• Title/Summary/Keyword: Chemical phenomena

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Study of the Trophic State Assessment and Analysis of Water Quality Improvement by Dredging in Hwoiya Reservoir (회야호 부영양화 평가 및 준설에 의한 수질개선 효과 분석 연구)

  • Suh, Myung-Gyo;Lee, Sang-Hyeon;Suh, Jung-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.11
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    • pp.6943-6951
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    • 2014
  • The trophic state assessment of the Hwoiya reservoir was estimated using the Trophic state indices (TSIs) of Carlson and Aizaki using the transparency and concentrations of chlorophyll-a and total phosphorus obtained from two sites of the reservoir. The TSIs assessments showed that eutrophic phenomena occur frequently in the Hwoiya reservoir. In addition, strategies to reduce the phosphorus especially would be prepared because the Hwoiya reservoir exceeded phosphorus-limiting state of 17 < TN/TP (total nitrogen/total phosphorus). Three scenarios for a simulation of the dredging effect of sediments on the water quality using the WASP7 model were made at two sites, which were 10% (scenario 1), 40% (scenario 2) and 60% elution of the pollutants from sediments (scenario 3). In the most elution case (60%), scenario 3, it was considered that 6.4% TN and 9.3% TP at site 1, and 3.9% TN and 5.6% TP at site 2 could be reduced.

Effect to the Copper System Pigments by the Nitrogen Dioxide(NO2) Gas (이산화질소(NO2)가 구리(Cu)계통 안료에 미치는 영향)

  • Kim, Ji Won;Lee, Hwa Soo;Lee, Han Hyeong;Kim, Myoung Nam;Kang, Dai Ill
    • Journal of Conservation Science
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    • v.31 no.4
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    • pp.403-409
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    • 2015
  • Malachite and Azurite are the typical copper system pigments which used the mural paintings since ancient times. The mural painting is at risk for damages of the painting layer by atmosphere gas because it is exposed at external environment. In this study, it did experiment about an effect to Malachite and Azurite by environmental pollution gas($NO_2$, $CO_2$, $SO_2$) then analysis and estimate about test for pieces using mural painting colored that two pigments. As a result, Malachite and Azurite were changed on $NO_2$ but not changed $CO_2$ and $SO_2$. Especially as the concentration of $NO_2$ is increased, exfoliation of the pigment layer weave remarkably formed pores on the pigment particles on SEM, the phenomenon to be pieces were observed together with smaller particles. In the case of Malachite that were exposed to $NO_2$ gas, new compounds(Rouaite : dicopper (nitrate(V) trihydroxide, $Cu_2(NO_3)(OH)_3$)) was appeared by XRD analysis. Therefore, there had been able to verify the fact that the cause exfoliation and discoloration phenomena accompanied by chemical changes for Malachite and Azurite.

Effect of Bioluminescence Stimulating Agent of the Genetically Engineered Strain KG1206 on the Monitoring of the Petroleum Hydrocarbon Contaminated Groundwater Samples (발광유전자 재조합 균주 활성 촉진 조건이 석유계 탄화수소 오염지하수 모니터링에 미치는 영향)

  • Ko, Kyung-Seok;Kong, In-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.1
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    • pp.79-84
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    • 2008
  • This paper describes the application of bioluminescence stimulating agents on a genetically engineered microorganism, Pseudomonas putida mt-2 KG1206, to monitor toluene analogs using in groundwater samples from petroleum hydrocarbon contaminated sites. The maximum bioluminescent response with pure chemicals followed in the order: m-methyl benzyl alchohol > m-toluate > toluene > m-xylene > benzoate > p-xylene > o-xylene. Generally, the bioluminescence production of strain mixed with groundwater samples was dependent on the contaminated total inducer concentrations. However, few samples showed opposite results, where these phenomena may be caused by the complexicity of environmental samples. Two chemicals, SL(sodium lactate) and KNO$_3$, were tested to determine a better bioluminescence stimulant. Both chemicals stimulate the bioluminescence activity of strain KG1206, however, a slightly high bioluminescence was observed with nitrogen chemical. This selected stimulant was then tested on samples collected from contaminated groundwater samples. The bioluminescence activity of all samples mixed with the strain was stimulated with KNO$_3$ amendment. This suggests that the low bioluminescence activity exhibited by the environmental groundwater samples can be stimulated by amending the culture with a proper agent, such as nitrogen compound. These findings would be useful, especially, when strain was used to monitor the groundwater samples contaminated with low inducer contaminants. Overall, the results of this study found the ability of bioluminescence producing bacteria to biosensor a specific group of environmental contaminants, and suggest the potential for more efficient preliminary application of this engineered strain in a field-ready bioassay.

