• Title/Summary/Keyword: Chemical leaching

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Paleo-red Soil on the High Fluvial Surface in the Middle Basin of Nam-Han River (남한강 중류 하성고위면의 고적색토)

  • Kang, Young-Pork;Lee, Sang-Min
    • Journal of the Korean earth science society
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    • v.26 no.8
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    • pp.828-835
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    • 2005
  • The purpose of this study is to clarify the landform development of fluvial terrace and the soil characteristics occurring on the terrace deposit. In order to achieve the purpose, the characteristics of soil profiles, the physic-chemical properties of soils that are developed on terrace deposits and X-ray diffraction analysis of clay were investigated. The horizon of Al in the high fluvial surface is silt clay loam of red (2YR 4/6). The soil structure is a developed granular structure. The horizon of B1 is silt clay reddish-brown (2.5YR 4/6). The soil structure is a medium subangular blocky structure. This red soil structure is made on heavy textured and compactly packed parent materials of high terrace sediments and usually has A-B-C profile. In most cases, clay accumulations in B-horizon and clay cutans on ped surfaces are observed, which mean the formation of agrillic horizon. As the result of this study, soils derived from fluvial terrace deposits on high fluvial surfaces are considered paleo-red soil which were developed by pedogenese-strong desilicification and rubefaction and strong leaching of bases- under warmer bio-climatic condition during in the old Pleistocene period.

Mineral Distribution of Soil at Different Depth in a Fairway Slope (훼어웨이 경사의 토양 깊이별 무기성분 분포)

  • Choi, B. J.;Ju, Y. H.;Park, H.
    • Asian Journal of Turfgrass Science
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    • v.11 no.2
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    • pp.89-95
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    • 1997
  • Soil chemical properties were investigated to elucidate vertical movement of mineral nutrients in a fairway slope of 27 year-old golf course. Soil samples were taken at every 10cm depth to 4Ocm on 4 sites 20m apart each along two parallel lines 60m apart on the slope(15˚) in August. Accord-ing to the similarity of vertical distribution pattern they could be classified into 6 distinctive groups(magnesium, nitrate, phosphorus, ammonium, manganese and copper) and the slope tended to affect the vertical movement of minerals. The contents of Ca and Mg increased with depth while NO$_3$-N and Zn decreased and correlated positively. Soil pH showed significant positive correlation with depth, Ca and Mg. Phosphorus content was highest in 10~20cm depth and decreased resulting in relatively high content in 30~40cm depth of the bottom site of slope. Iron distribution pattern was similar to phosphorus. Potassium and $NH_4$showed various(irregular) patterns. Mn was highest in the deep layer at the lower sites of slope but it was reverse at the upper sites and negatively correlated with Fe. Cu content incresed with depth and heighest in 20~30cm depth. Electroconductivity showed significant positive correlation with $NO_3$-N. Magnesium, cal-cium and copper seem to be prone to defficiency due to fast leaching, and nitrate and phosphorus prone to excess problem. Preventive measures on acidification of surface soil should be taken.

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Available Organic Carbon Controls Nitrification and Immobilization of Ammonium in an Acid Loam-Textured Soil

  • Choi, Woo-Jung;Lee, Sang-Mo;Han, Gwang-Hyun;Yoon, Kwang-Sik;Jung, Jae-Woon;Lim, Sang-Sun;Kwak, Jin-Hyeob
    • Journal of Applied Biological Chemistry
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    • v.49 no.1
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    • pp.28-32
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    • 2006
  • Effect of organic-C on immobilization and nitrification patterns in acidic soil was examined during 20 weeks incubation period to verify if organic amendments such as composted material can increase soil retention of N by stimulating microbial immobilization of $NH_4^+$. Four treatments were laid out: control without fertilizer N and glucose (treatment code: S), ammonium sulfate (SN), ammonium sulfate with single glucose at the commencement (0 week) of incubation (SNG), and ammonium sulfate with double glucose at 0 and 4 weeks of incubation (SNGG). Glucose application (SNG) significantly increased microbial immobilization of $NH_4^+$ within 1 week of incubation over SN. Immobilization was followed by remineralization thereafter; however, second-application of glucose (SNGG) restored $NH_4^+$ immobilization. At the same time, nitrification was significantly inhibited by glucose application as indicated by consistently low $NO_3^-$ concentration in SNG and SNGG soils, suggesting that microbial assimilation of $NH_4^+$ is predominant compared to nitrification when available C-source is abundant. These results suggest application of chemical fertilizer-N with organic amendment would have beneficial effect on soil-N retention and environmental conservation by reducing production of $NO_3^-$ which is likely to be lost through leaching or denitrification.

