• Title/Summary/Keyword: Chemical weathering index

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Material Characteristics and Deterioration Assessment of the Stone Buddhas and Shrine in Unjusa Temple, Hwasun, Korea (화순 운주사 석조불감의 재질특성과 풍화훼손도 평가)

  • Park, Sung-Mi;Lee, Myeong-Seong;Choi, Seok-Won;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.24
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    • pp.23-36
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    • 2008
  • The stone Buddhas and Shrine of Unjusa temple (Korea Treasure No. 797) in Hwasun formed in Koryo Dynasty are unique style which the Buddha faces each other the back parts of south and north within the stone Shrine. The stone Buddhas and Shrine are highly evaluated in historical, artistic and academic respects. But, the stone properties have been exposed in the open system various aspects of degradations weathered for a long time without specific protective facilities. The rock materials of the stone Buddhas and Shrine are about 47 blocks, and total press load is about 56.6 metric ton. The host rocks composed mainly of white grey hyaline lithic tuff and rhyolitic tuff breccia. In addition, biotite granite used as part during the restoration works. The chemical index of alteration for host tuffaceous rocks and the replacement granites range from 52.1 to 59.4 and 50.0 to 51.0, respectively. Weathering types for the stone Buddhas and Shrine were largely divided with physical, chemical and biological weathering to make a synthetic deterioration map according to aspects of damage, and estimate share as compared with surface area. Whole deterioration degrees are represented that physical weathering appeared exfoliation. Chemical weathering is black coloration and biological weathering of grey lichen, which show each lighly deterioration degrees. According to deterioration degree by direction of stone Buddhas and Shrine, physical weathering mostly appeared by 39.1% on the sorthern part, and chemical weathering is 61.2% high share on the western part. Biological weathering showed 38.3% the largest distribution on the southern part. Therefore, it is necessary to try hardening for the parts with serious cracks or exfoliations, remove secondary contaminants and organisms through regular cleaning. Also necessary to make a plan to remove moisture of the ground which causes weathering, and estimate that need established and scientific processing through clinical demonstration of conservation plan that chooses suitable treatment.

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Geochemical weathering properties of marine terrace sediment at Gangneung-Donghae area, South Korea (강릉-동해에 분포하는 해안단구 퇴적물의 지화학적 풍화 특성)

  • Hong, Seongchan;Choi, Jeong-Heon;Kim, Jong Yeon
    • Journal of The Geomorphological Association of Korea
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    • v.23 no.2
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    • pp.95-108
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    • 2016
  • Several flights of marine terraces were developed along the Eastern coast of Korea (Gangneung-Donghae). Various dating techniques have been applied to determine the age of these terraces, with a view to better understand the regional uplift history. In this study, we compare the major element compositions of the terrace deposits and modern beach sediments to estimate the relative formation age of these terraces. We observed a discernible difference in major element geochemistry between modern beach sediments and various elevated terrace deposit (i.e. palaeobeach sediments). In general, weathering properties of marine terrace sediments are expected to be affected by the formation ages of terraces, and here, we confirm that the chemical composition are indicative of the relative age of the terraces in this region.

Effect of Isocyanate Curing Agents on the Physical Properties and Flame Retardancy of Flame-Retardant PU Coatings (이소시아네이트 경화제 종류에 따른 PU 난연도료의 도막물성 및 난연효과)

  • Park, Hong-Soo;Shim, Il-Woo;Jo, Hye-Jin;Hahm, Hyun-Sik;Kim, Young-Geun
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.3
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    • pp.264-271
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    • 2006
  • PU type flame-retardant coatings (TBAO/L-75, TBAOL ; TBAO/N-100, TBAON) were prepared by blending bromine-containing modified polyester (TBAO) which was synthesized in our earlier work. with two kinds of isocyanate curing agents, Desmodur L-75 and Desmodur N-100. Physical properties of the prepared flame-retardant coatings were tested. TBAOL shows better hardness than TBAON, while TBAON shows better viscosity, accelerated weathering resistance, yellowness index and lightness index difference than TBAOL. There were no remarkable differences in fineness of grind, $60^{\circ}$ specular gloss, cross-hatch adhesion, and abrasion resistance of TBAOL and TBAON. There was no discernable difference in flame-retardancy between the two flame-retardant coatings, TBAOL and TBAON. When the content of tribromo acetic acid, which is flame-retarding component, was 30wt% the LOI value was in a range of $29{\sim}30%$, which indicates that the two coatings are good flame-retardant coatings.

