• Korean Chemical Engineering Research
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• v.55 no.6
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• pp.807-815
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• 2017

This study investigated the removal efficiency of residual pentane from paclitaxel according to the drying temperature in the case of rotary evaporation, and performed a kinetic and thermodynamic analysis of the drying process. At all the temperatures (25, 30, 35, 40, and $45^{\circ}C$), a large amount of the residual solvent was initially removed during the drying, and the drying efficiency increased when increasing the drying temperature. Five drying models (Newton, Page, modified Page, Henderson and Pabis, Geometric) were then used for the kinetic analysis, where the Henderson and Pabis model showed the highest coefficient of determination ($r^2$) and lowest root mean square deviation (RMSD), indicating that these models were the most suitable. Furthermore, in the thermodynamic analysis of the rotary evaporation, the activation energy ($E_a$) was 4.9815 kJ/mol and the standard Gibbs free energy change (${\Delta}G^0$) was negative, whereas the standard enthalpy change (${\Delta}H^0$) and standard entropy change (${\Delta}S^0$) were both positive, indicating that the drying process was spontaneous, endothermic, and irreversible.

• Journal of Industrial and Engineering Chemistry
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• v.67
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• pp.92-98
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• 2018

The effect of surfactants with different chain length on the drying dynamics of nanosized dispersion droplets and on the final morphology of the grains formed after water evaporation is investigated experimentally. An acoustic levitator was used to examine the drying dynamics of single droplets and SEM imaging was used to characterise the morphology of the final dried grains. Results show that the drying of drops with high molecular weight surfactants leads to more irregular grains and that the grain morphology is related to surface tension driven instability of the evaporating droplets which may lead to formation of hollow dried grains.

• Proceedings of the Membrane Society of Korea Conference
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• 2004.05a
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• pp.69-69
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• 2004

Cellulose hollow fiber membranes (CHFM) were prepared from the cellulose/N-methylmorpholine-N-oxide/$H_2O$ system by immersion-precipitation and wet spinning. Different drying methods were carried out to investigate their influences on the properties of CHFM.(omitted)

• Journal of The Korean Society of Grassland and Forage Science
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• v.21 no.2
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• pp.67-74
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• 2001

A field experiment was carried out to determine the effects of chemical/mechanical treatments at mowing on the field drying rate and hay quality of alfalfa(Medicago sativa L., cv. Vernal) and spring oats(Avena satvia L., cv. Swan). The chemical drying agent of 2% $K_2CO_3$, mechanical mower conditioning, and no treatment(control) were treated for hastening hay-making in the spring of 1997. The forages were harvested at early bloom stage in alfalfa and heading stage in oats. After field dry, square bales were made by hay baler, and the dry matter(DM) loss, visual estimation and nutritive value of hay were evaluated after storing two months. The field drying rates of alfalfa and oats were high at mechanical treatment, but the drying effectiveness of chemical agents alone was very low. With mower conditioning, the duration of field dry was shortened by 1 day compared with control. therefore, mower conditioning enhance the field drying rate of alfalfa and oats. The DM loss of alfalfa and oats hay was reduced by mechanical treatment, but the efficiency by chemical alone was low. The visual score(leafiness, green color, odor and softness) of hay at mechanical treatment was slightly higher than that of chemical and control. The nutritive value(ADF, NDF, in vitro digestibility, and relative feed value) of hay was also high with treatment of mechanical, but those of chemical alone were similar compared with control. The nutritive value of hay after two months in both alfalfa and oats was decreased when compared with at harvest.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.41 no.3
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• pp.362-369
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• 1996

Seven different drying methods were tested in peony roots of Euisung cultivar, harvested in February, in three year's old plant. The roots were selected in length and diameter and half of the samples were removed cork-layers to compare the effects of cork-layer in processing of drying. The 3$0^{\circ}C$ heat drying without cork-layer reduced in days to drying by five days compared to those of the with cork-layers at the same temperature. The 5$0^{\circ}C$ heat drying after cork-layers removed was the most effective in days to drying. In quality of skin color of the 5$0^{\circ}C$ heating was worse to compare with the lower drying temperature. In the drying at room temperature and the heat drying at lower temperature, the paeoniflorin content in drying after cork-layers removed were higher than that of the drying with cork-layers. However, in the boiling water treatment, the paeoniflorin contents in drying after cork-layers removed were lower than those of with cork-layers. In heat drying, paeoniflorin content showed a decreasing tendency to increase of drying temperature. Total sugars in the peony roots showed a decreasing tendency according to the drying temperature increasing, but starch concentration showed a increasing tendency at the same condition. Concentrations of crude protein, crude fiber and crude ash were showed no differences in various drying methods and the materials with or without cork-layers. Relationships between the paeoniflorin and total sugars, and the paeoniflorin and starch were different significantly by the materials of cork-layers removed or not. The 30~4$0^{\circ}C$ heat drying without cork-layers was the most advisable condition for drying in paeoniflorin concentration, days to drying and skin color after drying.

