• Title/Summary/Keyword: Chemical Tools

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Fabrication of Micro Diamond Tip Cantilever for AFM-based Tribo-Nanolithography (AFM 기반 Tribo-Nanolithography 를 위한 초미세 다이아몬드 팁 켄틸레버의 제작)

  • Park Jeong-Woo;Lee Deug-Woo
    • Journal of the Korean Society for Precision Engineering
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    • v.23 no.8 s.185
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    • pp.39-46
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    • 2006
  • Nano-scale fabrication of silicon substrate based on the use of atomic force microscopy (AFM) was demonstrated. A specially designed cantilever with diamond tip, allowing the formation of damaged layer on silicon substrate by a simple scratching process, has been applied instead of conventional silicon cantilever for scanning. A thin mask layer forms in the substrate at the diamond tip-sample junction along scanning path of the tip. The mask layer withstands against wet chemical etching in aqueous KOH solution. Diamond tip acts as a patterning tool like mask film for lithography process. Hence these sequential processes, called tribo-nanolithography, TNL, can fabricate 2D or 3D micro structures in nanometer range. This study demonstrates the novel fabrication processes of the micro cantilever and diamond tip as a tool for TNL using micro-patterning, wet chemical etching and CVD. The developed TNL tools show outstanding machinability against single crystal silicon wafer. Hence, they are expected to have a possibility for industrial applications as a micro-to-nano machining tool.

Advanced Characterization Techniques of Organic Matter in Aqueous Solutions (물 속 유기물의 고도 특성 분석)

  • Shon, Ho Kyong;Vigneswaran, Saravanamuthu;Kandasamy, Jaya;Kim, Jong Beom;Kim, Jong-Ho
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.1-14
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    • 2011
  • Water is the most precious resource to human being, but it is polluted by different organic compounds. Organic matter (OM) in aqeous solutions is one of the important parameters of concern for human and environmental impact, and thus, it is essential to better characterize specifically targeted organic matter in aggregated and individual level of concentrations. This review presents different analytical tools and protocols to investigate detailed properties and characterization. Physical, chemical and biological aspects of OM are envisaged in terms of traditional and advanced measurement methods.

Perception of Workers and Managers for the Chemical Hazard (화학물질 유해성에 대한 작업자와 관리자들의 인식)

  • Cho, YongMin;Kim, Hee Jung;Choi, Jae-Wook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.22 no.4
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    • pp.293-300
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    • 2012
  • Objectives: In chemical hazard communication, information receiver's perception is a important factor, but the study on the perception was few. Therefore, this study evaluated the perception of managers and workers group about chemical hazard communication by chemical hazard communication tools that were being used in fields. Methods: 91 managers and 238 workers were surveyed in two companies where use chemicals. All subjects were asked about the comprehensibility and perception for MSDS and GHS Pictograms being used in their workplaces through face-to-face interviews. Results: Most of the respondents knew MSDS, and more than half of the respondents had used MSDS once or more per year. The level of use to find the information on chemicals with MSDS was higher in the managers in comparison with workers. Also, the managers could understand and find the information on MSDS easier(p < 0.05). In the question asking the meaning of GHS Pictograms, the managers responded more correctly, as well(p < 0.05). 86.8% of the managers and 62.6% of the workers were conscious of the possible health hazards of chemicals that they could be exposed at work. However, among the respondents conscious of the health hazards, only less than 70% were well aware of the contents of the health hazards correctly. Conclusions: In chemical hazard communication, it is very important to evaluate whether information receiver have proper and correct knowledge and perception or not and actions based on the evaluations as well as provide correct information.

Assessment of Chemical Risks in Moroccan Medical Biology Laboratories in Accordance with the CLP Regulation

