• Bulletin of the Korean Chemical Society
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• 제20권3호
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• pp.267-268
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• 1999

• Natural Product Sciences
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• 제25권2호
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• pp.81-91
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• 2019

Marrubium vulgare, plant species belonging to Marrubium genus, is widespread in the Mediterranean areas, introduced elsewhere and also cultivated in many countries. Its oil is recognized to possess a considerable biological activities with varied chemical composition. This paper aims to overview the chemical composition and biological activities of M. vulgare essential oil's considered as a medicinal plant, widely used in folk medicine overall the world. In essential oils of M. vulgare, germacrene D, ${\beta}$-caryophyllene, ${\beta}$-bisabolene, bicyclogermacrene and carvacrol are generally considered as either mains or minor constituents and each species presents its own composition. Sesquiterpenoids were the dominant fraction while monoterpenoids were present in appreciable or in trace amount. Oxygenated fractions dominated in monoterpenes however, hydrocarbon fraction overpowered in sesquiterpenes. These oils are biologically active, they exhibit an antioxidant and antimicrobial activities and other activities. Due to the variability of composition of essential oil, further studies are necessary, particularly regarding their chemical's which may cause an important change in the biological activities of oils and probably defined different chemotype.

• 펄프종이기술
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• 제43권3호
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• pp.43-51
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• 2011

Chemical composition and contents of carbohydrates, lignin, and extractives in Moso(Phyllostachys pubescens Mazel), Henon(Phyllostachys nigra var. henonis Stapf ex. Rendle), and Timber bamboo(Phyllostachys bambusoides Sieb. et Zucc.) known as economically valuable bamboo species in Korea were analyzed as a function of ages. All of tested bamboo species were composed of fucose, arabinose, rhamnose, galactose, glucose, xylose, and mannose. Glucose was the sugar which showed the highest content followed by xylose. The contents of others were below 3%. Sugar contents of bamboo shoots showed the lowest among the tested bamboo samples, and the constant rates were shown after 50 days of growth. Lignin content increased by the growth of one year, and the increasing rates tended to be constant after the growth of three years. Bamboo shoots have the highest contents of acid-soluble lignin, which turned into insoluble lignin after the growth of 50 days. Bamboo shoots showed the highest content of extractives and tend to be decreased by the growth of 50 days and then the content increased slowly in proportion to the period of bamboo growth. No relationship was found between species and chemical composition of bamboo. However, there were significant difference in chemical composition between bamboo shoots and 50-day old bamboo.

• 한국환경복원기술학회지
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• 제4권3호
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• pp.19-29
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• 2001

This study was carried out to examine the recovery of forest ecosystem at the burned areas of coniferous (Mt. Chosdae) and broad leaved forest (Samsinbong in Mt. Chiri) by investigating the changes of forest vegetation. The results obtained are summarized as follows; 1. In the Samsinbong, the total number of species appeared at the burned area were 5 species at tree layer, 11 species at sub-tree layer and 24 species at herb layer, and at the unburned area were 5 species at tree layer, 14 species at sub-tree layer, 18 species at shrub layer and 23 species at herb layer, respectively. In the Mt. Chosdae, the total number of species appeared at the burned area only showed to 83 species at herb layer, and at the unburned area were 7 species at tree layer, 13 species at sub-tree layer, 21 species at shrub layer and 46 species at herb layer, respectively. 2. In the soil chemical properties of the burned area of Samsinbong, pH was 5.8, and contents of Organic matter, Total nitrogen, Available $P_2O_5$, Exchangeable $K^+$, Exchange $Ca^{{+}{+}}$ and Exchange $Mg^{{+}{+}}$ were 7.42%, 0.73%, 28.5mg/kg, 1.3me/100g, 13.3me/100g and 2.2me/100g, respectively. But they showed a tendency to decrease by passing the time. In the soil chemical properties of the burned area of Mt. Chosdae, pH was 5.3, and contents of Organic matter, Total nitrogen, Available $P_2O_5$, Exchangeable $K^+$, Exchange $Ca^{{+}{+}}$ and Exchange $Mg^{{+}{+}}$ were 6.42%, 0.25%, 24.4mg/kg, 0.7me/100g, 3.7me/100g and 2.1me/100g, respectively, and they also showed a tendency to decrease by passing the time. 3. An the burned and unburned areas of Samsinbong, the total evolved amounts of soil respiration were $4,049.1mg/m^2/h$ and $9,950.0mg/m^2/h$, respectively. An the burned and unburned areas of Mt. Chosdae, the total evolved amounts of soil respiration were $4,392.4mg/m^2/h$ and $8,286.5mg/m^2/h$, respectively.

• Bulletin of the Korean Chemical Society
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• 제27권5호
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• pp.694-698
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• 2006

A method has been described for the chemical speciation, preconcentration and determination of Cr(III) and Cr(VI) species in filtered tannery waste waters by flame atomic absorption spectrometry using ion-exchange resins. Amberlite IR-120($H^+$) strongly acidic cation exchanger and Amberlite IRA-410($CI ^-$) strongly basic anion exchanger resins were used for the separation and preconcentration of Cr(III) and Cr(VI) species, respectively. Optimum condition for preconcentration and speciation was obtained by testing pH of sample and eluent, flow rates of sample and eluent, amount of resins, volume of sample and eluents, and effect of foreign ions. The recommended method has been successfully applied for the preconcentration and determination of chromium species in the dissolved phase of waste water samples collected from a tannery waste water treatment plant in Kayseri, Turkey. The detection limits achieved were 0.73 $\mu$g/L for Cr(III) and 0.81 $\mu$g/L for Cr(VI). Recovery studies showed 99% for Cr(III) and 98% for Cr(VI), for samples spiked with single species.

