• Title/Summary/Keyword: Chemical reactions

Search Result 2,729, Processing Time 0.028 seconds

Chemical Characteristics of Soils in Cheju Island -III. Aluminum Composition of the Citrus Orchard Soils (제주도(濟州道) 토양(土壤)의 화학적(化學的) 특성(特性) 조사(調査) 연구(硏究) -III. 감귤원(柑橘園) 토양(土壤)에서의 알루미늄 특성(特性))

  • Yoo, Sun-Ho;Song, Kwan-Cheol
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.17 no.2
    • /
    • pp.167-172
    • /
    • 1984
  • The aluminum composition of the citrus orchard soils (volcanic ash soil) in Cheju Island was studied. The content of extractable Al was high, especially for the sub-soil. However the exchangeable Al was relatively low : it was only one-tenth of the extractable Al content. The exchangeable Al of the citrus orchard soils decreased with increasing number of years of cultivation. This has resulted from an increase in pH. The content of the extractable Al of the citrus orchard soils also decreased with the increase in number of years of cultivation. This is related to the fact that the application of phosphate fertilizers led to a reduction in Al activity. Therefore, the extractable Al showed a highly significant correlation with the available phosphorus in the top soil. However it was not significantly affected by phosphates in the sub-soil where the available phosphorus was extremely low. The extractable Al content strongly correlated with the organic matter and pH(NaF) in the sub-soil, but the correlation was less significant in the top soil. This suggests that large amounts of the extractable Al are released from the hydrous oxides of Al and that the organically complexed form in the sub-soil and non-extractable due to the reactions with phosphates applied to the top soil.

  • PDF

Design Scheme to Develop Integrated Remediation Technology: Case Study of Integration of Soil Flushing and Pneumatic Fracturing for Metal Contaminated Soil (복합복원기술 개발을 위한 설계안 : 중금속 오염토양을 위한 토양세척과 토양파쇄의 통합 사례 연구)

  • Chung, Doug-Young;Yang, Jae-E.
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.39 no.1
    • /
    • pp.29-37
    • /
    • 2006
  • In remediation of the contaminated soil, it requires to select at least more than two remediation technologies depending on the fate and transport phenomena through complicated reactions in soil matrix. Therefore, methodologies related to develop the integrated remediation technology were reviewed for agricultural soils contaminated with heavy metals. Pneumatic fracturing is necessary to implement deficiency because soil washing is not effective to remove heavy metals in the subsurface soil. But it needs to evaluate the characteristics such as essential data and factors of designated technology in order to effectively apply them in the site. In the remediation site, the important soil physical and chemical factors to be considered are hydrology, porosity, soil texture and structure, types and concentrations of the contaminants, and fate and its transport properties. However, the integrated technology can be restrictive by advective flux in the area which remediation is highly effective although both soil washing and pneumatic fracturing were applied simultaneously in the site. Therefore, we need to understand flow pathways of the target contaminants in the subsurface soils, that includes kinetic desorption and flux, predictive simulation modeling, and complicated reaction in heterogenous soil.

Experiment for Reduction Effectiveness of Pollutants with the Improvement of Infiltration Ability in Vegetation Filter Strip (식생여과대내 침투능력 향상에 따른 오염물질 저감효과에 대한 실험)

  • Lee, Young-A;Choi, I-Song;Oh, Jong-Min
    • Journal of Korea Water Resources Association
    • /
    • v.40 no.2 s.175
    • /
    • pp.183-190
    • /
    • 2007
  • Soil layer in vegetation filter strip is one of the very important factor for reduction of non-point pollutants by physical, chemical and biological reactions of it through infiltration process. This study was carried out to prepare more effective vegetation filter strip through modification of soil layer for river water quality improvement. Therefore, the main aims of this study are to compare and evaluate normal (straighten type) and modified (step type) vegetation filter strip, which make artificially change the soil layer to improve infiltration ability, through bench scale experiments. In the results of this study, vegetation filter strip of step type is much more highly reduction effectiveness of pollutants in surface flow compared with normal vegetation filter strip. In case of below effluent, however, it appeared that the vegetation filter strip modified soil layer showed lower reduction effectiveness of pollutants than the general vegetation filter strip. This result was judged because effluent through the vegetation filter strip of step type passed bigger size of aggregate or sand than the vegetation filter strip of straighten type. If we compare it as a definition of pollutant load to estimate total amount of reduced pollutants by vegetation filter strip, reduced pollutants load by step type showed higher than those by straighten type because below effluent amount relied on total effluent amount was higher at step type (4%) than at straighten type (2%). In conclusion, the vegetation filter strip of step type to improve infiltration effect is much more reduction effectiveness of pollutants than vegetation filter strip of straighten type.

