Rapid Communication in Photoscience

Korean Society of Photoscience (한국광과학회)
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E-beam Irradiated Fragmentation of Thio-Alkyne Cobaltcarbonyl Complex in Gas Phase as Alkyne Precursor

  • Lee, Young Bae (Department of Bio & Chemical Engineering, Hongik University) ;
  • Hwang, Kwang-Jin (Department of Bio & Chemical Engineering, Hongik University)
  • Received : 2016.12.09
  • Accepted : 2016.12.26
  • Published : 2016.12.30
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Abstract

Arylalkyne cobalt complexes 5, 6 were prepared and irradiated with e-beam to study their fragmentation focused in alkyne formation. Thioaryl complex 6 showed facile CO ligand release and generated parent alkyne in 89% relative intensity. Meanwhile, hydroxyaryl complex 5 gave alkyne in 6% relative intensity.

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References

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