• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.1
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• pp.1-12
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• 2021

The present study proposes the modified-stoichiometric model for describing hydration of sodium silicate-based alkaliactivated slag(AAS), and compares the results with the thermodynamic modelling-based calculations. The proposed model is based on Chen and Brouwers(2007a) model with updated database as reported in recent studies. In addition, the calculated results for AAS are compared to those for hydrated portland cement. The maximum difference between the proposed model and the thermodynamic calculation for AAS was at most 20%, and the effects of water-to-binder ratio and activator dosages were identically described by both approaches. In particular, the amount of non-evaporable water was within 10% difference, and was in excellent agreement with the experimental results. Nevertheless, notable deviation was observed for the chemical shrinkage, which is largely dependent on the volume of hydrates and pores.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.1A
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• pp.101-108
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• 2009

The performance of high-early strength pavement concrete for large areas is influenced by the physical and chemical environment during service life. Generally, penetration, diffusion, and absorption of harmful materials that exist outside the concrete cause damage to its structure. Thus, we have to use a mixture for durability to keep the required quality for the planned service life. Moreover, in using high-early-strength cement and accelerators, a high heat of hydration to create the initial strength can cause cracks. Based on evaluations from optimal mix proportions of high-early-strength pavement concrete for large areas, we conducted water permeability, abrasion resistance, freeze-thaw, plastic, drying, and autogenous shrinkage tests. Test result showed that a mix of accelerator and PVA fibers showed excellent performance.

• Journal of the Society of Disaster Information
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• v.19 no.4
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• pp.747-756
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• 2023

Purpose: In this study, a grout material mixed using non-alkaline silica-based materials, which is an eco-friendly injection material to stabilize ground, is investigated to improve conventional problems. Method: The homogel specimens of Eco-Friendly Non-Alkaline Silica Sol (ENASS) and L.W. and S.G.R., representative silicate grouting are manufactured. Physicochemical and engineering properties of the specimens are evaluated in laboratory with uniaxial compression strength, hydraulic conductivity, shrinkage, chemical resistance, elution, fish poison, waste leaching. Result: Laboratory test results show that the ENASS was superior in all aspects compared to the existing injection matirial. The suitability of the grout material with ENASS is investigated with filed tests. Conclusion: The results of laboratory and field tests demonstrates that the grout material with ENASS is eco-friendly material that increases the strength, decreases the permeability, and discharges pollutants without leaching.

• Journal of Radiation Industry
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• v.18 no.3
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• pp.227-233
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• 2024

Polyolefins (PO) are used in various industrial fields due to their excellent mechanical properties, processability, and chemical resistance. However, they have low flame retardancy, and when exposed to high temperatures, there are problem that mechanical properties deteriorate due to oxidation. In this study, we developed PO/metal hydroxide composites that exhibit excellent mechanical strength, heat resistance, and flame retardancy by using antioxidants and radiation crosslinking technology. To improve mechanical strength, heat resistance, and flame retardancy, PO/metal hydroxide/antioxidant composites were prepared and irradiated with an electron beam. Specifically, at temperatures above 200℃, the PO/metal hydroxide composites with primary and secondary antioxidants added and irradiated with a 100 kGy electron beam exhibited excellent thermal stability with a thermal shrinkage rate of less than 3%. In addition, the flame retardancy of the PO/metal hydroxide/antioxidant composites was improved due to enhanced thermal stability from electron beam irradiation and reduced thermal decomposition rate from the antioxidants. These results indicate that radiation crosslinking and antioxidants are effective method to simultaneously achieve mechanical properties, heat resistance, and flame retardancy.

• Membrane Journal
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• v.18 no.1
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• pp.84-93
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• 2008

Poly(vinylidene fluoride) has received much attention in the last several years for the lithium secondary batteries. In this study, to enhance the porosity, PVdF was prepared by phase inversion method using as an additive, PEG (poly(ethylene glycol)), with N,N-dimethylformamid as a solvent. The pores are generated during the solvent and non-solvent exchange process in the coagulation bath filled with non-solvent (distilled water). The surface and cross-section of the membranes were observed with a scanning electron microscopy (SEM). The mechanical property of the membrane was determined by using an universal testing machine (UTM) and thermal property was verified by heat shrinkage. Uniformed sponge structure of PVdF-PEG membrane for the lithium secondary batteries was prepared with 10 wt% of PEG concentration in the PVdF-PEG solution. Porosity, elongation and tensile strengh of the membrane were 87%, 75.45%, and 275. 27 MPa respectively.

• Journal of the Korean Chemical Society
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• v.33 no.3
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• pp.326-331
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• 1989

Superconducting fiber of high Tc $YBa_2Cu_3O_{7-{\sigma}}$ was successfully prepared by the sol-gel method. The stoichiometric mixture of Y, Ba and Cu nitrates was dissolved in water, to which citric acid solution was added. Then ammonium hydroxide was added to the mixture in order to increase the pH to a value between 5.8 and 6.2. The mixture was heated carefully to form a homogeneous colloid sol at 358 K. The solution was viscous enough to draw a long gel fiber, which was then heated at 1223K for 8 hrs. under oxygen partial pressure of $Po_2$ = 1 atm., cooled slowly and annealed at 723K for 13 hrs.. The reacted superconducting sample maintained a fiber form with some shrinkage of its volume. The superconducting transition temperatures (Tc, onset and Tc, offset) of $YBa_2Cu_3O_{7-{\sigma}}$ have been determined to be approximately 95K and 82K, respectively. The superconducting phase was also confirmed by Meissner effect at liquid nitrogen boiling temperature.