A Study on Exothermic Properties of TiO2/Epoxy Nanocomposites (TiO2/Epoxy 나노복합재의 발열 특성에 관한 연구)

  • Ahn, Seok-Hwan;Ha, Yoo-Sung;Moon, Chang-Kwon
    • Journal of Ocean Engineering and Technology
    • /
    • v.27 no.5
    • /
    • pp.99-104
    • /
    • 2013
  • Recently, various nanoparticles have been used for filler in polymer matrices. The particles of nano size are whether high or not cross-link density in polymer affects the thermal and mechanical properties of one. The properties change as a result of chemical reactions between the nanoparticles and the surface of the polymer. There are two models for nanocomposites: "repulsive interaction" and "attractive interaction" between the nanoparticles and matrix. In this study, the variation in the curing mechanism was examined when nano-size $TiO_2$ was dispersed into an epoxy (Bisphenol A, YD-128) with different curing agents. The results of this study showed that the exothermic temperature and Tg in the case of the nanoparticles used (Jeffamine) (D-180) at room temperature were reduced by an increase in the $TiO_2$ contents because of the "repulsive interaction" between the nanoparticles and the matrix. The tensile strengths were increased by increasing amounts of $TiO_2$ until 3 wt% because of a dispersion strengthening effect caused by the nanoparticles, because of the repulsive interaction. However, such tensile properties decreased at 5 wt% of $TiO_2$, because the $TiO_2$ was agglomerated in the epoxy. In contrast, in the case of the nanoparticles that used NMA and BDMA, the exothermic temperature and Tg tended to rise with increasing amounts of $TiO_2$ as a result of the "attractive interaction." This was because the same amounts of $TiO_2$ were well dispersed in the epoxy. The tensile strength decreased with an increase in the $TiO_2$ contents. In the general attractive interaction model, however, the cross-link density was higher, and tensile strength tended to increase. Therefore, for the nanoparticles that used NMA, it was difficult to conclude that the result was caused by the "attractive model."

Love as Communication: Focusing on Dewey's Concept of Aesthetic Experience (소통으로서의 사랑 - 듀이의 미적 경험을 중심으로 -)

  • Ju, Seon-hee
    • Journal of Korean Philosophical Society
    • /
    • v.130
    • /
    • pp.337-361
    • /
    • 2014
  • The main purpose of this paper is to reconstruct the modern thought of love in terms of Dewey's esthetic experience. In the contemporary Korean society, discussions of love are represented in the two tendencies, scientification of love and idealization of love. In actuality, they support the insistence of impossibility of love by the modern sociologists. The former deals with love as chemical reactions in brain, which is based on physiology and biology. The latter regards hypothetical love through the media as the idea of love and displaces concrete love in reality with it. To see love as the subject catching, understanding, and desiring the object depends upon a narrow concept of experience. It comes from the idea that experience is not doing and suffering in a concrete situation but knowing and understanding the object. In this case, the uniqueness and the qualitativeness with each experience of love are ignored. When these traits of a romantic relationship are disregarded, love cannot help but subordinate to the logic of capitalism. This paper, therefore, attempts to find a new way to understand experience of love, focusing on Dewey's concept of aesthetic experience. I suggest that we can expect the possibility of experience of love if love is experienced in a similar way with aesthetic experience based on emotional interaction, and that the very experience of love leads to growth of our personality. Furthermore, I think this communicative experience makes people to change their community as well as each person's private life.

