• Title/Summary/Keyword: Chemical process industry

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A Preliminary Design Concept of the HYPER System

  • Park, Won S.;Tae Y. Song;Lee, Byoung O.;Park, Chang K.
    • Nuclear Engineering and Technology
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    • v.34 no.1
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    • pp.42-59
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    • 2002
  • In order to transmute long-lived radioactive nuclides such as transuranics(TRU), Tc-99, and I- l29 in LWR spent fuel, a preliminary conceptual design study has been performed for the accelerator driven subcritical reactor system, called HYPER(Hybrid Power Extraction Reactor) The core has a hybrid neutron energy spectrum: fast and thermal neutrons for the transmutation of TRU and fission products, respectively. TRU is loaded into the HYPER core as a TRU-Zr metal form because a metal type fuel has very good compatibility with the pyre- chemical process which retains the self-protection of transuranics at all times. On the other hand, Tc-99 and I-129 are loaded as pure technetium metal and sodium iodide, respectively. Pb-Bi is chosen as a primary coolant because Pb-Bi can be a good spallation target and produce a very hard neutron energy spectrum. As a result, the HYPER system does not have any independent spallation target system. 9Cr-2WVTa is used as a window material because an advanced ferritic/martensitic steel is known to have a good performance under a highly corrosive and radiation environment. The support ratios of the HYPER system are about 4∼5 for TRU, Tc-99, and I-129. Therefore, a radiologically clean nuclear power, i.e. zero net production of TRU, Tc-99 and I-129 can be achieved by combining 4 ∼5 LWRs with one HYPER system. In addition, the HYPER system, having good proliferation resistance and high nuclear waste transmutation capability, is believed to provide a breakthrough to the spent fuel problems the nuclear industry is faced with.

Automotive Door Impact Beam Development using Thermoplastic Composite (열가소성 복합재 적용 자동차 도어 임팩트 빔 개발)

  • Kim, Won-Seock;Kim, Kyung-Chul;Jung, Woo-Cheol;Kim, Hwa-nam
    • Composites Research
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    • v.33 no.6
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    • pp.383-389
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    • 2020
  • Thermoplastic composite is introduced to design an automotive door impact beam, and the manufacturing process is demonstrated. The safety regulation for vehicles has been steadily tightened, and weight-reduction has become a mandatory factor in the automotive industry. Hence, both high-performance and lightweight are demanded for automotive components. The aim of the present study is to develop an automotive door impact beam using fiber-reinforced thermoplastic composites to reduce the weight of the impact beam while increasing its mechanical performance. A new production method which combines continuous fiber-reinforced composite and LFT(Long Fiber-reinforced Thermoplastic) is implemented by using insert injection molding process. The mechanical performance of the composite impact beam was evaluated using 3-point bending tests. Thermoplastic composite will expand its application range to various automotive components due to its light-weight design capability and high productivity.

A Review on Ceramic Based Membranes for Textile Wastewater Treatment (염색폐수의 처리를 위한 세라믹 분리막에 대한 고찰)

  • Kwak, Yeonsoo;Rajkumar, Patel
    • Membrane Journal
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    • v.32 no.2
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    • pp.100-108
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    • 2022
  • Among various industries, the textile industry uses the largest amount of water for coloring textiles which leads to a large amount of wastewater containing various kinds of dye. There are various methods for the removal of dye such as flocculation, ozone treatment, adsorption, etc. But these processes are not much successful due to the issue of recycling which enhances the cost. Alternatively, the membrane separation process for the treatment of dye in wastewater is already documented as the best available technique. Polymeric membrane and ceramic membrane are two separate groups of separation membranes. Advantages of ceramic membranes include the ease of cleaning, long lifetime, good chemical and thermal resistance, and mechanical stability. Ceramic membranes can be prepared from various sources and natural materials like clay, zeolite, and fly ash are very cheap and easily available. In this review separation of wastewater is classified into mainly three groups: ultrafiltration (UF), microfiltration (MF), and nanofiltration (NF) process.

Functional graphene sheets-TiO2 nanocomposites and their photocatalytic performance for wastewater treatment

  • R. Aitbelale;A. Timesli;A. Sahibed-dine
    • Advances in nano research
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    • v.15 no.4
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    • pp.295-304
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    • 2023
  • In this paper, a powerful photocatalyst based on carbon nanocomposite is developed in order to obtain a new material applicable in water treatment and especially for the discoloration of effluents used in the textile industry. For that, TiO2-graphene nanocomposites have been successfully synthesized by a mixture of Functionalized Graphene Sheet (FGS) and tetrachlorotitanium complexes to form FGS-TiO2 nanocomposite. In the presence of an anionic surfactant, we used a new chemical process to functionalize graphene sheets in order to make them an excellent medium for blocking and preventing the aggregation of TiO2 nanoparticles. The components of these nanocomposites are characterized by means of X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM), which confirms the successful formation of the FGS-TiO2 nanocomposite. It was found that the TiO2 nanoparticles were dispersed uniformly on the graphene plane which possesses better charge separation capability than pure TiO2. The FGS-TiO2 nanocomposites exhibited higher photocatalytic activity compared to pure TiO2 for the removal of three dyes: such as Methylene Blue (MB), Bromophenol Blue (BB) and Alizarin Red-S (AR) in water. The removal process was fast and more efficient with FGS-TiO2 nanocomposite in daylight (in the absence of UV irradiation) compared to pure TiO2 nanoparticles without and under UV in all pH range.

