• 제목/요약/키워드: Chemical phenomena

검색결과 702건 처리시간 0.025초

On the Critical Scattering Phenomena of a Nonpolar Binary Liquid Mixture

  • Dong J. Lee;Shoon K. Kim
    • Bulletin of the Korean Chemical Society
    • /
    • 제12권4호
    • /
    • pp.403-406
    • /
    • 1991
  • Light scattering phenomena are discussed for a nonpolar binary liquid mixture composed of an optically active solute and an optically nonactive solvent in the critical region, using the Fisher theory. Comparing them with those in the case that the Ornstein-Zernike theory is satisfied, the appropriate analytic results are obtained and discussed.

The Critical Phenomena of a Model for the Metabolic Control System with Positive Feedback

  • Kim, Cheol-Ju;Lee, Dong- J.;Shin, Kook-Joe;Lee, Jong-Myung;Ko, Seuk-Beum;Jeon, Il-Cheol
    • Bulletin of the Korean Chemical Society
    • /
    • 제10권5호
    • /
    • pp.452-458
    • /
    • 1989
  • The static and dynamic phenomena of a model for the metabolic control system with positive feedback are discussed with the static and dynamic renormalization group theory. Then, the explicit results for the static and dynamic exponents are obtained up to the second order of ${\varepsilon}$-expansion, ${\varepsilon}$ being 4-d, where d is the space dimensionality of the system.

이온결합 화합물과 산의 용해 현상을 물리변화와 화학변화로 구분하는 문제에 대한 중·고등학교 과학교사들의 인식 조사 (A Survey of Secondary School Science Teachers’ Thinking on Classifying Phenomena Related to Dissolution of Ionic Compound and Acid into Physical and Chemical Change)

  • 백성혜;김선경
    • 대한화학회지
    • /
    • 제46권6호
    • /
    • pp.561-568
    • /
    • 2002
  • 이 연구에서는 물리변화와 화학변화에 대한 중·고등학교 과학교사들의 인식을 조사하였다. 연구를 위해 중·고등학교 과학교사들에게 설문지를 투입하여 총 80명의 설문을 분석하였다. 과학교사들의 인식 조사 결과, 이온결합 물질이나 산이 물에 녹는 현상을 물리${\cdot}$화학변화로 구분하는 것에 대해 교사들은 다양한 견해를 가지고 있음을 알 수 있었다. 그리고 유사하거나 동일한 현상에 대해서도 문항에서 언급한 초점이 다를 경우 다른 변화로 판단하는 경향이 있었다. 즉, 응답에 일관성을 기지지 못하는 것으로 나타났다.

黃砂現象時 降水의 化學的 成分에 關한 硏究 (A Study on the Chemical Composition of Precipitation during the Period of Sandy Dust Phenomena)

  • 李敏熙;韓振錫;韓義正;辛燦基
    • 한국대기환경학회지
    • /
    • 제5권2호
    • /
    • pp.1-11
    • /
    • 1989
  • Sandy dust phenomena was observed from April 19 to 23, 1988 in Seoul. During this period it rained and the precipitation was collected to investigate the rain chemistry. This study was carried out to analyzed the chemical composition of precipitation by the measurements of conditivity, cations $(H^+, NH_4^+, K^+, Na^+, Ca^{2+}, MG^{2+})$, and anions $(SO_4^{2-}, NO_3^-, Cl^-, F^-, Br^-)$ which are believed to be the major ions playing an important role in the acidity of rain water. During the period of sandy dust phenomena the range of pH value and conductivity concentration of rainwater were 6.0-6.7, 172-254 $\mu \mho/cm$. The anions and cations concentrations increased and the orders of these concentrations were $SO_4^{2-} > Cl^- > NO_3^- > Na^+ > Ca^{2+} > NH_4^+ > Mg^{2+}$. THe principal chemical compounds of rainwater were estimated at $(NH_4)_2 SO_4, CaSO_4, NaCl, and MgCl_2$.

  • PDF

Preferential Solvation and Statistical Analysis for Solvent Polarity Parameters in MeOH Binary Mixtures

  • Sakong Yeol;Yoo Seoung-Kyo;Lee Ikchoon
    • Bulletin of the Korean Chemical Society
    • /
    • 제13권6호
    • /
    • pp.636-642
    • /
    • 1992
  • Preferential solvation (PS) phenomena of solutes based on solvent polarity, $E_T$ and AN, were studied by UV/vis. and NMR spectra in MeOH binary mixtures. According to the extent of solvent-solvent interaction, different solvation phenomena were found. PS concept was applied to explain the reactivity of tert-butyl halides solvolysis. The findings of solvation phenomena have been related to the rate of solvolysis and PS suggested as a reason for the solvent dependence of the rates of reaction. Moreover, we found that the results of principal components analysis using six parameters are in good accordance with the results of PS phenomena in mixed methanol systems.