Risk Mitigation Measures in Arsenic-contaminated Soil at the Forest Area Near the Former Janghang Smelter Site: Applicability of Stabilization Technique and Follow-up Management Plan ((구)장항제련소 주변 송림숲 등 식생지역에서의 비소오염토양 위해도 저감 조치: 안정화 공법 적용성 평가 및 사후관리 계획)

  • An, Jinsung;Yang, Kyung;Kang, Woojae;Lee, Jung Sun;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.22 no.6
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    • pp.1-11
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    • 2017
  • This study was conducted to investigate the performance of four commercial chemical agents in stabilizing arsenic (As) in soil at the forest area near the former Janghang smelter site. After amending the stabilizing agents (A, B, C, and D) into As-contaminated soil samples, synthetic precipitation leaching procedure (SPLP) and solubility bioavailability research consortium (SBRC)-extractable As concentrations significantly decreased except for agent D, which is mainly composed of fly ash and calcium carbonate. Increase of SPLP and SBRC-extractable As concentrations in four soil samples (S1, S2, S3, and J2) was attributed to desorption of As adsorbed on iron oxides due to high pH generated by agent D. It is therefore necessary to consider application conditions according to soil characteristics such as pH and buffering capacity. Results of sequential extraction showed that readily extractable fractions of As in soil (i.e., sum of $SO_4-$ and $PO_4-extractable$ As in soil) were converted into non-readily extractable fractions by amending agents A, B, and C. Such changes in the As distribution in soil resulted in the decrease of SPLP and SBRC-extractable As concentration. A series of follow-up monitoring and management plan has been suggested to assess the longevity of the stabilization treatments in the site.

Contamination Level and Behavior of Heavy Metals in Stream Sediments Within the Watershed of Juam Reservoir (주암댐 집수유역 내 하상퇴적물의 중금속 오염현황 및 거동 특성)

  • 염승준;이평구;강민주;신성천;유연희
    • Economic and Environmental Geology
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    • v.37 no.3
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    • pp.311-324
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    • 2004
  • We investigated the contamination and behavior of heavy metals in stream sediments within the watershed of Juam Reservoir. Many abandoned mines within the reservoir can act as a potential contaminant source for water quality. Heavy metal concentrations (Cr, Cu, Ni, Pb and Zn) in stream sediments from watershed are very low, indicating that content of heavy metals in the sediments probably do not affect the water quality in Juam Reservoir. However Pb concentration in the stream sediments increases downward streams, suggesting the possible diffusion of Pb contamination. According to the leaching ratio for stream sediments at a strong acidic condition in the abandoned mine areas, the relative mobility for metals decreases in the order of Pb>Zn=Cu>Ni>Cr, indicating that Pb can have a bad effect upon the water quality in Jum Reservoir. Moreover, if contaminated sediment is placed in the bottom of reservoir (i.e., reducing condition), the relative mobility of Pb is the highest, indicating that Pb in the bottom sediments can be leached to water at interface between water and sediment with changing in physicochemical conditions.

Assessment of the physico-chemical quality and extent of algal proliferation in water from an impounding reservoir prone to eutrophication

  • Ballah, Mohun;Bhoyroo, Vishwakalyan;Neetoo, Hudaa
    • Journal of Ecology and Environment
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    • v.43 no.1
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    • pp.22-30
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    • 2019
  • Background: Piton du Milieu (PdM) impounding reservoir is suspected to be eutrophic based on the elevated level of orthophosphate and nitrate. Water supplies from three adjacent rivers are primarily thought to contribute to the nutrient enrichment of the reservoir. It is also suspected that there is leaching of orthophosphate, nitrate and organic matter into the rivers during rainfall events and also as a result of anthropogenic activities within the catchment area. The aim of this study was to ascertain the impact of nutrient loading on the water quality of PdM water and on the population of freshwater microalgae in the reservoir. The enumeration and identification of algae from PdM were performed by differential interference contrast microscopy. Dissolved oxygen (DO) and pH were determined by electrometric methods, whereas nutrient levels, silica and total organic carbon (TOC) were determined by instrumentation techniques. Results: Annual mean orthophosphate, nitrate and total organic carbon input from the three feeders within the catchment area of PdM reached levels as high as 0.09 mg/L, 0.4 mg/L and 2.62 ppm respectively. Over a 12-month period, mean TOC concentration in the reservoir was 2.32 ppm while the mean algal cell count was 4601 cells/mL. The dominant algal species identified were Oscillatoria, Cyclotella, Navicula and Cosmarium. Conclusion: This study highlights the trophic state of the reservoir water and clearly points to the need for constant monitoring in order to avoid the occurrence of an impending harmful algal bloom.