Development of Flavouring Ontology for Recommending the Halal Status of Flavours

  • Siti Farhana Mohamad Hashim;Shahrul Azman Mohd Noah;Juhana Salim;Wan Aida Wan Mustapha
    • Journal of Information Science Theory and Practice
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    • v.12 no.2
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    • pp.22-35
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    • 2024
  • There has been a growing interest in halal-related ontology research in recent years, as ontology has gained recognition in the halal industry. This paper discusses the development of a flavouring ontology that will assist halal management auditors in predicting the halal status of flavours in order to process food producers' applications for halal certification. The development of a flavouring ontology is based on multiple references, because the auditors of halal management divisions must consult a variety of sources independently in order to determine the halal status of flavourings. The process includes 1) determining the ontology goal and scope, 2) building ontologies, and 3) evaluating the ontologies. The researcher used Protégé to design the ontologies, and Phyton was used to develop a prototype based on flavouring ontology. The developed ontology consists of four classes, nine sub-classes, and 11 relationships. The evaluation of the ontology using the prototype revealed that the majority of experts were satisfied with the information generated by the ontology in the prototype, particularly in relation to synonyms and the hierarchical structure of a flavour. However, the experts suggest improvements in terms of flavour metadata, especially on raw materials and natural occurrence data, so that the flavour information retrieved is comprehensive and accurate.

A state-of-the-art analysis of fresh, mechanical, durability and microstructural characterization of wastewater concrete

  • Nabil Ben Kahla;Ali Raza;Muhammad Arshad;Ahmed Babeker Elhag
    • Advances in concrete construction
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    • v.17 no.2
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    • pp.93-110
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    • 2024
  • The process of concrete production consumes an immense volume of water, with approximately one billion metric tons of freshwater being utilized for tasks such as aggregate washing, fresh concrete production, and concrete curing. The accessibility of clean water for the public is hindered by the limited availability of water resources, primarily due to the rapid expansion of industries such as tanneries, stone quarries, and concrete manufacturing. These industries not only consume substantial amounts of freshwater but also generate significant volumes of various types of waste. Therefore, the use of fresh water in concrete production should be minimized. Few studies have reviewed the production of concrete using wastewater to derive practical and applicable findings for the industry. Thus, this study thoroughly explores the physical and chemical effects of wastewater on concrete, examining aspects like durability, hardened properties, and rheological characteristics. It identifies key factors that can compromise concrete properties when exposed to wastewater. The scarcity of research on integrating wastewater into concrete production underscores the urgent necessity for innovative approaches and methodologies in this field. While the inclusion of wash water typically reduces the workability of fresh concrete, it often enhances its compressive strength. Notably, significant improvements have been observed when using tertiary processed wastewater, wash water, polyvinyl alcohol-based wash water (PVAW), and reclaimed water in the concrete mixing process. The application of tertiary treatment to wastewater resulted in a notable enhancement of compressive strength, showing increases of up to 7%. In contrast, wastewater treated through secondary methods experienced a decline in strength ranging from 9% to 18% over a period of six months. However, the use of reclaimed wastewater demonstrated an improvement in strength by 8% to 17%, depending on the concentration level ranging from 25% to 100%. In contrast, the utilization of secondary processed wastewater and industrial water has a minimal impact on the concrete's strength.

Theoretical Proposal for the Mix Design of Recycled Cement Utilizing Inorganic Construction Wastes (무기계 건설폐기물을 이용한 재생시멘트 배합설계에 관한 이론적 제안)

  • Kim, Ji-Hoon;Tae, Sung-Ho;Song, Hun;Shin, Hyeon-Uk
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.250-258
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    • 2016
  • Until now, the construction material industry has been recognized as a typical environmental destruction industry. However, recently, in order to reduce $CO_2$ emission, the main cause of environmental problems, lots of studies have been done about recycling industrial by-products and construction wastes. Therefore, the purpose of this study is to confirm whether it is possible to use as an alternative material in cement production process as a part of the development of recycled cement using an inorganic construction waste. For this study, the inorganic construction wastes was collected and analyzed each chemical component by XRF(X-ray Fluorescene). Also, the inorganic construction wastes were combined based on the chemical component of the cement, to perform this analysis. As a result, when the inorganic construction wastes was properly combined, it is possible to consider the development of the recycled cement used the inorganic construction wastes.