Influence of Gd0.1Ce0.9O2-δ Interlayer between La0.6Sr0.4Co0.2Fe0.8O3-δ Cathode and Sc-doped Zirconia Electrolyte on the Electrochemical Performance of Solid Oxide Fuel Cells (La0.6Sr0.4Co0.2Fe0.8O3-δ 공기극과 Sc이 도핑된 지르코니아 전해질 사이에 삽입한 Gd0.1Ce0.9O2-δ 중간층이 고체산화물 연료전지의 전기화학적 성능에 미치는 영향)

  • Lim, Jinhyuk;Jung, Hwa Young;Jung, Hun-Gi;Ji, Ho-Il;Lee, Jong-Ho
    • Ceramist
    • /
    • v.21 no.4
    • /
    • pp.378-387
    • /
    • 2018
  • The optimal fabrication conditions for $Gd_{0.1}Ce_{0.9}O_{2-{\delta}}$(GDC) buffer layer and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ (LSCF) cathode on 1mol% $CeO_2-10mol%\;Sc_2O_3$ stabilized $ZrO_2$ (CeScSZ) electrolyte were investigated for application of IT-SOFCs. GDC buffer layer was used in order to prevent undesired chemical reactions between LSCF and CeScSZ. These experiments were carried out with $5{\times}5cm^2$ anode supported unit cells to investigate the tendencies of electrochemical performance, Microstructure development and interface reaction between LSCF/GDC/CeScSZ along with the variations of GDC buffer layer thickness, sintering temperatures of GDC and LSCF were checked, respectively. Electrochemical performance was analyzed by DC current-voltage measurement and AC impedance spectroscopy. Microstructure and interface reaction were investigated by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Although the interfacial reaction between these materials could not be perfectly inhibited, We found that the cell, in which $6{\mu}m$ GDC interlayer sintered at $1200^{\circ}C$ and LSCF sintered at $1000^{\circ}C$ were applied, showed good interfacial adhesions and effective suppression of Sr, thereby resulting in fairly good performance with power density of $0.71W/cm^2$ at $800^{\circ}C$ and 0.7V.

Anti-irritation and Moisturizing Effects of Exopolysaccharide Produced by Grifola frondosa (잎새버섯이 생산하는 세포외 다당체의 보습력과 자극완화 효과)

  • Lee, Bum-Chun;Kim, Jin-Hwa;Bae, Jun-Tae;Lee, Dong-Hwan;Sim, Gwan-Sub;Pyo, Heong-Bae;Choe, Tae-Boo
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.31 no.1 s.49
    • /
    • pp.35-41
    • /
    • 2005
  • We investigated the effects of skin hydration and anti-irritation of exopolysaceharide (GF-glucan) produced from submerged culture of Grifola frondosa. The moisturizing effects and trans-epidermal water loss (TEWL) of GF-glucan in cosmetic products (O/W emulsion) were clinically studied. GF-glucan showed good skin hydration effects when compared with sodium hyaluronate which is a commonly using moisturizer. The skin protective effects of GF-glucan against sodium lauryl sulfate (SLS) were also found. Twice a day application of the CF-glucan to skin reduced local inflammation remarkably. Irritant reactions were assessed by various aspects of skin function, erythema (skin color reflectance), hydration (electrical capacitance) and TEWL. In the human skin test, 5-day treatment of the GF-glucan was found to reduce SLS-induced skin erythema and Improve bier regeneration. Taken all together, GF-glucan should be a very useful cosmetic ingredient, as a moisturizer, and a protecting agent for various skin irritations.

A Study on the Characteristics of Coffee Ground(CG)-RDF by Using Different Drying Method (건조법에 따른 커피박 고형연료의 특성 고찰 연구)

  • Kim, Sang-bin;Ha, Jin-wook
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.20 no.2
    • /
    • pp.451-457
    • /
    • 2019
  • In this study, the characteristics of coffee grounds were reviewed by making them from solid fuel through heat-drying and oil-drying method. The differences in the higher calorific power by each dried sample were compared. And industrial analysis using the thermogravimetric analyzer was considered for applicability to organic waste and oily samples. Before and after drying, the surface of the specimen was observed with SEM equipment and the ingredients were measured through the EDS equipment. As a result, no other hazardous substances, such as heavy metals, were measured. Next, The differences between thermal decomposition and combustion reactions were considered through the TG and DTG curves. As a result, it is that the oil-dried coffee grounds is longer to burn than the heat-dried coffee grounds. Finally, the combustion gases emitted through the thermogravimetric analyzer were collected and the carbon monoxide and carbon dioxide performed qualitative and quantitative analysis using GC over time.

