• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2008년도 제39회 하계학술대회
• /
• pp.1218-1219
• /
• 2008

Thin films (< 30 nm) of titanium carbide (TiC) are coated on carbon nanotubes (CNTs), which are directly grown on nano-sized ($\sim$ 500 nm in diameter) conical-type tungsten (W) tips, by employing an inductively coupled plasma-chemical vapor deposition (ICP-CVD) technique. Any modification in structural properties (such as length to diameter ratio, crystal quality, and growth behavior) of CNTs due to TiC-coating has been monitored by using high-resolution TEM, field-emission SEM, and Raman spectroscopy. Driving voltage for obtaining the same level of emission current in CNTs-emitter is significantly reduced by TiC-coating. It is also worthy of being noted that the degradation of emission current due to prolonged operation (up to 30 h) is remarkably suppressed by TiC-coating.

• Advances in concrete construction
• /
• 제9권4호
• /
• pp.367-374
• /
• 2020

Concrete surfaces, industrial floors, sidewalks, roads and parking lots are typically subjected to abrasions. Many studies indicated that the abrasion resistance is directly related to the ultimate strength of the cured concrete. Chemical reactions, freeze-thaw cycles, and damages under abrasion are among many factors negatively affecting the concrete strength and durability. One of the major solutions to address the abrasive resistance of the concrete is to use fibers. Fibers are used in the concrete mix to improve the mechanical properties, strength and limit the crack propagations. In this study, implementation of the steel fibers in concrete to enhance the abrasive resistance of the concrete is investigated in details. The abrasive resistance of the concrete with and without steel fibers is studied with the sandblasting technique. For this purpose, different concrete samples are made with various hooked steel fiber ratios and investigated with the sandblasting method for two different strike angles. In total, 144 ASTM verified cube samples are investigated and it is shown that those samples with the highest steel fiber ratios have the highest abrasive resistance. In addition, the experiments determine that there is a meaningful correlation between the steel fiber percentage in the mix, strike angle and curing time which could be considered for improving structural behavior of the fiber-reinforced concrete.

• E2M - 전기 전자와 첨단 소재
• /
• 제10권9호
• /
• pp.930-937
• /
• 1997

Polycrystalline CdTe thin films have been studied for photovoltaic application because of their high absorption coefficient and optimal band energy(1.45 eV) for solar energy conversion. In this study CdTe thin films were deposited on CdS(chemical bath deposition)/ITO(indium tin oxide) substrate by rf-magnetron sputtering under various conditions. Structural optical and electrical properties are investigated with XRD UV-Visible spectrophotometer SEM and solar simulator respectively. The fabricated CdTe/CdS solar cell exhibited open circuit voltage( $V_{oc}$ ) of 610 mV short circuit current density( $J_{sc}$ ) of 17.2 mA/c $m^2$and conversion efficiency of about 5% at optimal sputtering conditions.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2002년도 하계학술대회 논문집 C
• /
• pp.1533-1535
• /
• 2002

Carbon nanotubes (CNTs) were grown with high density on a large area of Ni-coated silicon oxide substrates by using an inductively coupled plasma-chemical vapor deposition (ICP-CVD) of $C_2H_2$ at temperatures ranging from 600 to $700^{\circ}C$. The Ni catalyst was formed using an RF magnetron sputtering system with varying the operating pressure and exposure time of $NH_3$ plasma. The surface morphology of nickel catalyst films and CNTs was examined by SEM and AFM. The graphitized structure of CNTs was confirmed by Ramman spectra, SEM, and TEM. The growth of CNTs was observed to be strongly influenced by the surface morphology of Ni catalyst, which depended on the pre-treatment time and growth temperature. Dense CNTs with uniform-sized grains were successfully grown by ICP-CVD.

• 방사성폐기물학회지
• /
• 제14권1호
• /
• pp.11-19
• /
• 2016

This paper focuses on the estimation of durability and service-life of reinforced concrete structures in Wolsong Low- and intermediate-level wastes Disposal Center (WLDC) in Korea. There are six disposal silos located in the saturated environment. The silo concrete is degraded due to reactions with groundwater and chemical attacks, and finally it will lose its properties as a transport barrier. The infiltration of sulfate and magnesium, leaching of potassium hydroxide, and chlorine induced corrosion are the most significant factors for degradation of reinforced concrete structure in underground environment. From the result of evaluation of the degradation time for each factor, the degradation rate of the reinforced concrete due to sulfate and magnesium is $1.308{\times}10^{-3}cm/yr$, and it is estimated to take 48,000 years for full degradation while potassium hydroxide is leached in depth of less than 1.5 cm at 1,000 years after the initiation of degradation. In case of chlorine induced corrosion, it takes 1,648 years to initiate corrosion in the main reinforced bar and 2,288 years to reach the lifetime limit of the structural integrity, and thus it is evaluated as the most significant factor.