Design Parameters of Sequencing Batch Reactor treating ship sewage (연속 회분식 공정(SBR)을 이용한 선박 오 ${\cdot}$ 폐수처리 설계인자 도출)

  • Park, Sang-Ho;Kim, In-Soo
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.29 no.1
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    • pp.293-298
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    • 2005
  • Lab scale experimental study was carried out for SBR process, to investigate the effects of influent ship sewage organic compound removal and Bacillus sp. state on design parameters. This process was able to remove nitrogen and phosphorus as well as organic matter efficiently. More than 95% of chemical oxygen demand(COD) were removed. In addition, about 97% of total nitrogen (T-N) was reduced. The total phosphorus(T-P) reduction averaged 93%. The performance load of SBR process was shown to be 0.095kg ${\cdot}$ TOC/$m^{3}$ ${\cdot}$ day. The pH was decreased from 8.1 to 7.0 within 30 min and increased to 7.3 at the end of anoxic stage, and these phenomena were explained. The sluge produced in the SBR process is characterized by low generation rate (about 0.36kg ${\cdot}$ MLSS/kg ${\cdot}$ TOC) and excellent settleability. The number of Bacillus sp. in the SBR was 24.2%, indicating that Bacillus sp. was a predominant species in the reactor.

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Glaze from Wood Ashes and their Color Characteristics (여러 가지 나무재를 이용한 도자기용 유약제조와 색상 특성)

  • 한영순;이병하
    • Journal of the Korean Ceramic Society
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    • v.41 no.2
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    • pp.158-164
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    • 2004
  • This study is to analyze the characteristics of typical Korean wood ashes from twelve trees, oak tree needles and pine bark, which are common in the area, and to suggest their applications in ash glaze making. The chemical analysis of the ashes shows that the main component of wood ash is CaO while wood bark ash consists of $SiO_2$, and leaf ash consists of CaO and $SiO_2$. The results of the study are as follows: Ashes made from the wood of Acasia, Popular and Jujube contained relatively high amounts of Fe$_2$ $O_3$ and MgO compared to other tree ashes. The ashes had yellowish green color glaze. From the result of W analysis they presented the highest chroma. Therefore these ashes are good for making transparent glaze. From the result of W analysis Grapevine, pear and oak wood ashes containing the highest amounts of Fe$_2$ $O_3$, MgO, P$_2$O$\_$5/ and MnO presented yellowish green color glaze compared to other ashes are suitable for making opaque glazes because of their showing stable and opacity phenomena. Pine tree, Platanus and Zelkova wood ashes consist of high amounts of CaO and P$_2$O$\_$5/ compared to other tree ashes. So they showed the most vivid and bluish green color glaze among 12 ashes. Therefore, they would make a good celadon glaze. Birch, oak and chestnut tree ashes have high content or MnO which affects on glaze color with small amount. These ashes presented yellowish green color not as much strong as Acacia ash, Poplar ash, Jujube tree ash. These are good for Irabo glaze.