Comparison of Physicochemical Characteristics of Topsoil and Subsoil for Soil Conservation and Management (토양 보전 및 관리를 위한 표토와 심토의 물리화학적 특성 비교)

  • Lee, So-Jin;Choo, Chang-Oh;Kim, Jong-Tae;Jeong, Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.31 no.4
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    • pp.731-739
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    • 2021
  • This research aimed to analyze the characteristics of topsoil for soil conservation and promote the process of turning subsoil into topsoil. The physicochemical characteristics of topsoil and subsoil of different types of soil were compared, and their quantitative differences were examined. 204 soil samples were collected from a total of 102 areas according to rock types. These samples were tested to measure grain size, water content, and unit weight, along with XRF and XRD analyses. The topsoil and subsoil of the soil samples were also analyzed. The results of this research showed that the topsoil and subsoil had different physical characteristics, and that the chemical alteration index of the topsoil was higher than that of the subsoil. This would imply that the topsoil was high in clay minerals since it was directly affected by weathering more than the subsoil. In particular, vermiculite, one of the final products generated from weathering, was common in the topsoil.

Characterization of Wetness Index in Western Area of Yangsan Fault, Sangbuk-myeon, Kyeongnam-do (경상남도 상북면 양산단층 서부지역에 대한 습윤지수 특성 연구)

  • Kim, Sung-Wook;Han, Ji-Young;Lee, Son-Kap;Kim, Sang-Hyun;Kim, Choon-Sik;Kim, In-Soo
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.904-909
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    • 2004
  • The study area adjoins with Yangsan fault in Sangbuk-myeon, Samsam-ri, Kyongsang-namdo and consist of the natural steep slope. After drawing data layer which have altitude by using digital topography data, it is converted to lattice DEM of $10m{\times}10m$ size. From this, gradient map of unit lattice, slant direction map and shadow relif map are made. Using flow apportioning algorithm, upper slope contributing area and wetness index by established lattice can be calculated. Area that have high wetness index shows lineament structure of northwest-southeast direction, and this agrees with shear fracture system. The result of electricity specific resistance survey in the study area shows that area of high wetness index has low electricity specific resistance anomaly. That is, wetness index conforms with distribution of fractured zone that accompanied chemical weathering of rock. Therefore, wetness index can be used as the method of detecting fractured zones and judging the stability of the area.

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Geological Environments and Deterioration Causes of the Sitting Buddha Carved on Rockcliff in Bukjiri, Bonghwa (봉화 북지리 마애여래좌상의 지질환경과 훼손원인)

  • Hwang, Sang-Koo;Nam, Jae-Guk
    • Economic and Environmental Geology
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    • v.40 no.1 s.182
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    • pp.47-66
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    • 2007
  • The Sitting Buddha Carved on Rockcliff (National treasure No. 201) in Bukjiri consists of porphyritic biotite granite, which was fractured by three joint sets of NE-SW, EW and NS directions. They produced a physical weathering that broke many parts of the Buddha and background. The chemical index of alteration is 59 to 61 from the major elements in the granite that was weathered into producing kaolin minerals from alteration of feldspars and biotite. With weathering degree, major element compositions increase in $SiO_2$ and MnO, whereas decrease in $TiO_2,\;{Fe_2O_3}^t,\;MgO,\;CaO\;and\;K_2O$. Change proporations of trace elements to $Al_2O_3$ increase in all transition elements, Rb and Y, whereas decrease in Li, Sr and Ba. REE pattern increases only in HREE. Particularly, a decrease in CaO, $K_2O$, Sr and Ba results in what they are effluxed to dissolve from feldspars by groundwater. The Buddha image has been deteriorated into joints, color changes, brown rusts, granular decay, microorganic smears by the such weathering causes as deformation, moisture, temperature variation and microorganic living. The moisture, which leaks along the joints in the granite, not only dissolve to decompose minerals but also grows many microorganism and is frozen over during winter. NE-SW and NS joint sets affect to seep in water during rainy days to deteriorate the image because they extend outward.

Analysis of Weathering Sensitivity by Swelling of Domestic Highway Sites (국내 고속도로현장의 스웰링에 의한 풍화민감도 분석)

  • Jang, Seokmyung;Han, Heuisoo
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.3
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    • pp.15-22
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    • 2022
  • This study aims to observe the swelling representative rocks in Korea and to suggest improvements in the use of test methods and prior analysis in relation to the weathering of rocks. The swelling test and analysis were performed on the drilling cores obtained for the ground investigation at the domestic highway construction site. For the method of determining the absorption expansion index of rocks, the method proposed in "Standard Methods for Sample Collection and Specimen Preparation" of ISRM and Korean Rock Engineers Standard Rock Test Method was used. The specimen for the measurement of the expansion displacement was cylindrical with a height of 10 cm and a diameter of 5 cm. The existing swelling analysis method evaluates the sensitivity to weathering by using the maximum expansion displacement, but since the classification by bedrock grade is unclear, it is reasonable to use the rate of change of the expansion displacement according to the immersion time. It is necessary to conduct an experiment to distinguish between weathering and fault deterioration. In addition, long-term weathering prediction technology for each cancer type is needed through the expansion displacement analysis of the chemical weathering stage.