황사현상시 서울지역 대기분진의 성분에 관한 연구 (A Study on the Metal Ion Components of Airborn Particulates during Yellow Sand Phenomena in Seoul)

  • 신찬기;박태술;김윤신
    • 환경위생공학
    • /
    • 제6권1호
    • /
    • pp.47-62
    • /
    • 1991
  • Yellow Sand Phenomena was observed from April 8 th to 10 th in 1990. During this period particle was collected to investigate the chacteristics of chemical composition of particulate by High Volume Air Sampler and Andersen Air Sa~npler in Seoul. During this period the particle concentration was 350 yg/$m^3$ and the anions, cations, and metal concentrations were increased and the orders of these were $S0_4\;^{-2}>N0_3\;^->Cl^->F^-, Na^+>Ca^{+2}>NH_4\;^+>Mg^{2+}>K^+$, and Fe>Al>Si>Zn>Pb respectively. The principal source of Yellow Sand were identified soil and sea salt. Mn used by the trace element of soil, the persentage of contribution from soil was calculated to be about 81.3% for the particle increased by Yellow Sand Phenomena. Also the principal chemical compounds of particle were estimate metals(Fe, Al, Si, Zn) oxides, $CaSO_4, NaSO_4, MgSO_4, NaC1, MgCl_2$ and $(NH_4)_2SO_4$.

  • PDF

Bioproduct 분리를 위한 결정화 연구 동향 (Technological Trend of Crystallization Research for Bioproduct Separation)

  • 김우식;이은규
    • KSBB Journal
    • /
    • 제20권3호
    • /
    • pp.164-176
    • /
    • 2005
  • In bioengineering field, current academic trends and informations on crystallization technology for bioproduct separation were summarized. It is essential for utilizing the crystallization technology to understand the fundamental phenomena of crystallization of crystal nucleation, crystal growth, crystal agglomeration and population balance for the design of crystallizers. In general, the crystal nucleation that the crystalline solids occur from the solution is analyzed by Gibb's free energy change in the aspect of thermodynamics and in the present paper the crystal nucleation models based on the above thermodynamics are summarized by their key characteristics. The crystal growth and agglomeration, which have been studied over 50 years and are essential phenomena for separation technology, are reviewed from their basic concept to most leading edge trend of researches. In the material and population balances for the designs of crystallization separation process, the analysis of crystallizers is summarized. Thereon, the present review paper will academically contribute the understanding the crystallization phenomena and the design of the crystallization separation process.

Non Stationary Ionic Current through Polymer Charged Membrane

  • Jeong, Sung-Hyun;Lee, Won-Chul;Yang, Wong-Kang
    • Bulletin of the Korean Chemical Society
    • /
    • 제24권7호
    • /
    • pp.937-942
    • /
    • 2003
  • The relaxation phenomena of ionic currents through the charged membrane under the constant applied potentials has been studied. The formulation was obtained for the non stationary current by assuming that the ion mobility is independent of concentration and the potential gradient is a constant within membrane, and it was applied to the experimental results with the sulfonated polystyrene collodion base membrane. It has been shown that the initial ion distributions in the membrane play a predominant role in the relaxation phenomena.

Transprt Phenomena in Bulk Crystal Growth Processes

  • Lan, C.W.
    • 한국결정성장학회:학술대회논문집
    • /
    • 한국결정성장학회 1998년도 PROCEEDINGS OF THE 14TH KACG TECHNICAL MEETING AND THE 5TH KOREA-JAPAN EMGS (ELECTRONIC MATERIALS GROWTH SYMPOSIUM)
    • /
    • pp.29-33
    • /
    • 1998
  • Transport phenomena paly an inmportant role in bulk crystal growth processes. During crystal growth, the control of the growth front and the dopant concentration is crucial to crystal quality. The growth feasibility in thus determined by the heat transfer controlling the interface convexity and by the mass transfer controlling the constitutional supercooling. Through numerical modeling, a thorough understanding of the growth processes is possible, which in turn is a key to process improvenment. In this paper, we will summarize some work dine in my laboratory, both numerical and experimental, to illustrate the importance of understanding the transport phenomena during crystal growth processes.

  • PDF