• Journal of the Korea Concrete Institute
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• v.12 no.6
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• pp.51-56
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• 2000

Fly ash used as a cement replacement material increases the long term strength and also improves the durability of concrete and mortar. However, the use of fly ash is a little in spite of great benefit. In order to increase the consumption of fly ash, it has to be used as a cement replacement materials in the production of mortar and concrete, and the reduction of early strength development due to the use of fly ash also has to be diminished. In this study, many chemical compounds which accelerate the early strength was investigated. The $Na_2$$SO_4$, $K_2$$SO_4$, Triethanolamine were selected and applied to the production of mortar. It was found that they enhance the early strength development of mortar(1, 3day) and decrease the amount of $Ca(OH)_2$, and also increase the production of ettringite. According to the results of mercury instruction test, the pores ranged from 0.01 $\mu\textrm{m}$ to 5$\mu\textrm{m}$ were decreased and it was also found in the analysis of X ray and SEM that fly ash increases the amount of ettringite at early ages.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.156-157
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• 2017

It is possible in the case of the chemical admixtures for concrete currently being used in actual work sites to omit quality evaluation and replace it with the scores of the admixture manufactures; this can create a problem of decline in reliability in quality on the work site. Therefore this study sought to analyze the degree of influence changes in the solid content rate of lignin- and naphthalene-based water-reducing agents have on the fundamental characteristics of cement mortar. The results showed that in fresh mortar, the flow and amount of air decreases with decrease in the solid content ratio. In hardened mortar, the condensation strength had hardly any effect on the use of lignin-based water-reducing agent, but naphthalene-based water-reducing agent increased with the decrease in the solid content ratio.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06b
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• pp.387-390
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• 2006

Cationic rosin sizes are prepared by premixing extremely pure ployaluminum chloride (PAC) and dispersed rosin size (DRS). It turned out that zeta potential and particle size of the sizing agents took a big change by Plus90 analyzer's and FTIR analyzer's analysis. It turned out that -C=O and -COOH of the DRS have both chemical reaction with PAC to form the muti-hydroxyl aluminum rosin acid and that the cationic rosin sizes modified by PAC has dissymmetric and symmetric flexible vibration two absorbing peaks of the groups (its absorbing peaks $at1596cm^{-1}\;and\;1425cm^{-1}$). By DRS reacting with PAC, zeta potential of the resin size varied from negative to cationic. $Al_{2}O_{3}/rosin=1:0.3$, zeta potential of premixed admixture is tiptop28.8mv, When joined continuously PAC, zeta potential of cationic rosin sizes descend on the contrary.

• 한국문화재보존과학회:학술대회논문집
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• 2004.10a
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• pp.72-74
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• 2004

The color change of lead-containing pigments is one of the most serious diseases in watercolor, oil paintings and wall paintings. These pigments have a tendency to darken or brighten. It was proved that oxidation of lead containing pigments in the formation of brown-colored lead dioxide is a photochemical reaction under high humidity conditions. Therefore, we carried out some analogic experiments on the color change of three typical lead containing pigments ; $Pb_3O_4$, Pbo and $PbCo_3{\cdot}Pb(OH)_2$ at the conditions of illuminations under the high humidity ($2PbCo_3{\cdot}Pb(OH)_2$ R. H.). The reason for the chemical reactions are discussed and the results of these experiments are shown in some spectrograms, micrographs and X-ray micro-diffraction patterns. Important conclusions were drawn in our research. Due to the formation of brown $PbO_2$, red lead $(Pb_3O_4)$ and massicot (PbO) turned brown or dark when they were illuminated light under high humidity. We noticed that the brightening of red lead occurred d to admixture with chalk or lead white in egg yolk or linseed oil medium on exposure to light. Lead white used in oil paintings turned yellowish on dark.

• Journal of the Korea Concrete Institute
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• v.11 no.4
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• pp.21-29
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• 1999

In this study, an experiment was performed to analyze the influence of water-cement ratio on the fundamental characteristics of antiwashout underwater concrete using blended sand (sea sand:river sand = 1:1). The water-cement ratio (45%, 50%, 55%, 60%), andtiwashout underwater agent contents (0.82%, 1.00%, 1.14% of water contents per unit volume of concrete), and superplasticizer contents (1.5%, 2.0%, 2.5% of cement contents per unit volume of concrete) were chosen as the experimental parameters. The experimental results show that the underwater segregation resistance, unit weight of hardening concrete and compressive strength were increased as the water-cement ratio decreased and as the antiwashout underwater agent contents increased. On the other hand, the flowability(slump flow) was increased to the 55% of the increase of water-cement ratio, however, it was decreased at the ratio of 60%. From this study, the antiwashout underwater concrete can potentially be used as a materials underwater work of ocean if the water-cement ratio and chemical admixture contents for the suitable balance between cost and performance are properly selected.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.445-448
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• 2006

