• Title/Summary/Keyword: Chemical release

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A Study on the Application of Criteria for the Classification of Explosive Hazardous Areas in Flammable Liquid Handling Laboratories (인화성액체 취급 연구실의 폭발위험장소 구분에 관한 기준 적용 연구)

  • Min-Ho, Kim;Jun-Seo, Lee;Eun-Hee, Kim;Byung-Chol, Ma
    • Journal of the Korean Institute of Gas
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    • v.26 no.6
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    • pp.1-8
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    • 2022
  • With the development of the chemical industry, related accidents frequently occur, and fire and explosion accidents account for a large proportion. In order to prevent fire and explosion accidents, places that handle flammable liquids are classified according to the Korean Industrial Standards (KSC IEC60079-10-1) in accordance with the relevant laws. The same applies to laboratories dealing with flammable liquids. This paper verified the applicability of the procedure for classifying explosion hazard areas according to the Korean Industrial Standards when flammable liquid release from the laboratory to form an evaporative pool, and also verified the effect of a change in ventilation speed on the release characteristics. Through this, it was found that it was difficult to apply the criteria for the classification of places at risk of explosion according to the Korean Industrial Standards, and special safety measures should be prepared.

Distribution of Nutrients in Dae-Cheong Reservoir Sediment

  • Hwang Jong Yeon;Han Eui Jung;Kim Tae Kehn;Kim Shin Jo;Yu Soon Ju;Yoon Young Sam;Jung Yong Soon;Park Pan Wook
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.2 no.2
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    • pp.169-179
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    • 1998
  • This paper was performed to estimate interrelations between humus level of sediments and nutrient release from sediments in Dae-cheong reservoir. For investigations, sediments were sampled in June and October, in 1997 at fish farms, embayment, and the main stream of Dae-cheong reservoir. Items for investigation are as follows; water content, weight loss on ignition(IG), porosities of sediments, contents of element such as hydrogen, nitrogen, carbon, and nutrient release rates. Water contents and porosities were measured to conjecture the physical trait and grain size trait. Weight loss on ignition was measured to determine the contents of organic substance. For determination of the humus level of sediments, carbon and nitrogen contents were measured by elemental analyzer. As a result of elemental analysis, C/N ratio was determined in the range of $3.0\~13.1$. From the elemental analysis, humus level of Dae-cheong reservoir sediment was estimated from mesohumic state to oligotrophic state. For the determination of nutrient release rate, $PO_4-P$ and $NH_4-N$ concentrations of interstitial water and overlying water were measured. By using the concentration difference between interstitial water and overlying water and using the Fick's diffusion law, the release rates of phosphorus and nitrogen from the sediment samples were calculated. Release rates of nutrients which directly influence to the water quality were $0.05\~8.63mgP/m^2day$ and $4.99\~36.56mgP/m^2day$. It was found that release rate was measured higher in the 1st sampling period than in the 2nd sampling period. For the determination of phosphorus content in sediment, TPs were measured in 807\~1542{\mu}g/g$ in the 1st samling period and $677\~5238{\mu}g/g$ in the End samling period. Phosphorus release rate and phosphorus content were not interrelated each other.

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Synthesis of Triazole-functionalized Phenolic Resin and its Inherent Flame Retardant Property

  • Poduval, Mithrabinda K.K.;Kim, Tae-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.35 no.11
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    • pp.3249-3253
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    • 2014
  • A novel triazole-functionalized phenolic resin was developed, and its thermal and flame-retardant properties were investigated. The triazole group was incorporated as a pendant unit on the phenolic resin via copper-mediated click chemistry between propargylated phenolic resin and benzyl azide. The newly-developed triazole-functionalized phenolic resin showed higher thermal stability and char yield, together with a reduced total heat release (THR), than the non-functionalized bare phenolic resin, indicating enhanced flame retardancy for the triazole-functionalized phenolic resin.