Investigation on Weathering Degree and Shear Wave Velocity of Decomposed Granite Layer in Hongsung (홍성 지역 화강 풍화 지층의 풍화도 및 전단파 속도에 관한 고찰)

  • Sun, Chang-Guk;Kim, Bo-Hyun;Chung, Choong-Ki
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.6C
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    • pp.431-443
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    • 2006
  • As part of a fundamental characterization for subsurface layers in Korea, the weathering degree and shear wave velocity ($V_S$) were evaluated from the X-ray fluorescence analyses and the site investigations containing boring and in-situ seismic tests, respectively, for decomposed granite layer in Hongsung. The subsurface layers at Hongsung were composed of 10 to 40 m thickness of weathered layer in most sites. According to the results of weathering degree analyses in Hongsung, it was examined that three chemical weathering indexes such as MWPI, VR and WIP generally increased with decreasing depth. From the in-situ seismic tests, the $V_S$ was determined as the range between 200 and 500 m/s in weathered layer. Based on the $V_S$ and N value at borehole seismic testing sites, N-$V_S$ correlations were established for weathered layer. Furthermore, the relationships of three representative weathering indexes with the $V_S$ and N value indicated that the MWPI, WIP and 100/VR increased linearly as increasing $V_S$ and exponentially as increasing N value.

Correlation between Water Values and Chemical Index of Alteration (CIA) in Rocks (퇴적암에서 수분값과 화학적 풍화지수(CIA) 간의 상관관계)

  • Park, Kyunggun;Shin, Jaeryul
    • Journal of the Korean Geographical Society
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    • v.50 no.5
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    • pp.505-514
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    • 2015
  • This study analyzes a correlation between water content values and chemical index of alteration (CIA) for coarse sedimentary rocks of Mt. Cheonsaeng in Gumi-si, Kyeongsangbuk-do. Through measurement of various water values of 20 samples including water content rate, water absorption rate and equipment measuring we comparatively analyzed the values with CIA of the samples obtained by X-ray fluorescence. As a result of analysis water content rate and water absorption rate in a sedimentary rock are likely to be higher when matrix is psephitic and less compact. Furthermore the higher water content rate is, the higher CIA is due to increase of $SiO_2$ and $Al_2O_3$ and decrease of CaO and $Na_2O$ derived by chemical weathering of felspar. This correlation between water content rate and CIA represents a similar result with previous studies targeting granite.

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The Effects of Bed-rock Formations on Water Quality and Contamination : Statistical Approaches (수자원의 수질과 오염에 대한 기반암의 영향 연구 : 통계학적 접근)

  • 이병선;우남칠
    • Economic and Environmental Geology
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    • v.36 no.6
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    • pp.415-429
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    • 2003
  • This study was objected to identify the difference of water quality and the characteristics of water contamination in adjacent bed-rock areas of Upper Hwajeonni and Guryongsan Formations in Miwon, Choongchungbuk-do, Korea. Water samples showed mainly (Ca, Mg)-$HCO_3$ type in Upper Hawjeonni Formation and (Ca, Mg)-$SO_4$ and (Ca, Mg)-$HCO_3$ types in Guryongsan Formation indicating the enrichment of $SO_4$ in major compositions. Groundwater quality could be divided into two groups based on the major weathering processes, implied by the ratio of bicarbonate to silica. Carbonate-silicate weathering predominates in Upper Hwajeonni Formation, and silicate weathering in Guryongsan Formation. Stream-water quality also appeared to be controlled by water-rock interaction. Cluster analysis identified three groups of groundwater and four groups of stream-water with distinctive geochemical characteristics. The results of factor analysis indicated that the levels of each chemical constituent in water samples derived from both natural weathering reactions and anthropogenic contamination sources. To delineate the pollution potential of water resources, Modified Pollution Index(M.P.I.) was developed. M.P.I. scores of water samples ranged from -0.08 to 0.18, with mostly positive along the rock quarry in Guryongsan Formation areas. M.P.I. scores appeared to be a useful predictor of metal contamination of water resources.