• 한국초지조사료학회지
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• 제20권3호
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• pp.227-232
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• 2000

Triticale을 사료로서의 특성을 알기 위하여 밀(북견 66호, 월한1호, 치오쿠코무기), 호밀(Amilo, W Warko, Mardar), triticale(Moniko, Presto, Tewo)을 출수기, 유숙기, 호숙기, 황숙기에 수확하여, 건물 수량, 사료성분 및 IVDMD을 조사했다. 1. 재료의 건물수량은 어느 초종도 생육에 따라 증가했고, triticale은 다른 2종의 초종보다 수량성이 우수했다. 2. triticale의 사료성분은 대부분 멸과 호밀의 중간에 위치했다. 3. triticale과 호멸의 IVDMD는 출수기부터 호숙기까지 저하하고, 성숙기에 향상한 것에 반해 밀은 생육에 따라 저하했다. triticale의 IVDMD는 출수기와 성숙기에서 가장 높았고, 유숙기와 호숙기에서는 밀이 높았고, 호밀은 출수기를 제외한 모든 시기에서 최저였다.

• 한국자기공명학회논문지
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• 제9권1호
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• pp.1-20
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• 2005

Vanadium-incorporated aluminophophate molecular sieve VH-SAPO-11 has been studied by electron spin resonanace (ESR) and electron spin echo modulation (ESEM) spectroscopies to determine the vanadium locatin and interaction with various adsorbate molecules. As-synthsized VH-SAPO-11 contains only vanady1 species with distored octahral coordination. After calcinations in $O_2$ and exposure to moisture, only species A is observed with reduced intensities. Species A is suggested as a VO$(H_2O)_2^{2+$} complex coordinate to three framwork oxygen bonded to aluminum. When calcined, hydrate VH-SAPO-11 is dehydrated at elevated temperature, species A loses it water ligands and transforms to $VO^{2+}$ ions coordinated to three framework oxygens (species B). Species B reduces its intensities significantly after treatment with $O_2$at high temperature, thus suggesting oxidation of $v^{4+}$to $v^{5+}$. When dehydrated VH-SAPO-11 contacts with $D_2O$ at room temperature, the ESR signal of species A is observed. This species assumed as a $VO(O_f)_3(D_2O)_2$, by considering 3 framework oxygens. Adsorption of deuterated methanol on dehydrated VH-SAPO-11 results in another new vanadium species D, which is identified as a $VO(CD_{3}OH)$ complex. When deuterated ethanol is adsorbed on dehydrated VH-SAPO-11, another new vanadium species E identified as a $VO(C_{2}H_{5}OD)^{2+}$, is observed. When deuterated propanol is adsorbed on dehydrated VH-SAPO-11, a new vanadium species F identified as a $VO(C_{3}H_{7}OD)$, is observed. Possible coordination geometries of these various complexes are discussed.

• Asian-Australasian Journal of Animal Sciences
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• 제12권3호
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• pp.449-459
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• 1999

Non-conventional roughage (NCR) is shrub and tree fodders, crop residues and agroindustrial oy-products which is not commonly used as livestock feed traditionally and commercially. Eventhough many sources of NCR is available, the farmers perceptions on NCR not only vary from country to country in tropical and sub-tropical Asian-Australasian countries, but also vary from region to region within the country. Chemical composition and nutritive value of NCR are not only vary from species to species but also vary between species within the genera, between provenances/cultivars within the species and such variations are affected by season, climatic zone, topography and land utilization. The nutritive value of NCR can be improved by physical, chemical and biological treatments and conservation. Feeding NCR to ruminant and non-ruminant is not only improve performance of the livestock but also economically feasible. Future direction of NCR is inventarization, exchange information through NCR information centre, integration with either agrisilvicultural, agrisilvipastoral or silvipastoral system, and use of genetic engineering to produce high quality NCR that ultimately become conventional roughage for agroindustry and agribissiness.

• Mycobiology
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• 제36권4호
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• pp.222-227
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• 2008

Upon studying the diversity of fungal endophytes associated with pine trees in Korea, many species of Penicillium were encountered. In this study, we report two species of Penicillium isolated from the needles of Pinus rigida. Based on ID region analysis, cultural and morphological characteristics, the two species were identified as Penicillium fellutanum and P. toxicarium, both of which are new to Korea.

• Bulletin of the Korean Chemical Society
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• 제30권4호
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• pp.810-816
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• 2009

The interactions between four Keggin-type POMs (${SiW_{12}O_{40}}^{4-},\;{PW_{12}O_{40}}^{3-},\;{SiMo_{12}O_{40}}^{4-},\;and\;{PMo_{12}O_{40}}^{3-}$) and glassy carbon (GC) and highly oriented pyrolytic graphite (HOPG) surfaces are investigated in a systematic way. Electrochemical results show that molibdate series POMs adsorb relatively stronger than tungstate POMs on GC and HOPG surfaces. Adsorption of POMs on HOPG electrode surfaces is relatively stronger than on GC surfaces. ${SiMo_{12}O_{40}}^{4-}$ species exhibits unique adsorption behaviors on HOPG surfaces. Surface-confined ${SiMo_{12}O_{40}}^{4-}$ species on HOPG surfaces exhibit unique adsorption behaviors and inhibit the electron transfer from the solution phase species. The catalytic activity of the surface-confined POMs for hydrogen peroxide electroreduction is also examined, where ${PW_{12}O_{40}}^{3-}$ species adsorbed on GC surfaces exhibits the highest catalytic efficiency among the investigated POM modified electrode systems.