Nitrogen Top Dressing for Improving Feed Value of Rice Straw (벼짚의 사료가치(飼料價値) 향상(向上)을 위(爲)한 질소추비(窒素追肥))

  • Kim, Yung Sup;Park, Hoon;Park, Young Sun
    • Korean Journal of Soil Science and Fertilizer
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    • v.6 no.3
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    • pp.179-183
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    • 1973
  • For the increase of protein content in the straw without detrimental effect on grain yield by top dressing with various nitrogen amount IR667 (Suwon 214) and Jinheung were grown under field condition and the value as feed was investigated by chemical analysis on the harvested straw. 1. In straw IR667 was higher in crude protein, crude fiber and ash, and lower in total carbohydrate than Jinheung, and crude fat content was not much different. 2. The contents of crude protein and total carbohydrate increased with nitrogen level but crude fiber, crude fat and ash decreased, and those phenomena were clear in IR667. 3. The content of phosphorus in straw decreased with increasing nitrogen level more clearly in Jinheung. 4. Protein content was greatly increased in brown rice and calcium content tended to decrease with the increase of nitrogen application amount. 5. Country mean of crude protein in straw was 4.06% much lower than that of mixed wild grasses and forages (6.71) but crude protein could be increased above that of wild sources, moreover with grain yield increase by the improvement of nitrogen fertilizer application.

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Hydrogeochemistry of Groundwaters at the Gogum island area in Jeonnam, Korea (전남 고금도 지역 지하수의 수리지구화학)

  • Park, Cheon-Young;Ahan, Kun-Sang;Jeong, Youn-Joong;Shin, In-Hyun
    • Journal of the Korean earth science society
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    • v.23 no.6
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    • pp.474-485
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    • 2002
  • The object of this study is to investigate the contamination degree and the interpretation of sea water intrusion phenomena with hydrogeochemical and hydrogen-oxygen stable isotope of coastal aquifer in the Gogum area, Korea. The physical characteristics of groundwaters is the neutral pH condition and transitional Redox environments, and groundwater is affected by sea water & surface water. The chemical properties of groundwaters are showing an increase in contamination owing to the sea water intrusion, waste water from the surface and agricultural chemicals. In the case of chloride, 6 samples of the groundwater in the study area are in excess of the drinking water standard. The Piper diagram shows the contamination in GG-4 and 14 by sea water intrusion. GG-3, 7 and 13 dominate the Na-HCO$_{3}$ type water and regional (GG-14) is indicated to dominate the Na-Cl type water such as sea water. According to the Sl (saturation index), sea water is oversaturated with respect to calcite and dolomite, GG-3, 14 and 18 are approaching the saturation state. The hydrogen-oxygen stable isotope ratio of groundwaters originates in the meteoric water, and groundwaters of GG-1, 5 and 14 display high oxygen isotope value due to surface water trespass and sea water intrusion. The result of this study, GG-14 is contaminated by sea water intrusion, groundwaters expected GG-3, 7 and 13 is in progress to artificial pollution and sea water intrusion.

Internal Flow Analysis of Urea-SCR System for Passenger Cars Considering Actual Driving Conditions (운전 조건을 고려한 승용차용 요소첨가 선택적 촉매환원장치의 내부 유동 해석에 관한 연구)

  • Moon, Seong Joon;Jo, Nak Won;Oh, Se Doo;Lee, Ho Kil;Park, Kyoung Woo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.3
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    • pp.127-138
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    • 2016
  • Diesel vehicles should be equipped with urea-selective catalytic reduction(SCR) system as a high-performance catalyst, in order to reduce harmful nitrogen oxide emissions. In this study, a three-dimensional Eulerian-Lagrangian CFD analysis was used to numerically predict the multiphase flow characteristics of the urea-SCR system, coupled with the chemical reactions of the system's transport phenomena. Then, the numerical spray structure was modified by comparing the results with the measured values from spray visualization, such as the injection velocity, penentration length, spray radius, and sauter mean diameter. In addition, the analysis results were verified by comparison with the removal efficiency of the nitrogen oxide emissions during engine and chassis tests, resulting in accuracy of the relative error of less than 5%. Finally, a verified CFD analysis was used to calculate the interanl flow of the urea-SCR system, thereby analyzing the characteristics of pressure drop and velocity increase, and predicting the uniformity index and overdistribution positions of ammonia.