Synthesis and Structural Characterization of β-Carboline Compounds (β-카볼린 화합물의 합성 및 구조분석)

  • Byeon, Hong-Ju;Han, Min-Hui;Moon, Gi-Seong;Jung, Kyung-Hwan;Lee, Hyang-Yeol
    • Journal of the Korean Applied Science and Technology
    • /
    • v.36 no.2
    • /
    • pp.676-684
    • /
    • 2019
  • The Pictet-Spengler reactions have widely known for the organic synthesis or biosynthesis of biologically active compounds, tetrahydro-${\beta}$-carbolines. We have developed the simple and efficient synthetic method for the synthesis of ${\beta}$-carbolines in water. Their chemical structures were characterized by nmr and UPLC/MS/QTOF. Calculated masses of compound 1 ($C_{17}H_{17}N_2$ 249.1392), 2 ($C_{17}H_{23}N_2$ 255.1861), 3 ($C_{19}H_{21}N_2O_3$ 325.1552) and 4 ($C_{19}H_{19}N_2O$ 279.1497) were almost identical with the detected masses of compound 1 (249.1315), 2 (255.1789), 3 (325.1460) and 4 (279.1364) respectively. Those synthesized four compounds showed strong antibiotic activity against the common E. coli.

Pollution characteristics of PM2.5 observed during January 2018 in Gwangju (광주 지역에서 2018년 1월 측정한 초미세먼지의 오염 특성)

  • Yu, Geun-Hye;Park, Seung-Shik;Jung, Sun A;Jo, Mi Ra;Jang, Yu Woon;Lim, Yong Jae;Ghim, Young Sung
    • Particle and aerosol research
    • /
    • v.15 no.3
    • /
    • pp.91-104
    • /
    • 2019
  • In this study, hourly measurements of $PM_{2.5}$ and its major chemical constituents such as organic and elemental carbon (OC and EC), and ionic species were made between January 15 and February 10, 2018 at the air pollution intensive monitering station in Gwangju. In addition, 24-hr integrated $PM_{2.5}$ samples were collected at the same site and analyzed for OC, EC, water-soluble OC (WSOC), humic-like substance (HULIS), and ionic species. Over the whole study period, the organic aerosols (=$1.6{\times}OC$) and $NO_3{^-}$ concentrations contributed 26.6% and 21.0% to $PM_{2.5}$, respectively. OC and EC concentrations were mainly attributed to traffic emissions with some contribution from biomass burning emissions. Moreover, strong correlations of OC with WSOC, HULIS, and $NO_3{^-}$ suggest that some of the organic aerosols were likely formed through atmospheric oxidation processes of hydrocarbon compounds from traffic emissions. For the period between January 18 and 22 when $PM_{2.5}$ pollution episode occurred, concentrations of three secondary ionic species ($=SO{_4}^{2-}+NO_3{^-}+NH_4{^+}$) and organic matter contributed on average 50.8 and 20.1% of $PM_{2.5}$, respectively, with the highest contribution from $NO_3{^-}$. Synoptic charts, air mass backward trajectories, and local meteorological conditions supported that high $PM_{2.5}$ pollution was resulted from long-range transport of haze particles lingering over northeastern China, accumulation of local emissions, and local production of secondary aerosols. During the $PM_{2.5}$ pollution episode, enhanced $SO{_4}^{2-}$ was more due to the long-range transport of aerosol particles from China rather than local secondary production from $SO_2$. Increasing rate in $NO_3{^-}$ was substantially greater than $NO_2$ and $SO{_4}^{2-}$ increasing rates, suggesting that the increased concentration of $NO_3{^-}$ during the pollution episode was attributed to enhanced formation of local $NO_3{^-}$ through heterogenous reactions of $NO_2$, rather than impact by long-range transportation from China.