• EDISON SW 활용 경진대회 논문집
• /
• 제6회(2017년)
• /
• pp.499-505
• /
• 2017

Photoisomerizing molecules which can transform their structure by the light irradiation have great deal for the application of photo-switching devices. And azobenzene is the representive type of the photoisomerizing molecules. It can transform their trans- structures into cis- structure as the light for certain wave lengths they receive. This property shows the potential of ON/OFF switching functionalization which can be used into the nano scale photo switch. Furthermore, many studies are interested in the organic linkers that connect the azobenzene and metal electrodes. We used S, $CH_2S$, $(CH_2)_4S$ as the linker to watch the influence of linkers for electronic properties. So We suggest a photoswitching device based on the vertical junction using the first-principles calculations with density functional theory and non-equilibrium Greens function (NEGF). By analyzing the electronic structure and tunneling current caused by the structural difference of the system between cis- and trans- azobenzene, the difference in switching mechanism, ON/OFF ratio and transmission will be watched as the linker changes. And finally We will suggest which linker would be the better for the optimal device architecture which can achieve high control of the ON/OFF photocurrent ratio. This result will show the potential of azobenzene-based photoswitch and provide the critical insight in constructing the optimal device architecture.

• 한국세라믹학회지
• /
• 제45권11호
• /
• pp.667-674
• /
• 2008

In this study, we prepared Fe-activated carbon fiber(ACF)/$TiO_2$ composites with titanium (VI) n-butoxide (TNB) as the titanium source for ACF pre-treated with iron compounds through the impregnation method. In terms of textural surface properties, the composites demonstrate a slight decrease in the BET surface area of the samples and an increase in the amount of iron compounds treated. The surface morphology of the Fe-ACF/$TiO_2$ composites was characterized by means of SEM. The composites have a porous texture with homogenous compositions of Fe and titanium dioxide distributed on the sample surfaces. The phase formation and structural transition of the iron compounds and titanium dioxide were observed in X-ray diffraction patterns of the Fe-ACF/$TiO_2$ composites. The chemical composition of the Fe-ACF/$TiO_2$ composites, which was investigated with EDX shows strong peaks for the C, O, Fe and Ti elements. The photo degradation results confirm that the Fe-ACF/$TiO_2$ composites show excellent removal activity for the COD in piggery waste due to photocatalysis of the supported $TiO_2$, radical reaction by Fe species, and the adsorptivity and absorptivity of ACF.

• 한국세라믹학회지
• /
• 제32권7호
• /
• pp.809-816
• /
• 1995

Ti1-xAlxN films were successfully deposited on high speed steel and silicon wafer by plasma-assisted chemical vapor deposition using a TiCl4/AlCl3/N2/Ar/H2 gas mixture. Plasma process enabled N2 gas to nitride AlCl3, which is not possible in sense of thermodynamics. XPS analyses revealed that the deposited layer contained Al-N bond as well as Ti-N bond. Ti1-xAlxN films were polycrystalline and had single phase, B1-NaCl structure of TiN. Interplanar distance, d200, of (200) crystal plane of Ti1-xAlxN was, however, decreased with Al content, x. Al incorporation into TiN caused the grain size to be finer and changed strong (200) preferred orientation of TiN to random oriented microstructure. Those microstructural changes with Al addition resulted in the increase of micro-hardness of Ti1-xAlxN film up to 2800Kg/$\textrm{mm}^2$ compared with 1400Kg/$\textrm{mm}^2$ of TiN.

• 한국농공학회:학술대회논문집
• /
• 한국농공학회 2000년도 학술발표회 발표논문집
• /
• pp.477-483
• /
• 2000

Fly ash is the unburned residue resulting from the combustion of coal in utility and industrial boilers such as thermal power plants. Annually about 5 million tons of fly ash is being produced in korea. Less than 25 percent of total volume of fly ash is currently being used effectively for some ways. In the future, the volume of fly ash discharge from thermal power stations will be increasing more and more, and the development of the utilization of high volume fly ash is required. Fly ash has a lower compacted density and specific gravity than coarse grained natural aggregates but equivalent strength properties indicating that the fly ash could be used as a structural fill materials. So, clay-fly ash mixtures can be used as a fill material in the construction of embankments. Laboratory tests have been carried out to determine the physical, chemical, and geotechnical characteristics of the clay and fly ash. The fly ash is mixed with the clay in different proportions and the geotechnical characteristics of the mixtures have been studied also. In this study describes the results of the experimental study. The implications of the use of clay and clay-fly ash mixtures on the stability of embankments are discussed.

• 한국미생물·생명공학회지
• /
• 제21권1호
• /
• pp.47-53
• /
• 1993

순수분리된 2,000여주의 혐기성 세균으로부터 선발된 Clostridium sp. KN-431은 bacteria 및 fungi에 대하여 재현성있는 항균활성을 나타내는 항생물질 KG-431A와 KG-431B를 생산하였다. 이들 중 KG-431B는 항암활성이 1차 검색에서도 양성반응을 보인 바 이에 대한 후속연구를 계획중에 있다. 이들의 MIC 값을 비교해 보면 완전정제가 가능하였던 KG-431B 보다는 차라리 정제과정에서 많은 어려움이 따라 불완전 상태로 실험을 행한 KG-431A의 활성이 더 뛰어난 것을 알 수 있었다. 정제된 KG-431B의 여러가니 이화학적 특성과 spectra datark 기지물질인 3-IPA와 일치하나 본 실험을 통해 밝혀진 항암활성의 검색은 정제된 3-IPA에서는 아직까지 알려진 바 없는 생물학적 특성으로 간주된다. 또한 Clostridium 속에서 최초로 발견된 3-IPA 존재에 대한 결과는 아직 정제가 완료되지 않은 KG-431B에 관한 연구와 함께 후속적인 확인 연구가 진행중에 있다.