  • Mourry, Ghita E.;Alami, Rachid;Elyadini, Adil;Hajjaji, Souad El;kabba, Saad El;Zouhdi, Mimoun
    • Safety and Health at Work
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    • v.11 no.2
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    • pp.193-198
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    • 2020
  • Background: Medical laboratory workers are frequently exposed to a wide range of chemicals. This exposure can have adverse effects on their health. Furthermore, a knowledge lack of the chemical risk increases the likelihood of exposure. The chemical risk assessment reduces the risk of exposure to hazardous chemicals and therefore, guarantees health and safety of the workers. Method: The chemical risk assessment was conducted using a modified INRS method, according to the new CLP Regulation, of 11 unit laboratories in a Moroccan medical laboratory. Observation of each workstation and analysis of safety data sheets are key tools in this study. Results: A total of 144 substances and reagents that could affect the health of the analytical technicians were identified. Among these products, 17% are concerned by the low priority risk score, with 55% concerned by the average priority risk score and 28% concerned by the high priority risk score. This study also enabled to better identify the chemical agents that have restrictive occupational exposure limit value and controls were conducted to this effect. On the basis of the results obtained, several corrective and preventive measures have been proposed and implemented. Conclusion: Risk assessment is essential to ensure the health and safety of workers and to meet regulatory requirements. It enables to identify all the risky manipulations and to adopt appropriate preventive measures. However, it is not a one-time activity but it must be continuous in order to master the changes and thus ensure the best safety of all.

Thermal and Mechanical Properties of Electro-Slag Cast Steel for Hot Working Tools

  • Moon Young Hoon;Kang Boo Hyun;Van Tyne Chester J.
    • Journal of Mechanical Science and Technology
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    • v.19 no.2
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    • pp.496-504
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    • 2005
  • The thermal and mechanical properties of an electro-slag cast steel of a similar chemical composition with an AISI-6F2 steel are investigated and compared with a forged AISI-6F2 steel. AISI-6F2 is a hot-working tool steel. Electro-slag casting (ESC) is a method of producing ingots in a water-cooled metal mold by the heat generated in an electrically conductive slag when current passes through a consumable electrode. The ESC method provides the possibility of producing material for the high quality hot-working tools and ingots directly into a desirable shape. In the present study, the thermal and mechanical properties of yield strength, tensile strength, hardness, impact toughness, wear resistance, thermal fatigue resistance, and thermal shock resistance for electro-slag cast and forged steel are experimentally measured for both annealed and quenched and tempered heat treatment conditions. It has been found that the electro-slag cast steel has comparable thermal and mechanical properties to the forged steel.

A Study on Development of the Assessment System for the Program Outcomes on the Communication Skill Competence (의사소통 능력에 대한 학습성과 평개발에 관한 연구)

  • Kim, Jin-Young;Kang, Sung-Ju;Kang, Bo-Seon;Kim, Dae-Ik
    • Journal of Engineering Education Research
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    • v.14 no.6
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    • pp.41-47
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    • 2011
  • Professional communication skills in writing and speaking with multiple and complex audiences are required to engineers in society of modern technology. In this paper, we proposed the effective assessment system for the Program Outcomes on the communication skill competence(PO7), which is one of the 12 program outcomes stipulated by ABEEK (Accreditation Board for Engineering Education of Korea). To ensure logical connectivity of the assessment system, we carefully selected the performance criteria by defining the core concept of "written communication" and "verbal communication". Based on the selected performance criteria, the whole process of creating assessment tools and rubrics was explained in detail. It can be expected that the assessment for the Program Outcomes on the communication skill competence would be more systematic by using the proposed assessment system.

Fuzzy inference systems based prediction of engineering properties of two-stage concrete

  • Najjar, Manal F.;Nehdi, Moncef L.;Azabi, Tareq M.;Soliman, Ahmed M.
    • Computers and Concrete
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    • v.19 no.2
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    • pp.133-142
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    • 2017
  • Two-stage concrete (TSC), also known as pre-placed aggregate concrete, is characterized by its unique placement technique, whereby the coarse aggregate is first placed in the formwork, then injected with a special grout. Despite its superior sustainability and technical features, TSC has remained a basic concrete technology without much use of modern chemical admixtures, new binders, fiber reinforcement or other emerging additions. In the present study, an experimental database for TSC was built. Different types of cementitious binders (single, binary, and ternary) comprising ordinary portland cement, fly ash, silica fume, and metakaolin were used to produce the various TSC mixtures. Different dosages of steel fibres having different lengths were also incorporated to enhance the mechanical properties of TSC. The database thus created was used to develop fuzzy logic models as predictive tools for the grout flowability and mechanical properties of TSC mixtures. The performance of the developed models was evaluated using statistical parameters and error analyses. The results indicate that the fuzzy logic models thus developed can be powerful tools for predicting the TSC grout flowability and mechanical properties and a useful aid for the design of TSC mixtures.

