• Title/Summary/Keyword: Chemical-structural properties

Search Result 973, Processing Time 0.031 seconds

Effects of catalyst pretreatment on structural and field emissive properties of carbon nanotubes synthesized by ICP-CVD method (ICP-CVD 방법으로 합성된 탄소 나노튜브의 구조적 물성 및 전계방출 특성에 촉매의 전처리 공정이 미치는 영향)

  • Hong, Seong-Tae;Park, Chang-Kyun;Park, Jin-Seok
    • Proceedings of the KIEE Conference
    • /
    • 2005.07c
    • /
    • pp.1862-1864
    • /
    • 2005
  • Carbon nanotubes [CNTs] are grown on TiN-coated Si substrates at $700^{\circ}C$ by inductively coupled plasma-chemical vapor deposition (ICP-CVD). Pre-treatment of Ni catalysts has been performed using an RF magnetron sputtering system. Structural properties and field-emission characteristics of the CNTs grown are analyzed in terms of the RF power applied and the treatment time used in the pre-treatment process. The characterization using various techniques, such as FE-SEM, AFM, and Raman spectroscopy, show that the physical dimension as well as the crystal quality of CNTs are changed by pre-treatment of Ni catalysts. It is also seen that Ni catalysts with proper grain size and uniform surface roughness may produce much better electron emission. The physical reason for all the measured data obtained are discussed to establish the relationship between the structural property and the electron emission characteristic of CNTs.

  • PDF

Recyled Concrete Aggregate (RCA) in Structural Concrete of Developing Nation: A Cace Study of Ethiopian Construction Industry

  • Damtie, Mitiku;Woldesenbet, Asregedew
    • International conference on construction engineering and project management
    • /
    • 2015.10a
    • /
    • pp.405-410
    • /
    • 2015
  • Today, the booming construction in Ethiopia is leading to an increased demolition of concrete structures whereby these demolished structures are disposed at landfills. The current practice is creating a huge amount of waste which is environmentally unfriendly and is becoming the main source of pollution in communities. This paper discusses the potential use of demolished concrete from site tested specimens as a recycled aggregate material for new structural concrete. The mechanical, physical and chemical properties of RCA are studied to understand the suitability in the production of recycled concrete. Tests including gradation, unit weight, soundness, density, and abrasion will be conducted to assess RCA properties. Since the percentage of RCA govern the strength of concrete, a C25 concrete is mixed by the ratio of 25%, 50% & 100% RCA with and without water reducing admixture and a control mixture composed of natural aggregate. The output of this study will highly impact the growing construction industry and communities in Ethiopia thereby reducing waste, saving cost, conserving natural aggregates, building capacity and setting quality standards.

  • PDF

Conversion Characteristics of Chemical Constituents in Liriodendron tulipifera and Their Influences on Biomass Recalcitrance during Acid-Catalyzed Organosolv Pretreatment

  • Ki-Seob GWAK;JunHo SHIN;Chae-Hwi YOON;In-Gyu CHOI
    • Journal of the Korean Wood Science and Technology
    • /
    • v.52 no.2
    • /
    • pp.101-117
    • /
    • 2024
  • The conversion characteristics of the major components of Liriodendron tulipifera were investigated during acid-catalyzed organosolv pretreatment. Glucan in L. tulipifera was slowly hydrolyzed, whereas xylan was rapidly hydrolyzed. Simultaneous hydrolysis and degradation of xylan and lignin occurred; however, after complete hydrolysis of xylan at higher temperatures, lignin remained and was not completely degraded or solubilized. These conversion characteristics influence the structural properties of glucan in L. tulipifera. Critical hydrolysis of the crystalline regions in glucan occurred along with rapid hydrolysis of the amorphous regions in xylan and lignin. Breakdown of internal lignin and xylan bonds, along with solubilization of lignin, causes destruction of the lignin-carbohydrate complex. Over a temperature of 160℃, the lignin that remained was coalesced, migrated, and re-deposited on the surface of pretreated solid residue, resulting in a drastic increase in the number and content of lignin droplets. From the results, the characteristic conversions of each constituent and the changes in the structural properties in L. tulipifera effectively improved enzymatic hydrolysis in the range of 140℃-150℃. Therefore, it can be concluded that significant changes in the biomass recalcitrance of L. tulipifera occurred during organosolv pretreatment.

