• Title/Summary/Keyword: Chemical phenomena

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On the Critical Scattering Phenomena of a Nonpolar Binary Liquid Mixture

  • Dong J. Lee;Shoon K. Kim
    • Bulletin of the Korean Chemical Society
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    • v.12 no.4
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    • pp.403-406
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    • 1991
  • Light scattering phenomena are discussed for a nonpolar binary liquid mixture composed of an optically active solute and an optically nonactive solvent in the critical region, using the Fisher theory. Comparing them with those in the case that the Ornstein-Zernike theory is satisfied, the appropriate analytic results are obtained and discussed.

The Critical Phenomena of a Model for the Metabolic Control System with Positive Feedback

  • Kim, Cheol-Ju;Lee, Dong- J.;Shin, Kook-Joe;Lee, Jong-Myung;Ko, Seuk-Beum;Jeon, Il-Cheol
    • Bulletin of the Korean Chemical Society
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    • v.10 no.5
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    • pp.452-458
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    • 1989
  • The static and dynamic phenomena of a model for the metabolic control system with positive feedback are discussed with the static and dynamic renormalization group theory. Then, the explicit results for the static and dynamic exponents are obtained up to the second order of ${\varepsilon}$-expansion, ${\varepsilon}$ being 4-d, where d is the space dimensionality of the system.

A Survey of Secondary School Science Teachers’ Thinking on Classifying Phenomena Related to Dissolution of Ionic Compound and Acid into Physical and Chemical Change (이온결합 화합물과 산의 용해 현상을 물리변화와 화학변화로 구분하는 문제에 대한 중·고등학교 과학교사들의 인식 조사)

  • Baek, Seong Hye;Kim, Seon Gyeong
    • Journal of the Korean Chemical Society
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    • v.46 no.6
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    • pp.561-568
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    • 2002
  • This study examined secondary school science teachers' thinking on physical and chemical change. For this research, we analysed the answers of 80 secondary school science teachers. According to the result of the analysis,teachers had various opinions when they classified phenomena of dissolving ionic compound or diluting acid into phys-ical change and chemical change. Many teachers tended to classify similar phenomena into different change when those were represented with different focus. It means that teachers' opinions were not consistent.

A Study on the Chemical Composition of Precipitation during the Period of Sandy Dust Phenomena (黃砂現象時 降水의 化學的 成分에 關한 硏究)

  • 李敏熙;韓振錫;韓義正;辛燦基
    • Journal of Korean Society for Atmospheric Environment
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    • v.5 no.2
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    • pp.1-11
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    • 1989
  • Sandy dust phenomena was observed from April 19 to 23, 1988 in Seoul. During this period it rained and the precipitation was collected to investigate the rain chemistry. This study was carried out to analyzed the chemical composition of precipitation by the measurements of conditivity, cations $(H^+, NH_4^+, K^+, Na^+, Ca^{2+}, MG^{2+})$, and anions $(SO_4^{2-}, NO_3^-, Cl^-, F^-, Br^-)$ which are believed to be the major ions playing an important role in the acidity of rain water. During the period of sandy dust phenomena the range of pH value and conductivity concentration of rainwater were 6.0-6.7, 172-254 $\mu \mho/cm$. The anions and cations concentrations increased and the orders of these concentrations were $SO_4^{2-} > Cl^- > NO_3^- > Na^+ > Ca^{2+} > NH_4^+ > Mg^{2+}$. THe principal chemical compounds of rainwater were estimated at $(NH_4)_2 SO_4, CaSO_4, NaCl, and MgCl_2$.

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Preferential Solvation and Statistical Analysis for Solvent Polarity Parameters in MeOH Binary Mixtures

  • Sakong Yeol;Yoo Seoung-Kyo;Lee Ikchoon
    • Bulletin of the Korean Chemical Society
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    • v.13 no.6
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    • pp.636-642
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    • 1992
  • Preferential solvation (PS) phenomena of solutes based on solvent polarity, $E_T$ and AN, were studied by UV/vis. and NMR spectra in MeOH binary mixtures. According to the extent of solvent-solvent interaction, different solvation phenomena were found. PS concept was applied to explain the reactivity of tert-butyl halides solvolysis. The findings of solvation phenomena have been related to the rate of solvolysis and PS suggested as a reason for the solvent dependence of the rates of reaction. Moreover, we found that the results of principal components analysis using six parameters are in good accordance with the results of PS phenomena in mixed methanol systems.

