determined using HRESIMS data and NMR spectra. Flavanones 1-3 were assayed in the HeLa cancer cells. Compound 1 showed moderate activity with an IC50 value of 11.2 μM.