Studieson Titanium Enamel Frit (티타늄琺瑯후릿트에 關한 硏究)

  • Lee, Chong-Keun;Han, Ki-Sung
    • Journal of the Korean Chemical Society
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    • v.4 no.1
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    • pp.18-26
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    • 1957
  • There are two problems to be solved by our efforts in the enamel frit. One is how we can cover the enamel frit thin with complete milk white as possible, and the other is how it can be, made resistant for chemicals than before one. The frit which can solved the two problems just mentioned above is titanium enamel frit. This frit has been developed in America after War Ⅱ, and now the research for concerning antimony frit into titanium frit is under development entirely. In order to develope the enamel industry in Korea, it is urgent problem to convert antimony frit into titanium frit. By the way the titanium frit is emulsified titanium oxide crystal which made through reheating the supersaturated solution of titanium oxide in the basis of glass. Unfortunately, there are many obscure points in active fact or which influence on its composition and characteristics yet. However, this task was tried for the first in Korea. As first step, the test was carried on the reference books, and we can be possible convert antimony frit into titanium frit as a result of this experiment. As a conclusion, for the purpose of developing the enamel industry in Korea, we studied that the research for converting antimony enamel frit which has been used popularly into titanium enamel frit which is more economic and resistant for chemicals. As a result of experiments, the following points concerning with titanium frit have become clearly. 1. It is better when the composition of titanium enamel frit has as following table.Man Duck San Silica 24 An Yang Feldspar 20 Borax 28 Sodium Nitrate 4 Cryolite 7 Calcium Carbonate 3.6∼1 Titanium Oxide 10 Calcium phosphate 0 ∼3.2 Calcium Fluoride 0∼1.8 Antimony Oxide 0∼0.5 2. The amount of $TiO_2$, to be added is $10%\;to\;12{%,\;CaF_2\;is\;under\;1.8%,\;P_2O_5\;is\;under\;1.6%,\;Sb_2O_3\;is\;under\;0.5%$. 3. In the titanium frit, the limit of iron oxide amount to be included is under 0. 5%. 4. Comparing the titanium enamel frit with antimony enamel frit not only the titanium frit can be savely 20.6% in the price of raw materials, but one time of glazing and heating process is omitted in each case, and it is known the titanium frit is more resistant for chemicals than antimony frit.

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Calcium Removal from Effluent of Electronics Wastewater Using Hydrodynamic Cavitation Technology (수리동력학적 캐비테이션을 이용한 전자폐수 처리수에 함유된 칼슘저감에 관한 연구)

  • Park, Jin-Young;Kim, Sun-Jip;Lee, Yong-Woo;Lee, Jae-Jin;Hwang, Kyu-Won;Lee, Won-Kwon
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.6
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    • pp.715-721
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    • 2007
  • Residual calcium concentration is high, in general, at the effluent of the fluoride removal process in the electronics industry manufacturing semiconductor and LCD. To increase the stability of the membrane process incorporated for reuse of wastewater, the residual calcium is required to be pre-removed. Hyperkinetic Vortex Crystallization(HVC) process was installed in the electronics industry manufecturing semi conductor as a pilot scale for accelerating calcification of calcium ion. Compared to the conventional soda ash method, the 31% higher calcium removal efficiency was achieved when HVC was applied at the same sodium carbonate dosage. In order to maintain the economic calcium removal target of 70% preset by manufacturer, the dosing concentration of the soda ash was 530 mg/L based on influent flowrate. The seed concentration in the reactor was one of the critical factors and should be maintained in the range of $800\sim1,200mg$ SS/L to maximize the calcium removal efficiency. The calcite production rate was 0.30 g SS/g $Na_2CO_3$ in the average. The economic HVC passing time of the mixture was in the range of $2\sim5$ times. Relatively, stable calcium concentration was maintained in the range of $30\sim72$ mg/L(average 49 mg/L) although the calcium concentration in the feed was severely fluctuated with $74\sim359$ mg/L(average 173 mg/L). The HVC process was characterized as environment-friendly technology reducing chemical dosage and chemical sludge production and minimizing maintenance cost.

Effect of Metal Salt Coagulant on Membrane Fouling During Coagulation-UF Membrane Process (응집-UF 막 공정의 적용시 금속염 응집제가 막오염에 미치는 영향)

  • Jung, Chul-Woo;Shim, Hyun-Sool;Sohn, In-Shik
    • Korean Chemical Engineering Research
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    • v.45 no.5
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    • pp.523-528
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    • 2007
  • The objectives of this research are to investigate the mechanism of coagulation affecting UF, find out the effect of metal salt coagulant on membrane fouling. Either rapid mixing + UF or slow mixing + UF process caused much less flux decline. For PACl coagulant, the rate of flux decline was reduced for both hydrophilic and hydrophobic membrane than alum due to higher formation of flocs. In addition, the rate of flux decline for the hydrophobic membrane was significantly greater than for the hydrophilic membrane, regardless of pretreatment conditions. In general, Coagulation pretreatment significantly reduced the fouling of the hydrophilic membrane, but did little decrease the flux reduction of the hydrophobic membrane. When an Al(III) salt is added to water, monomers, polymers, or solid precipitates may form. Different Al(III) coagulants (alum and PACl) show to have different Al species distribution over a rapid mixing condition. During the rapid mixing period, for alum, formation of dissolved Al(III) (monomer and polymer) increases, but for PACl, precipitates of $Al(OH)_{3(s)}$ increases rapidly. This experimental results pointed out that precipitates of $Al(OH)_{3(s)}$ rather than dissolved Al(III) formation is major factor affecting flux decline for the membrane.