E-beam Irradiated Fragmentation of Thio-Alkyne Cobaltcarbonyl Complex in Gas Phase as Alkyne Precursor

  • Lee, Young Bae;Hwang, Kwang-Jin
    • Rapid Communication in Photoscience
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    • v.5 no.2
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    • pp.16-17
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    • 2016
  • Arylalkyne cobalt complexes 5, 6 were prepared and irradiated with e-beam to study their fragmentation focused in alkyne formation. Thioaryl complex 6 showed facile CO ligand release and generated parent alkyne in 89% relative intensity. Meanwhile, hydroxyaryl complex 5 gave alkyne in 6% relative intensity.

A Study ong the Environmental Management in Chemical Industry: with Relation to Dow Chemical's Environmental Management (화학산업의 환경친화적 경영에 관한 고찰: 다우케미컬사의 환경경영 사례를 중심으로)

  • Kim, Hyun-Soo;Park, Young-Taek
    • Journal of Korean Society for Quality Management
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    • v.28 no.2
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    • pp.192-210
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    • 2000
  • Chemical industry has contributed significantly to the enhancement of quality of human life, but it has been regarded as a major area of environmental problem due to the potential hazards in environment and safety. This paper examines environmental management programs of chemical industry such as RC(Responsible Care) and PRTR(Pollutant Release and Transfer Register). Through the survey of Dow Chernical's environmental management system, it is examined in detail how a leading company in chemical industry has coped with environmental problem companywide.

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Offsite Risk Assessment on Flammable Hazard Site (가연성물질 저장설비의 사고시 사업장외에 미치는 영향평가)

  • Lee, Dong Hoon;Park, Kyo Shik;Kim, Tae Ok;Shin, Dong Min;Shin, Seo Yun
    • Korean Journal of Hazardous Materials
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    • v.3 no.1
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    • pp.52-58
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    • 2015
  • Since the HF release in 2012 in Korea, it became one of the most significant to evaluate consequence to the vicinity of industry facilities handling hazardous materials. BTX plant is selected to assess off-site risk to check whether the facility satisfies the Chemical Control Law by Korea Government. Accident scenarios were listed using process safety information. The scenarios having effect to the off-site were selected and assessed further according to guideline provided by Korea government. Worst case and alternative scenarios including other interested scenarios were evaluated using ALOHA. Each evaluated scenario was assessed further considering countermeasures. The results showed that the facility handling chloric acid is safe enough and needed no further protections at the moment.

Nitric Oxide Delivery using Nanostructures and Its Biomedical Applications (나노 구조체를 이용한 산화질소 전달체에 대한 연구 및 바이오메디컬 응용)

  • Choi, Yunseo;Jeong, Hyejoong;Park, Kyungtae;Hong, Jinkee
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.305-312
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    • 2019
  • The discovery of nitric oxide (NO) as a major signaling molecule in a number of pathophysiological processes - vasodilation, immune response, platelet aggregation, wound repair, and cancer biology - has led to the development of various exogeneous NO delivery systems. However, the development of ideal delivery system for human body application is still left as a challenge due to its high reactivity and short half-life in physiological condition. In this article, an overview of several nano-structures as potential NO delivery system will be presented, along with their recent research results and biomedical applications. Nano-size delivery system has immense advantages compared to others due to its high surface-to-volume ratio and capability for surface modification; thus, it has been proven to be effective in delivering nitric oxide with enhanced performance. Through this novel nano-structure delivery system, we are expecting to achieve sustained release of nitric oxide within adequate range of concentration, which ensures desired drug effects at the target site. Among different nano-structures, in particular, nanoparticle, microemulsion and nanofilm will be reviewed and compared to each other in respect of nitric oxide release profile. The proposed nano-structures for exogeneous NO delivery have a biological significance in that it can be further utilized in diverse biomedical fields as a highly promising therapeutic method.

Development of New NMDA Receptor Agonists/Antagonists

  • Park, No-Sang
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.72-74
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    • 2003
  • Excitatory amino acid (EAA) receptor, particularly NMDA receptor, are now known to be one of major transmitter receptors involved in synaptic excitation. Excessive release of EAA neurotransmitter, glutamate, is an important causative factor in the neurodegenerative processes and can cause neuronal damage and cell death. This excitotoxicity has been shown to be $Ca^{++}$ dependent. (omitted)

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