Study on Oxygen Evolution Reaction of Ni-Zn-Fe Electrode for Alkaline Water Electrolysis (알칼라인 수전해용 Ni-Zn-Fe 전극의 산소 발생 반응 특성)

  • LEE, TAEKYUNG;KIM, JONGWON;BAE, KIKWANG;PARK, CHUSIK;KANG, KYOUNGSOO;KIM, YOUNGHO;JEONG, SEONGUK
    • Journal of Hydrogen and New Energy
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    • v.29 no.6
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    • pp.549-558
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    • 2018
  • The overall efficiency depend on the overpotential of the oxygen evolution reaction in alkaline water electrolysis. Therefore, it is necessary to research to reduce the oxygen evolution overpotential of electrodes. In this study, Ni-Zn-Fe electrodes were prepared by electroplating and the surface area was increased by Zn leaching process. Electroplating variables were studied to optimize the plating parameters(electroplating current density, pH value of electroplating solution, Ni/Fe content ratio). Ni-Zn-Fe electrode, which is electroplated in a modified Watts bath, showed 0.294 V of overpotential at $0.1A/cm^2$. That result is better than that of Ni and Ni-Zn plated electrodes. As the electroplating current density of the Ni-Zn-Fe electrode increased, the particle size tended to increase and the overpotential of oxygen evolution reaction decreased. As reducing pH of electroplating solution from 4 to 2, Fe content in electrode and activity of oxygen evolution reaction decreased.

Decay of Populus cathay Treated with Paraffin Wax Emulsion and Copper Azole Compound

  • Liu, Jie;Liu, Min;Hou, Bingyi;Ma, Erni
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.1
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    • pp.21-32
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    • 2019
  • In order to investigate the decay process of wood treated with preservative, waterproofing agent and their compound systems, a full-cell process was applied to impregnate the sapwood of poplar (Populus cathay) at paraffin wax emulsion concentrations of 0.5% and 2.0%, Copper Azole (CA) concentrations of 0.3% and 0.5%, and their four compound systems, respectively. Leaching tests and laboratory decay resistance against the white-rot fungus Corious versicolor (L.) Murrill for treated wood were carried out according to the America Standard E11-06 and China Standard GB/T 13942.1-2009. At certain time intervals during the decay test, samples were characterized by Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction technique (XRD) to investigate the time-dependent changes of chemical components and crystalline structure, thus clarifying the decay mechanisms. The results suggested that white-rot fungi degrade hemicellulose and lignin in the wood cell wall first, followed by a simultaneous degradation of polysaccharides and lignin. Besides, CA could not only slower the decomposition of both hemicellulose and lignin, but also reduce the degradation amount of hemicellulose. However, paraffin wax emulsion at high concentration had a negative effect on the impregnation of CA for the compound system treated wood.

Adsorption characteristics of NH4-N by biochar derived from pine needles

  • Kang, Yun-Gu;Lee, Jun-Young;Chun, Jin-Hyuk;Lee, Jae-Han;Yun, Yeo-Uk;Oh, Taek-Keun
    • Korean Journal of Agricultural Science
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    • v.48 no.3
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    • pp.589-596
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    • 2021
  • Nitrogen applied to soil is highly prone to leaching and volatilization leading to gaseous emissions of nitrous oxide (N2O) and ammonia (NH3) which are of great environmental concern. Usage of biochar to reduce the discharge of nitrogen to the environment has attracted much interest in the recent past. Biochar is produced by pyrolyzing various biomasses under oxygen-limited conditions. Biochar is a carbonized material with high adsorptive powers for not only plant nutrients but also heavy metals. The objective of this study was to investigate the adsorption characteristics of NH4-N onto biochar made from pine needles. The biochar was produced at various pyrolysis temperatures including 300, 400 and 500℃ and holding times of 30 and 120 minutes. The Langmuir isotherm was used to evaluate the adsorption test results. The chemical properties of the biochar varied with the pyrolysis conditions. In particular, the pH, EC and total carbon content increased with the increasing pyrolysis conditions. The rate of adsorption of NH4-N by the biochar decreased with the increasing pyrolysis conditions. Of these conditions, biochar that was pyrolyzed at 300℃ for 30 minutes showed the highest adsorption rate of approximately 0.071 mg·g-1. Thus, the use of biochar pyrolyzed at low temperatures with a short holding time can most efficiently reduce ammonia emissions from agricultural land.

A Study on the Characteristics of Alkali Silica Sol Grouting Material (알칼리성 실리카졸 지반주입재의 특성에 관한 연구)

  • Cho, Younghun;Kim, Chanki;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.4
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    • pp.17-24
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    • 2011
  • For the purpose of cut off and ground stabilization, water glass chemical grouting method using sodium silicate has problems of weakening durability and ground water pollution because leaching was conducted when the homogel is exposed to the ground water as time elapses. The purpose of this study is to identify the effect of alkali silica sol ground injection materials, it was compared with the sodium silicate ground injection materials using water glasses. For sodium silicate and alkali silica sol by mixing each case is divided into four different specimens were made and tested. The characteristic of alkali silica sol ground injection material was analyzed by unconfined compression test and environmental impact statement of ordinary portland cement and blast furnace slag cement. Alkali silica sol specimens were made mixing A-solution and B-solution in the proportion of one on one. Through this study, alkali silica sol ground injection mixing blast furnace slag cement has excellent strength and environment-friendly.