• Title/Summary/Keyword: Chemical phenomena

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Analyses on the Increment of Surface Hydrophobicity of Epoxy Composites by Thermal Treatment (열철리에 따른 Epoxy 복합재료의 표면 소수성증가에 관한 해석)

  • Lim, Kyung-Bum;Lee, Beak-Su;Chung, Mu-Yong;Lee, Duck-Chool
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.4
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    • pp.153-160
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    • 2001
  • In order to analyze the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to high temperature. Then, the degradation process was evaluated by comparing contact angle, surface potential, surface resistivity, and XPS. The experimental results showed that the amount of weight loss, contact angle, surface potential and surface resistivity increased up to 200 $^{\circ}C$ as a function of temperature. These phenomena show the existence of hydrophobic surface. With the change to the hydrophobic surface and the electrical potential and resistivity on FRP surface increased. In XPS to analyze surface chemical structures, the increased hydrophobicity in thermal increase of unsaturated double bond in carbon chains. Aslo, thermal treatment caused the discoloration on the point of treated surface. These phenomena were attributed to the generations of ether group.

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Chirality in Non-Hermitian Photonics

  • Yu, Sunkyu;Piao, Xianji;Park, Namkyoo
    • Current Optics and Photonics
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    • v.3 no.4
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    • pp.275-284
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    • 2019
  • Chirality is ubiquitous in physics and biology from microscopic to macroscopic phenomena, such as fermionic interactions and DNA duplication. In photonics, chirality has traditionally represented differentiated optical responses for right and left circular polarizations. This definition of optical chirality in the polarization domain includes handedness-dependent phase velocities or optical absorption inside chiral media, which enable polarimetry for measuring the material concentration and circular dichroism spectroscopy for sensing biological or chemical enantiomers. Recently, the emerging field of non-Hermitian photonics, which explores exotic phenomena in gain or loss media, has provided a new viewpoint on chirality in photonics that is not restricted to the traditional polarization domain but is extended to other physical quantities such as the orbital angular momentum, propagation direction, and system parameter space. Here, we introduce recent milestones in chiral light-matter interactions in non-Hermitian photonics and show an enhanced degree of design freedom in photonic devices for spin and orbital angular momenta, directionality, and asymmetric modal conversion.

Coupling mechanical phenomena with thermal, hydraulic and chemical phenomena (제 2주제 역학적 현상과 열.수리.화학적 현상과의 상호작용)

  • Detournay, E.;Van Sint Ian, M.
    • Tunnel and Underground Space
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    • v.9 no.4
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    • pp.282-283
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    • 1999
  • 핵폐기물 지하처분, 지열개발, 지하 환경의 안전과 제어 등과 관련된 문제에 있어서 암석 및 암반의 역학적 거동 외에 열·수리·화학적 상호작용에 대한 이해가 필요하다. 이미 전세계적으로 국가별로 혹은 공동연구를 통하여 열·수리·역학적 상호작용에 관하여 많은 연구가 진행되었으며 최근 화학적 상호작용에 대한 문제가 추가적으로 제기되고 있다. 특히 장기간의 지하 환경의 안정성에 미치는 중요한 요소로 크립현상과 열·수리 화학적 상호작용 연구에 대한 필요성이 제기된 바 있다. 이 중 열·역학적 상호작용에 대해서는 현장문제에 적용 가능한 만은 연구결과가 제시된 바 있으나 기타 상호작용에 대해서는 다양한시험방법과모델링으로 인하여 아직가지 통일된 의견이 제시된 바 없다. 제 2주제에는 총 92편의 논문이 접수되었으며, 이 논문들의 내용, 성격, 해석방법 등을 간략히 정리하였다.

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YSO Variability and Episodic Accretion

  • Lee, Jeong-Eun
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.35.1-35.1
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    • 2021
  • Variability in young stellar objects (YSOs) can be caused by various time-dependent phenomena associated with star formation, including accretion rates, geometric changes in the circumstellar disks, stochastic hydromagnetic interactions between stellar surfaces and inner disk edges, reconnections within the stellar magnetosphere, and hot/cold spots on stellar surfaces. Among these YSO variability phenomena, bursts of accretion, which are the most remarkable variability, usually occur sporadically, making it challenging to catch the bursting moments observationally. However, the burst accretion process significantly affects the chemical conditions of the disk and envelope of a YSO, which can be used as a prominent tracer of episodic accretion. I will introduce our ensemble studies of YSO variability at mid-IR and submillimeter and also cover the ALMA observations of several YSOs in the burst accretion phase, especially in the view of chemistry.

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Pore Size Control of a Highly Transparent Interfacial Layer via a Polymer-assisted Approach for Dye-sensitized Solar Cells

  • Lee, Chang Soo;Lee, Jae Hun;Park, Min Su;Kim, Jong Hak
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.392-399
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    • 2019
  • A highly transparent interfacial layer (HTIL) to enhance the performance of dye-sensitized solar cells (DSSCs) was prepared via a polymer-assisted (PA) approach. Poly(vinyl chloride)-graft-poly(oxyethylene methacrylate) (PVC-g-POEM) was synthesized via atom-transfer radical polymerization (ATRP) and was used as a sacrificial template. The PVC-g-POEM graft copolymer induced partial coordination of a hydrophilic titanium isopropoxide (TTIP) sol-gel solution with the POEM domain, resulting in microphase separation, and in turn, the generation of mesopores upon calcination. These phenomena were confirmed using Fourier-transform infrared (FT-IR) spectroscopy, UV-visible light transmittance spectroscopy, scanning electron microscopy (SEM), and X-ray diffraction (XRD) analysis. The DSSCs incorporating HTIL60/20 (consisting of a top layer with a pore size of 60 nm and a bottom layer with a pore size of 20 nm) exhibited the best overall conversion efficiency (6.36%) among the tested samples, which was 25.9% higher than that of a conventional blocking layer (BL). DSSC was further characterized using the Nyquist plot and incident-photon to electron conversion efficiency (IPCE) spectra.