Structural and Physicochemical Studies on DA-5018, a New Capsaicin Derivative (새로운 Capsaicin 유도체 DA-5018의 구조 및 물리화학적 성질 연구)

  • Kim, Heung-Jae;Lee, Jong-Jin;Lee, Eung-Doo;Shim, Hyun-Joo;Lee, Sang-Deuk;Ok, Kwang-Dae;Kim, Won-Bae;Park, No-Sang
    • Journal of Pharmaceutical Investigation
    • /
    • v.27 no.2
    • /
    • pp.119-123
    • /
    • 1997
  • The physicochemical and structural properties of new capsaicin derivative, DA-5018, were examined. The reference standard of this compound was obtained by the recrystallization. A method for the determination of the dissociation constant of the compound is described. pH-solubility and distribution coefficient were determined by chromatographic method. Fundamental properties on thermal behaviors were investigated by TG, DTA and DSC. Structural analysis based on spectroscopic method coincided with the chemical structure of DA-5018. Approximate dissociation constant of the compound determined by UV spectral method was 9.35. Solubilities and partition coefficients in various pH buffer solution appeared pH-dependency. No crystal transition or further transition was found in the thermal analysis. This compound showed good stability, but pH 13 buffer and acetone made some degradative products.

  • PDF

Apoptosis-inducing effect and structural basis of Polygonatum cyrtonema lectin and chemical modification properties on its mannose-binding sites

  • Liu, Bo;Xu, Xiao-Chao;Cheng, Yan;Huang, Jian;Liu, Yan-Hong;Liu, Zhen;Min, Ming-Wei;Bian, He-Jiao;Che, Jing;Bao, Jin-Ku
    • BMB Reports
    • /
    • v.41 no.5
    • /
    • pp.369-375
    • /
    • 2008
  • Polygonatum cyrtonema Lectin (PCL), which is classified as a monocot mannose-binding lectin, has received great regards for its uniquely biological activities and potentially medical applications in cancer cells. This paper was initially aimed to study apoptosis of PCL on Hela cells. Thus, 3-(4, 5-dimethylthiazol-2-yl)-2, 5-diphenyltetrazolium bromide (MTT) method was carried out. Through observation of cell morphologic changes and Lactate dehydrogenase (LDH) activity-based cytotoxicity assays, PCL induced HeLa cell apoptosis in a dose-dependent manner. To further gain structural basis, multiple alignments, homology modeling and docking experiments were performed to analyze the correlation between its biological activities and mannose-binding sites. Eventually, considering docking data, chemical modification properties on the three mannose-binding sites were analyzed by a series of biological experiments (e.g., hemagglutinating and mitogenic activity assays, fluorescence and Circular Dichrosim (CD) spectroscopy) to profoundly identify the role of some key amino acids in the structure-function relationship of PCL.

A Study on Photocatalytic Degradation Properties by Oxygen Partial Pressure for Tio2Thin Films Fabricated by DC Magnetron Sputtering (DC 마그네트론 스퍼터링법으로 제조된 Tio2 박막의 산소분압비에 따른 광분해 특성에 관한 연구)

  • Jeong, W.J.;Park, J.Y.;Park, G.C.
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.18 no.3
    • /
    • pp.226-230
    • /
    • 2005
  • This paper describes the photocatalytic degradation properties by oxygen partial pressure for TiO$_2$ thin films fabricated by dc magnetron reactive sputtering. And the structural, chemical, optical and photocatalytic properties were investigated at various analysis system. When TiO$_2$ thin film was made at deposition time of 120 min and Ar:O$_2$ ratio of 60:40, the best properties were obtained. That results were as follows: thickness; 360∼370 nm, gram size; 40 nm, optical energy band gap; 3.4 eV and Benzene conversion in the photocatalytic degradation; 11 %.