Characteristics of Machined Surface Roughness and Surface Layers of WC-Co Tools with Plasma Source Ion Implantation (WC-Co 공구의 이온 주입에 따른 표면층 및 가공된 표면거칠기 특성)

  • Kang, Seong-Ki;Kim, Yung-Kyu;Wang, Duck-Hyun;Chun, Young-Rok;Kim, Won-Il
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.9 no.1
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    • pp.106-113
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    • 2010
  • The most suitable condition for plasma source ion implantation(PSII) was found based on the study of the characteristics of PSIIed tool and machined surfaces. The depth analysis according to the chemical bonding state of elements and surface component elements through the XPS and SIMS, was conducted to find the improved property of the PSIIed surface. Due to the diffusion of PSII, the nitrogen was found up to a depth of about 150nm according to the supplied voltage and ion implanted time. The deep diffusion by nitrogen caused the surface modification, but the formation of oxide component was found due to the residual gas contamination on the surface. Statistical method of ANOVA was conducted to find the effects of spindle speed and feed rate in interaction for machined surface roughness with PSIIed tools. The surface modification was found largely occurred by the nitrogen implanted surface with 2 hours for 27kV, 35kV and 43kV.

A Study on the Chemically Vapor Deposited TiC, TiN, and TiC(C, N) on $Si_3N_4$-TiC Ceramic Tools. ($Si_3N_4-TiC$ Ceramic 공구에 화학증착된 TiC, TiN 및 Ti(C, N)에 관한 연구)

  • 김동원;김시범;이준근;천성순
    • Tribology and Lubricants
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    • v.4 no.2
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    • pp.36-43
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    • 1988
  • Titanium carbide(TiC) and titanium nitride(TiN) flims were deposited on $Si_3N_4$-TiC composite cutting tools by chemical vapor deposition(CVD) using $TiCl_4-CH_4-H_2$ and $TiCl_4-H_2-N_2$ gas mixtures, respectively. The nonmetal to metal ratio of deposit increases with increasing $m_{C/Ti}$(mole ratio of CH$_4$ to TiCl$_4$ in the input) for TiC coatings and $m_{N/Ti}$(mole ratio of N$_2$ to TiCl$_4$ in the input) for TiN coatings. The nearly stoiahiometric films could be obtained under the deposition condition of $m_{C/Ti}$ between 1.15 and 1.61 for TiC, and that of $m_{N/Ti}$ between 25 and 28 for TiN. Also maximum microhardness of the coatings can be obtained in these ranges. The interfacial region of TiC coatings on $Si_3N_4$-TiC ceramics is wider than that of TiN coatings according to Auger depth profile analysis, which indicates good interfacial bonding for TiC. Experimental results show that TiC coatings have an randomly equiaxed structure and Columnar structure with(220) preferred orientation can be obtained for TiN coatings. And, multilayer coatings have a dense and equiaxed structure.

Alteration of Physical and chemical Characteristics of Waterlogged Archaeological Woods After Cleaning (세척 후 수침고목재의 물리.화학적 특성 변화)

  • Cha, Mi-Young;Lee, Kwang-Ho;Kim, Yoon-Soo
    • Journal of Conservation Science
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    • v.19
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    • pp.19-30
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    • 2006
  • Alteration of physical and chemical characteristics and the effect of removal of mineral substances in waterlogged archaeological woods by different cleaning processes were examined using oak wood(Quercus spp.) that was excavated from wetland near Gwangju, Korea. Cleaning methods employed in the present work were (1) tools, (2) deaeration, (3) EDTA and (4) ultrasonic cleaning, which are being currently applied in the field of preservation treatment. Cleaning process were performed independently or continuously. Composition of mineral substances in the waterlogged archaeological wood was almost same as the that of soil in which waterlogged archaeological woods were buried. In case of independent cleaning, tools cleaning efficiently removed the mineral substances on surface. Surface color become brighter after cleaning with EDTA. In contrast, deaeration and ultrasonic cleaning did not show any significant removal of mineral substances. In continuous cleaning process, tool cleaning as the first step treatment showed the same effect as shown in independent cleaning. Although deaeration as the second step cleaning did not remove the mineral substances, it could be assumed to contribute the infiltration of dimensional agents by homogenization of wood. EDTA treatment (the third step cleaning) removed the iron(Fe) and increased the whiteness of wood color. The ultrasonic treatment (the fourth step cleaning) removed the sodium(Na) remained after EDTA treatment and the fine mineral substances.

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