A Study on the Metal Ion Components of Airborn Particulates during Yellow Sand Phenomena in Seoul (황사현상시 서울지역 대기분진의 성분에 관한 연구)

  • 신찬기;박태술;김윤신
    • Journal of environmental and Sanitary engineering
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    • v.6 no.1
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    • pp.47-62
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    • 1991
  • Yellow Sand Phenomena was observed from April 8 th to 10 th in 1990. During this period particle was collected to investigate the chacteristics of chemical composition of particulate by High Volume Air Sampler and Andersen Air Sa~npler in Seoul. During this period the particle concentration was 350 yg/$m^3$ and the anions, cations, and metal concentrations were increased and the orders of these were $S0_4\;^{-2}>N0_3\;^->Cl^->F^-, Na^+>Ca^{+2}>NH_4\;^+>Mg^{2+}>K^+$, and Fe>Al>Si>Zn>Pb respectively. The principal source of Yellow Sand were identified soil and sea salt. Mn used by the trace element of soil, the persentage of contribution from soil was calculated to be about 81.3% for the particle increased by Yellow Sand Phenomena. Also the principal chemical compounds of particle were estimate metals(Fe, Al, Si, Zn) oxides, $CaSO_4, NaSO_4, MgSO_4, NaC1, MgCl_2$ and $(NH_4)_2SO_4$.

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Technological Trend of Crystallization Research for Bioproduct Separation (Bioproduct 분리를 위한 결정화 연구 동향)

  • Kim, Woo-Sik;Lee, Eun-Kyu
    • KSBB Journal
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    • v.20 no.3
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    • pp.164-176
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    • 2005
  • In bioengineering field, current academic trends and informations on crystallization technology for bioproduct separation were summarized. It is essential for utilizing the crystallization technology to understand the fundamental phenomena of crystallization of crystal nucleation, crystal growth, crystal agglomeration and population balance for the design of crystallizers. In general, the crystal nucleation that the crystalline solids occur from the solution is analyzed by Gibb's free energy change in the aspect of thermodynamics and in the present paper the crystal nucleation models based on the above thermodynamics are summarized by their key characteristics. The crystal growth and agglomeration, which have been studied over 50 years and are essential phenomena for separation technology, are reviewed from their basic concept to most leading edge trend of researches. In the material and population balances for the designs of crystallization separation process, the analysis of crystallizers is summarized. Thereon, the present review paper will academically contribute the understanding the crystallization phenomena and the design of the crystallization separation process.

Non Stationary Ionic Current through Polymer Charged Membrane

  • Jeong, Sung-Hyun;Lee, Won-Chul;Yang, Wong-Kang
    • Bulletin of the Korean Chemical Society
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    • v.24 no.7
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    • pp.937-942
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    • 2003
  • The relaxation phenomena of ionic currents through the charged membrane under the constant applied potentials has been studied. The formulation was obtained for the non stationary current by assuming that the ion mobility is independent of concentration and the potential gradient is a constant within membrane, and it was applied to the experimental results with the sulfonated polystyrene collodion base membrane. It has been shown that the initial ion distributions in the membrane play a predominant role in the relaxation phenomena.

Transprt Phenomena in Bulk Crystal Growth Processes

  • Lan, C.W.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.06a
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    • pp.29-33
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    • 1998
  • Transport phenomena paly an inmportant role in bulk crystal growth processes. During crystal growth, the control of the growth front and the dopant concentration is crucial to crystal quality. The growth feasibility in thus determined by the heat transfer controlling the interface convexity and by the mass transfer controlling the constitutional supercooling. Through numerical modeling, a thorough understanding of the growth processes is possible, which in turn is a key to process improvenment. In this paper, we will summarize some work dine in my laboratory, both numerical and experimental, to illustrate the importance of understanding the transport phenomena during crystal growth processes.

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