• Korean Chemical Engineering Research
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• v.56 no.3
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• pp.430-434
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• 2018

In this study, an effective diffusion coefficient and mass transfer coefficient were investigated in microwave-assisted drying of paclitaxel for removal of residual methylene chloride. At all the temperatures (35, 45, and $55^{\circ}C$), a large amount of the residual methylene chloride was initially removed during the drying, and the drying efficiency increased when increasing the drying temperature. The effective diffusion coefficient ($1.299{\times}10^{-13}{\sim}2.571{\times}10^{-13}m^2/s$) and mass transfer coefficient ($1.625{\times}10^{-11}{\sim}4.857{\times}10^{-11}m/s$) increased with increasing drying temperature. The small Biot number (0.0100~0.0151) indicated that the process of mass transfer was externally controlled.

• Journal of The Korean Society of Grassland and Forage Science
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• v.19 no.3
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• pp.251-258
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• 1999

A field experiment was carried out to determine the effects of chemical /mechanical treatments at mowing on the field drying rate and hay quality of rye (Secale cereale L.). The chemical drying agent/mower conditioner ($K_2CO_3$ 2%, conditioning, $K_2CO_3$ 2% + conditioning and control) were treated at different harvest stage (late boot, heading and bloom stage) for hastening hay-making in the spring of 1996. After field dry, square bales were made by hay baler, and the dry matter(DM) loss, visual estimation and nutritive value of rye hay were evaluated after storing two months. The field drying rate of rye was higher with delayed stage of harvest, and mechanical and chemical + mechanical treatment, but the effectiveness of chemical alone was very low. With mower conditioning, the duration of field dry was shortened by 1.5 to 2 days compared with control. The DM loss of rye hay was reduced by late harvest and mechanical, and chemical + mechanical combined treatment, but the efficiency by chemical alone was very low. The visual score (Ieafiness, green color, odor and softness) of hay after storing was high in mechanical and chemical + mechanical, but the score by chemical alone was very low. The nutritive value (ADF, NDF, digestibility, and relative feed value) of hay was also high with treatment of mechanical and chemical + mechanical, but the quality by chemical alone was similar compared with control. The quality of hay was very low when harvested at bloom stage. In conclusion, mower conditioning can enhance the field drying rate of rye, but the drying effectiveness of chemical drying agent was very low. The effect of chemical/mechanical combined treatment was very similar when compared with mechanical alone. Harvest at early heading to heading stage was recommended for high quality rye hay.

• Journal of Nutrition and Health
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• v.8 no.4
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• pp.27-32
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• 1975

This investigation was designed to determine the influence of drying methods on the chemical changes in red pepper. Three different drying methods were employed: 1) Sun-drying at $25{\sim}28^{\circ}C$ for 15 days, 2) Drying in oven at $60^{\circ}C$ for 49 hours, and 3) Drying in oven at $90^{\circ}C$ for 8 hours. Dried and ground peels were used for the analysis of carotenoid pigments, capsaicin, and vitamin C. The results were as follows; 1. The total carotenoid content of sun-dried sample was more significantly in creased about 4% than that of the fresh sample, but both samples dried in oven were decreased about 30%. Among carotenoid groups, diol-polyol group was chiefly increased, and both samples dried in oven were decreased in the same trend; $17{\sim}18%$ reduction was found in hydrocarbons and monols and $36{\sim}38%$ was in diol-polyols. 2. In Capsaicin content in red pepper, the sun-dried sample was increased about twice of that of the fresh sample and both samples dried in oven were also tended to increase. 3. High reduction of vitamin C content was found in each treatment; 76% for the sun-dried and 89% for the oven-dried samples, respectively.

• Journal of the Korean Applied Science and Technology
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• v.28 no.3
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• pp.367-373
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• 2011

This research is a basic researching process for producing solid fuel that mixing paper sludge and Heat Transfer Medium Oil. Under the presence of Heat Transfer Medium Oil, paper sludge is heated and dried with home appliance microwave for comparing drying efficiency and energy efficiency of different types of drying method. As a result, Heat Transfer Medium Oil and paper mixing case of drying method, OMD, is the most efficient way to shorten the time for evaporating moisture in the paper sludge. In addition, heat transfer effect and density is increased with adding Heat Transfer Medium Oil by microwave. Future more, OMD's energy cost for evaporating whole moisture is 78% cheaper than MD. Also, OMD process shows the best energy efficiency with comparing other process. Evaporation rate of paper sludge evaporation process with microwave is 11.66% increased by adding Heat Transfer Medium Oil 150g. Preheating Heat Transfer Medium Oil or improving different ways injecting Heat Transfer Medium Oil is a good way to increase a rate of initiative moisture evaporation process.

• Korean Journal of Metals and Materials
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• v.47 no.8
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• pp.516-521
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• 2009

In this study we report a rapid synthesis of nanoporous organo-functional silica (OFS) with unimodal and bimodal pore structures encompassing pores ranging from meso-to macroscale. The problems of tediousness and high production cost in the conventional syntheses are overcome by co-condensation of an inexpensive inorganic precursor, sodium silicate with an organosilane containing trimethyl groups. The insitu covalent anchoring of the non-polar trimethyl groups to the inner pore walls prohibits irreversible shrinkage of the wet-gel during microwave drying at ambient pressure and thus larger size pores (from ca. 20 to ca. 100 nm) can be retained in the dried silica. The drying process of the silylated wet-gels at an ambient pressure can be greatly accelerated upon microwave exposure instead of drying in an oven or furnace. Using this approach, anoporous and superhydrophobic silicas showing a wide variation in texture and morphology can be readily synthesized in roughly two hours. The effects of various sol-gel parameters solely on the textural properties of the organo-functional silica (OFS) have been investigated and discussed.