• Journal of the Korea Concrete Institute
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• v.14 no.4
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• pp.540-548
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• 2002

The purpose of this study is to analyze the application of oyster shells (OS) as aggregates for concrete. For this purpose, five reference mixes with W/C ratios of 0.4 ∼0.6 at intervals of 0.05 were used. The replacement proportion of OS was varied with ratios of 0, 10, 30, 50 and 100％ by volume of fine or coarse aggregate in the reference mixes. OS was washed and crushed for using as aggregates. New chemical reaction between crushed OS aggregate and cement paste was tested through XRD and SEM analysis. Two strength properties (compressive and flexural) were considered. Strength tests were carried out at the ages of 1, 3, 7, 14 and 28 days. The variations of workability, air content and density, drying shrinkage of the specimens with different proportions of OS were also studied. Finally, the hollow concrete block using OS as a substitute material for fine aggregate was made for testing the application of OS. Experimental results showed that my new chemical reaction did not occur due to mixing OS in concrete. The workability and strengths decreased with increase in proportion of OS. The same trend was observed in density and unit weight, but air content increased due to the inherent pores in OS, which showed a possibility to produce light weight concrete with low strength by using OS as coarse aggregates for concrete. Tests on hollow concrete block showed that the compressive strength and absorption ratio were satisfied with quality requirements when the fine aggregate was substituted with OS up to 50％ in volume.

• Journal of the Korea Institute of Building Construction
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• v.15 no.3
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• pp.281-289
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• 2015

Carbonation of concrete causes reduction of pH and subsequently causes steel corrosion for reinforced concrete structure. However, for plain concrete structure or PC product, it can lead to a decrease in porosity, high density, improvement of concrete, shrinkage-compensation. Recently, based on this theory, research of $CO_2$ curing effect has been performed, but it was mainly focused on its effects on compressive strength using only ordinary portland cement. Researches on $CO_2$ curing effect for concrete containing $CO_2$ reactive materials such as ${\gamma}-C_2S$, MgO haven't been investigated. Therefore, this study has performed experiments under water-binder ratio 40%, and the replacement ratios of ${\gamma}-C_2S$ and MgO were 90%. Micro-chemical analysis, measurement of compressive strength according to admixtures and $CO_2$ curing were investigated. Results from this study revealed that higher strength was measured in case of $CO_2$ curing compared with none $CO_2$ curing for plain specimen indicating difference between 1.08 and 1.26 times, in case of ${\gamma}-C_2S$ 90, MgO 90 specimen, incorporating high volume replaced as much as 90%, it was proven that when applying $CO_2$ curing, higher strength which has difference between 14.56 and 45.7 times, and between 6.5 and 10.37 times was measured for each specimen compared to none $CO_2$ curing. Through micro-chemical analysis, massive amount of $CaCO_3$, $MgCO_3$ and decrease of porosity were appeared.

• Journal of Wetlands Research
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• v.26 no.2
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• pp.139-146
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• 2024

Various injection materials, such as asphalt-based injection materials, urethane-based injection materials, cement- based injection materials, and acrylic-based injection materials, are used for the repair of aged conduits and underground structures with cracks. In this study, research was conducted on an environmentally friendly acrylic- based leak repair material that exhibits good curing properties even in humid conditions and stability in temperature fluctuations. To compare the performance of the improved acrylic leak repair material with the existing acrylate injection material, experiments were conducted using KS standard methods, including underwater length change rate tests, underwater leakage resistance tests, and chemical performance tests. The comparative experiments revealed that the improved acrylic leak repair material showed no changes in shrinkage due to humidity, temperature variations, or chemical reactions compared to the existing acrylate injection material. In the underwater resistance test, the improved acrylic leak repair material did not show any leakage. Additionally, to assess the environmental impact of the improved acrylic leak repair material, acute fish toxicity tests and acute oral toxicity tests were conducted, and the results showed no mortality and no specific concerns with the test specimens. The experimental results led to the conclusion that the improved acrylic leak repair material is considered to be superior in performance, environmentally safe, and harmless to the human body. Based on various experimental results, it is inferred that the improved acrylic leak repair material is suitable for use as a repair material for cracks in manholes and underground structures compared to the existing acrylate repair material. This study aims to propose valuable data for future technological development by evaluating the applicability of acrylic leak repair materials.

• Korean Chemical Engineering Research
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• v.43 no.1
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• pp.146-152
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• 2005

The activated carbon was produced from Sancheong bamboo by carbon dioxide gas activation methods. The carbonization of raw material was conducted at $900^{\circ}C$, and $CO_2$ activation reactions were conducted under various conditions: activation temperatures of $750-900^{\circ}C$, flow rates of carbon dioxide $5-30cm^3/g-char{\cdot}min$, and activation time of 2-5 h. The yield, adsorption capacity of iodine and methylene blue, specific surface area and pore size distribution of the prepared activated carbons were measured. The adsorption capacity of iodine (680.8-1450.1 mg/g) and methylene blue (23.5-220 mg/g) increased with increasing activation temperature and activation time. The adsorption capacity of iodine and methylene blue increased with the $CO_2$ gas quantity in the range of $5-18.9cm^3/g-char{\cdot}min$. But those decreased over those range due to the pore shrinkage. The specific volume of the mesopore and macropore of bamboo activated carbon were $0.65-0.91cm^3/g$. Because of this large specific volume, it can be used to the biological activated carbon process. Bamboo activated carbon phisically adsorbed the $CO_2$ of maximum 106 mg/g-A.C in the condition of 90% $CO_2$ and adsorption temperature of $20^{\circ}C$. The $CO_2$ adsorption ability of bamboo activated carbon was not changed in the 5 cyclic test of desorption and adsorption.