Study on the Fouling Reduction of the RO Membrane by the Coating with an Anionic Polymer (역삼투막 표면에 음이온 고분자 코팅을 통한 파울링 현상 감소연구)

  • Cho, Eun Hye;Cheong, Seong Ihl;Rhim, Ji Won
    • Membrane Journal
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    • v.22 no.6
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    • pp.481-488
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    • 2012
  • The anionic exchange polymer, poly(vinyl amine)(PVAm), was coated onto polyamide (PA) reverse osmosis (RO) membranes by using 'salting-out' method. The effects of the fouling phenomena for these PVAm coated membranes were investigated using the model foulants, bovine serum albumin (BSA), humic acid (HA), and sodium alginate (SA). The surface coating and the fouling phenomena were observed by the scanning electron microscopy. And the flux was measured for each 100 ppm of above foulant aqueous solution at the operating pressure, 2, 4, 8 bar. The PVAm-coated PA membranes showed somewhat fouling improvements and the fouling reduction was shown in the order of HA > SA > BSA, particularly HA case was distinct.

Simulation of Heat and Smoke Behavior for Wood and Subway Fires by Fire Dynamics Simulator(FDS) (FDS에 의한 목재 및 지하철 화재의 열 및 연기 거동 시뮬레이션)

  • Sonh, Yun-Suk;Dan, Seung-Kyu;Lee, Bong-Woo;Kwon, Seong-Pil;Shin, Dong-Il;Kim, Tae-Ok
    • Journal of the Korean Institute of Gas
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    • v.14 no.6
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    • pp.31-37
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    • 2010
  • In this study, to propose the analysis method of heat and smoke behavior of fire using the CFD-based fire simulator FDS, comparison of the simulation results against the experimental results and the sensitivity of the results to the grid sizes have been investigated. For the wood fire, thermal images captured from the experiments were compared against the FDS simulations, and the maximum temperatures agreed in~4.3 % error, showing the applicability of FDS in the interpretation of the fire phenomena. In the aspect of the sensitivity to the grid size for the subway fire, FDS results of smoke temperature, CO concentration and visibility converged and showed no distinct changes for the grid size < $28(L){\times}28(W){\times}14(H)$, guaranteeing that the FDS fire model set in this research could interpret the fire phenomena successfully.

Simplistic Determination of Operation Parameters for Simulated Moving Bed (SMB) Chromatography for the Separation of Ketoprofen Enantiomer

  • Park, Tae-Hyun;Yoon, Tae-Ho;Kim, In-Ho
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.10 no.4
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    • pp.341-345
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    • 2005
  • Since it is troublesome to estimate adequate flow rates in four sections of SMB chromatography, a systematic determination of the flow rates has been suggested by using ketoprofen as a model chiral enantiomer. S-ketoprofen. less retained species, was separated from raffinate stream and the variation in its purity was dependent on the changes of the flow rate of section 4 ($Q_4$), the raffinate flow rate ($Q_{raf}$), and the feed flow rate ($Q_{feed}$) under a fixed switch­ing time t$^{\ast}$. When one parameter was changed at the given experimental condition, purities of product were changed and these phenomena has be well explained by the triangle theory.

Hydrodynamic interaction between two cylinders in planar shear flow of viscoelastic fluid

  • Jung, Hyun-Wook;Daejin Won;Kim, Chongyoup
    • Korea-Australia Rheology Journal
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    • v.14 no.4
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    • pp.203-207
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    • 2002
  • Particle-particle interaction is of great importance in the study of suspension rheology. In this research we have investigated the hydrodynamic interaction between two identical cylinders in viscoelastic fluids numerically as a model problem for the study of viscoelastic suspension. We confine two neutrally buoyant cylinders between two parallel plates and impose a shear flow. We determine the migration velocity of two cylinders. The result shows that cylinders move toward or away from each other depending upon the initial distance between them and that there is an equilibrium distance between two cylinders in viscoelastic fluids regardless of the initial distance. In the case of Newtonian fluid, there is no relative movement as expected. The results partly explain the chaining phenomena of spherical particles in shear flows of viscoelastic fluids.

SOME CHARACTERISTICS OF THE CERAMIC SUPERCONDUCTORS PHYSICS PROERTIES AND CHEMICAL ASPECTS

  • Escudero, Roberto
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1992.05a
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    • pp.17-17
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    • 1992
  • The ceramic high transition temperature superconducting materials present many interesting characteristics that will be analysed from two points of view: physical behavior, and chemical aspects. From the first point of view, these materials display an enormous variety of different physical properties. At low doping levels the normal state shows antiferromagnetism and insulating behavior. At intermediate doping levels, an anomalous metallic state appears and, the optimum Tc in the superconducting state is generated. With increasing doping a normal metallic state develops and superconductivity starts to disappear. Many of the physical phenomena that describe the overall behavior when doping levels are changed will be discussed. From the poing of view of the chemical aspects. we well discuss some of the problems involved in the methods of preparation with particular emphasis on defects, crystal structures, critical currrents, and applications in technology.

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