Analysis of Effects on SWAT Estimation of Warm-Up Period

  • Lee, Ji-Won;Moon, Jong-Pil;Woo, Won-Hee;Kum, Dong-Hyuk;Kim, Ki-Sung;Lim, Kyoung-Jae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2011.05a
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    • pp.260-260
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    • 2011
  • SWAT is semi-distributed and continuous-time distributed simulation watershed model, which can simulate point and nonpoint source pollutants as well as hydrology and water quality. It was developed to predict the effects of alternative management decisions on water, sediment, and chemical yields with reasonable accuracy. It is able to predict and manage hydrology, sediments, nutrients, and pesticides with Best Management Practices (BMPs) in a watershed. SWAT model also has potential for use in ungauged basins to predict streamflow and baseflow from saturated source area in watersheds. According to various cultivation practices and climate change, SWAT model is available to analyze relative change in hydrology and water quality. In order to establish optimum management of water quality, both monitering and modeling have been conducted actively using SWAT model. As SWAT model is computer program to simulate a lot of natural phenomena, it has limitation to predict and reflect them with on hundred percent accuracy. Thus, it is possible to analyze the effect of BMPs in the watershed where users want to simulate hydrology and water quality only if model accuracy and applicability are assessed first of all and the result of it is well for the study watershed. For assessment of SWAT applicability, most researchers have used $R^2$ and Nash and Sutcliffe Efficiency (NSE). $R^2$ and NSE are likely to show different results according to a warm up period and sometimes its results are very different. There have been hardly any studies of whether warm up period can affect simulation results in SWAT model. In this study, how warm up period has a effect on SWAT results was analyzed and a appropriate warm up period was suggested. Lots of SWAT results were compared after using measured data of Soyanggang-dam watershed and applying various warm up period (0 ~ 10 year(s)). As a result of this study, when there was no warm up period, $R^2$ and NSE were 0.645, 0.602 respectively, when warm up period was 2 years, $R^2$ and NSE were 0.648, 0.632, and when warm up period was 4 years, $R^2$ and NSE were 0.663, 0.652 separately. Through this study, sensitive analysis of warm up period in SWAT model was conducted, and this study could give a guideline able to simulate hydrology and water quality for more accuracy than before as users change a lot of warm up periods as well as any simulation parameters.

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Physico-chemical Properties of Bracken (Pteridium aquilinum) Root Starch - II. Physical Properties- (고사리(Pteridium aquilinum) 뿌리 전분의 이화학적 특성에 관한 연구 -제2보 : 전분의 물리적 특성-)

  • Jo, Jae-Sun;Kim, Sung-Kon;Lee, Ke-Ho;Kwon, Tai-Wan
    • Korean Journal of Food Science and Technology
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    • v.13 no.2
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    • pp.133-141
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    • 1981
  • The gelatinization phenomena of bracken root starch were examined by means of the loss of birefringence, degree of digestibility by amylase and X-ray diffraction. These results indicated that gelatinization temperature of the starch was $55{\sim}60^{\circ}$ and over 95% of starch were gelatinized at the temperature between 60 and $70^{\circ}C$. The swelling power of the bracken root starch was much less steeper than that of potato or tapioca starch. Amylograph data on the various starch concentrations showed the pasting temperature of $62{\sim}68^{\circ}$, peak height of $80{\sim}840$ Brabender unit (BU) and peak after cooling to $50^{\circ}C$ of $110{\sim}555\;BU.$. According to the information obtained from amylograph data, the bracken root starch showed low set back. The rate of retrogradation of the starch as tested by Texturometer was slower and faster than that of potato and tapioca starches, respectively.

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