Mix design of C80A which is applied to the vertical members of The Burj Dubai Tower, the tallest building of the world, was performed so as to meet the requirements of rheological property, mechanical properties & construction sequences based on material analysis in Dubai, UAE. Experimental investigations were carried out to evaluate & optimize the quantities of total binders, the proportions of Micro Silica, Dune Sand & PFA, changes of S/a and the comparison of chemical admixture, etc. Approximately $65,000m^3$ of C80A concrete has been poured to the vertical members since 16-Apr-2006. In the actual application, it was showed that C80A has proper early strength achievement, excellent mechanical properties and satisfactory flowability & workability. The results of extensive site testing can be summarized that the average compressive strength at 28days is 98.8MPa, the average elastic modulus at 28days is 47.8GPa, the flow of concrete after pumping at the height of 250m (L72) was over 500mm.

• Advances in concrete construction
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• v.3 no.3
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• pp.223-236
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• 2015

Concrete is the most widely used material of construction. Concrete gained the popularity as a construction material due to the easy availability of its component materials, the easy formability, strength and rigidity upon setting and curing.In construction industry, strength is the primary criterion in selecting a concrete for a particular application. Now a days, the substantial amount of waste materials, containing the properties of the Pozzolana, is being generated from the major industries; and disposal of such industrial wastes generated in abundance is also a serious problem from the environmental and pollution point of view. On this backdrop, efforts are made by the researchers for exploring the possible utilization of such waste materials in making the sustainable construction material. The present paper reports the experimental investigations to study the strength characterization of concrete made from the pozzolanic waste materials. For this purpose, the Pozzolanic materials such as fly ash and ground granulated blast furnace slag were used as a cement replacing materials in conjunction with ordinary Portland cement. Equal amount of these materials were used in eight trial mixes with varying amount of cement. The water cement ratio was also varied. The chemical admixture was also added to improve the workability of concrete. The compressive strengths for 7, 28, 40 and 90 days' were evaluated whereas the flexural and tensile strengths corresponding to 7, 28 and 40 days were evaluated. The study corroborates that the pozzolanic materials used in the present investigation along with the cement can render the sustainable concrete.

• International conference on construction engineering and project management
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• 2015.10a
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• pp.405-410
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• 2015

Today, the booming construction in Ethiopia is leading to an increased demolition of concrete structures whereby these demolished structures are disposed at landfills. The current practice is creating a huge amount of waste which is environmentally unfriendly and is becoming the main source of pollution in communities. This paper discusses the potential use of demolished concrete from site tested specimens as a recycled aggregate material for new structural concrete. The mechanical, physical and chemical properties of RCA are studied to understand the suitability in the production of recycled concrete. Tests including gradation, unit weight, soundness, density, and abrasion will be conducted to assess RCA properties. Since the percentage of RCA govern the strength of concrete, a C25 concrete is mixed by the ratio of 25%, 50% & 100% RCA with and without water reducing admixture and a control mixture composed of natural aggregate. The output of this study will highly impact the growing construction industry and communities in Ethiopia thereby reducing waste, saving cost, conserving natural aggregates, building capacity and setting quality standards.

• Journal of the Korean GEO-environmental Society
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• v.4 no.4
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• pp.35-43
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• 2003

In this study, the physical and chemical characteristics of incinerated pulp and sewage sludge ashes for recycling and reuse were examined. Then we studied the application to the cement admixture by pozzolanic reaction. The particle size of incinerated pulp and sewage sludge ashes was distributed around $10{\sim}100{\mu}$, and the contents of $SiO_2$ and $Al_2O_3$ were 45.8~51.0%, respectively. Compressive strengths of the solidified ashes were relatively higher, when the content of substituted incineration ashes was 10% and the porosity was also lower except for the case of sewage sludge ash. As results, it is shown that it may be possible to recycle incinerated pulp sludge ashes as cement admixtures.

• Journal of the Korean Recycled Construction Resources Institute
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• v.1 no.3
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• pp.204-210
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• 2013

This study has focused on the possibility for recycling tailings from the Sangdong tungsten mine (TA) as admixture for concrete. TA has been accumulating for several decades in Sangdong, a region in Korea, and there is a growing demand for alternative uses for this hazardous substance. In particular, the use must be in accordance with the hazardous materials stipulations under the Korean waste control act. This study showed that TA presented pH of 8.0-9.3, 18.7-22.0% of water content, 2.7% of maximum ignition loss. The chemical composition of TA showed minute differences from each depth of sampling that represented approximately 50% of $SiO_2$ and 13% of both $Al_2O_3$ and $Fe_2O_3$. The chemical composition of Cd, Cu, Zn and Pb from mortar incorporating TA showed lower levels of hazardous materials which met the specifications of the waste control act in Korea. The TA mortar also appeared very effective for stabilizing/solidifying heavy metals particularly when used in conjunction with SG.