Mechanical Properties for Major Parts in Agricultural Machinery (II) - Comparison for Suitability in Chemical Ingredient - (농업기계 주요부품의 기계적 성질에 관한 연구 (II) - 화학성분의 적합여부에 따른 비교 -)

  • 최규홍;권순홍
    • Journal of Biosystems Engineering
    • /
    • v.23 no.2
    • /
    • pp.187-194
    • /
    • 1998
  • This study was carried out to investigate mechanical properties o major part for agricultural machinery in Korea. The results are as follows ; 1. The mechanical Properties for heat resisting steel bars, alumium alloy castings, carbon steel for machine structural use, chromium molybdenum steels, high strength brass castings and carbon tool steels are proper for Korean standard. 2. The mechanical properties fir spring steels used to mould board, share of plow and blade of rotary are not suitable to Korean standard. Ⅰ think that a counterplan for quality rising is necessary such as supply of good quality materials and improvement of new materials in Korean agricultural machinery.

  • PDF

Characterization of Segmented Block Copolyurethane Network Based on Glycidyl Azide Polymer and Polycaprolactone

  • Min, Byoung-Sun;Ko, Seung-Won
    • Macromolecular Research
    • /
    • v.15 no.3
    • /
    • pp.225-233
    • /
    • 2007
  • To improve the poor mechanical and low-temperature properties of glycidyl azide polymer (GAP)-based propellants, the addition of binders was investigated using GAP and flexible polymer backbone-structural polycaprolactone (PCP) at various weight(wt) ratios, and varying the ratio of Desmodur N-100 pluriisocyanate (N-100) to isophorone diisocyanate (IPDI). Using Gee's theory, the solubility parameter of the PCP network was determined, in order to elucidate the physical and chemical interaction between GAP and PCP. The structure of the binder networks was characterized by measuring the cross-link densities and molecular weights between cross-links ($M_c$) obtained by a swelling experiment using Flory-Rhener theory. The thermal and mechanical properties of the segmented block copolyurethane (GAP-b-PCP) binders prepared by the incorporation of PCP into the binder recipes were investigated, along with the effect of the different curatives ratios.

Engineering Properties of Sewage Polymer Concrete Culvert (폴리머 콘크리트를 적용한 하수암거의 공학적 특성)

  • Kwon, Seung Jun;Min, Byung Yoon;Park, Sang Soon
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.16 no.6
    • /
    • pp.9-17
    • /
    • 2012
  • Concrete sewage culvert shows degradation with time since it is always exposed to various harmful ions, and deterioration of concrete culvert propagates to structural safety problems. After reclamation, maintenance for concrete sewage culvert is very difficult so that high durable and structural performance are essential for the sewage concrete culvert. Recently polymer concrete has been used to improve mechanical properties and durability performance. In this paper, engineering properties are evaluated for sewage culvert made with polymer concrete, and leakage and adhesive strength between joints are evaluated with small-scale models. The polymer sewage culvert shows high compressive strength over 100MPa with low water permeability and chloride penetration. Furthermore, high resistances to chemical and biological attack are evaluated. Through tests for leakage and adhesive, unification of joints is verified with evaluation of no leakage and high adhesive strength. Precast polymer sewage culvert in this paper can be actively used for severe conditions like sewage lines.

High-Temperature Structural Analysis of a Small-Scale PHE Prototype - Analysis Considering Material Properties in Weld Zone - (소형 공정열교환기 시제품 고온구조해석 - 용접부 물성치를 고려한 해석 -)

  • Song, Kee-Nam;Hong, Sung-Deok;Park, Hong-Yoon
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.36 no.10
    • /
    • pp.1289-1295
    • /
    • 2012
  • A process heat exchanger (PHE) in a nuclear hydrogen system is a key component for transferring the considerable heat generated in a very high temperature reactor (VHTR) to a chemical reaction that yields a large quantity of hydrogen. A performance test on a small-scale PHE prototype made of Hastelloy-X is underway in a small-scale gas loop at the Korea Atomic Energy Research Institute. Previous research on the high-temperature structural analysis of the small-scale PHE prototype had been performed using base material properties. In this study, a high-temperature structural analysis considering the mechanical properties in the weld zone was performed, and the obtained results were compared with those of the previous research.