• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2011년도 제37회 추계학술대회논문집
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• pp.123-126
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• 2011

케로신을 연료로 사용하는 연료 과잉 예연소기는 비평형 연소반응을 하며, 화학평형 해석으로는 정확한 연소가스 물성치 예측이 쉽지 않다. 본 연구에서는 연소 가스 물성치 예측을 위해, 예혼합 대향류 화염 해석을 수행하였다. 케로신 연료의 대표 물성치로 JP10을 선정하였으며, UC San Diego 반응 메커니즘을 사용하여 초임계 조건에서 비평형 연소해석을 수행하였다. 안정적인 화염 확보를 위해 예혼합 추진제의 대향류 화염을 가정하였으며, Huzel의 실험 결과에 비해 온도가 높게 예측 되었다. 이에 따라 비열, 비열비, 분자량 결과에서 차이를 보였으나 화학평형 결과에 비해 실험값과 더 유사한 경향을 보였다.

• 에너지공학
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• 제2권3호
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• pp.276-284
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• 1993

분류층 가스화기를 대상으로하여 석탄가스화 복합발전 시스템을 위한 가스화반응 모델링을 수행하였다. 가스화기 내에서의 가스화반응은 화학평형상태에 있다고 가정하여 Gibbs 자유에너지 최소화법을 이용하였다. 물질수지와 열수지를 동시에 고려한 모델링 결과와 실제 가스화기 실험자료를 비교하여 모델의 신뢰성을 확인하였다. 이를 토대로 가스화기에 공급되는 산화제의 양이 평형조성에 미치는 영향과 가스화기의 온도, 그리고 석탄종류가 가스화반응에 미치는 영향에 대해 알아보았다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2003년도 제21회 추계학술대회 논문집
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• pp.57-60
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• 2003

An axisymmetric compressible flow solver accounting for chemical equilibrium has been developed as an analysis tool exclusively suitable for performance prediction and optimum contour design of LRE thrust chamber. By virtue of several features focusing on user-friendliness and effectiveness including automatical grid generation and iterative calculations with changes in design parameters prescribed through only one keyword-type input file, a design engineer can evaluate very fast and easily the influences of various design inputs such as geometrical parameters and operating conditions on propulsive performance. Validations have been carried out for various aspects by detailed comparisons with the result of CEA code, experimental data of JPL nozzle, actual data for two historical engines, and ReTF data for KSR-III.

• 한국수소및신에너지학회논문집
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• 제16권4호
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• pp.307-314
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• 2005

In this work, a static volumetric method was experimentally implemented to measure the adsorption isotherm of hydrogen and methane by the activated carbon. The equilibrium data of stationary phase and mobile phase were correlated into the Langmuir, Freundlich, Langmuir-Freundlich, and Toth isotherms, respectively. In addition, the comparison between prediction and experimental data was made. By a nonlinear regression analysis, the experimental parameters in the equilibrium isotherms were estimated and compared. Then, the linear and quadratic equations for pressure and temperature to adsorption amounts were expressed. The adsorption amounts were increased with the pressure increase and the temperature decrease.

• Bulletin of the Korean Chemical Society
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• 제16권2호
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• pp.169-180
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• 1995

A topological theory is introduced to extend Tsenoglou's theory to polymer blends having temporary and permanent networks composed of multicomponent polymers which have miscible and flexible chains. The topological theory may estimate the values of free elastic energy, the molecular weight between entanglements, and the equilibrium shear moduli, and it may establish more correctly the topological relations among these physical quantities. Through such introduction of the topological theory, there can be topologically analyzed the mixing law for the rubbery plateau modulus of a fluid polymer blend, and there can be considered the topological relationship to the equilibrium modulus of an interpenetrating polymer network containing trapped entanglements and dangling segments. The theoretically predictive values are compared and show good agreement with the experimental data for several miscible polymer blends.

• 한국수소및신에너지학회논문집
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• 제13권1호
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• pp.42-51
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• 2002

Methane can be converted directly to hydrogen by pyrolysis. The reaction is highly endothemic and heat must be supplied at high temperatures. Gibbs free energy minimization calculations have been carried out for the methane pyrolysis to determine equilibrium products. The calculation parameters are the temperature, the initial H/C ratio, the pressure and Gibbs energies of each substance. Methane, ethylene, acetylene, benzene, naphthalene, and hydrogen are the main products. Excluding hydrogen, it is observed that ethylene and aromatics(benzene+naphthalene) are predominant products below 1400K, whereas acetylene is significantly formed above 1400K. Hydrogen dilution increases the selectivities for ethylene and acetylene and decreases the selectivity for aromatics. Increasing the pressure also decreases the decomposition of methane.

• International Journal of Aeronautical and Space Sciences
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• 제11권2호
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• pp.59-68
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• 2010

The aim of this work is to analyze high temperature flows around an axisymmetric blunt body taking into account chemical and vibrational non-equilibrium state for air mixture species. For this purpose, a finite volume methodology is employed to determine the supersonic flow parameters around the axisymmetric blunt body. This allows the capture of a shock wave before a blunt body placed in supersonic free stream. The numerical technique uses the flux vector splitting method of Van Leer. Here, adequate time stepping parameters, along with Courant, Friedrich, Lewis coefficient and mesh size level are selected to ensure numerical convergence, sought with an order of $10^{-8}$.

• 한국전산유체공학회지
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• 제5권2호
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• pp.47-54
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• 2000

A robust Navier-Stokes code has been developed to efficiently predict hypersonic flows in chemical nonequilibrium. The HLLE+ flux discretization scheme is used to improve accuracy and robustness of hypersonic flow analysis. An efficient LU approximate factorization method is also used to solve the flow equations and species continuity equations in fully coupled fashion to implicitly treat stiff source terms of chemical reactions. The HLLE+ scheme shows lower grid dependency for the wall heating rates than other schemes. The developed code has been used to compute chemical nonequilibrium air flow through expanding hypersonic nozzle and past two and three dimensional blunt-nosed bodies. The results are in good agreement with existing numerical and experimental results.

• 대한화학회지
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• 제49권5호
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• pp.479-487
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• 2005

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2006년도 추계 학술대회논문집
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• pp.101-105
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• 2006

The computational fluid dynamic analysis has been conducted for the thermo-chemical flow field in an arcjet thruster with mono-propellant Hydrazine (N2H4) as a working fluid. The Reynolds Averaged Navier-Stokes (RANS) equations are modified to analyze compressible flows with the thermal radiation and electric field. The Maxwell equation, which is loosely coupled with the fluid dynamic equations through the Ohm heating and Lorentz forces, is adopted to analyze the electric field induced by the electric arc. The chemical reactions of Hydrazine were assumed to be infinitely fast due to the high temperature field inside the arcjet thruster. The chemical and the thermal radiation models for the nitrogen-hydrogen mixture and optically thick media respectively, were incorporated with the fluid dynamic equations. The results show that performance indices of the arcjet thruster with 1kW arc heating are improved by amount of 180% in thrust and 200% in specific impulse more than frozen flow. In addition to thermo-physical process inside the arcjet thruster is understood from the flow field results.