• 한국유기농업학회지
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• 제9권1호
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• pp.61-73
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• 2001

This study was conducted to investigate the effect of sewage sludge application on the growth of chinese cabbage and the changes of chemical properties of soil. The experiment were set up with two different place and cultivated from Feb. 10 to June. 20 of 2000. Treatments are 0, 1.25, 2.5, 5, 10 and 20kg/3.3$\m^2$ of sewage sludge applicated into the soil and recorded the growth characteristics. Chemical properties of soil were also analysed before and after treatment. The application of the sewage sludge resulted in increasing the content of EC, cations exchange capacity, available phosphate and organic matter. And increased the growth characteristics in terms of the number of leaves, leaf area, fresh and dry weight regardless of crops experiments. Optimum amount of the sewage sludge depended on chemical properties of soil used. This results demonstrated that application of sewage sludge in the soil attribute to have play an important both improving soil chemical properties and promoting the crop growth. As lowering the soil pH(pH 6) heavy metal content increased compared with higher pH(pH 7). Feasibility was recognized in the application of sewage sludge as a fertilizer for the growth of chinese cabbage. Detrimental effects such as heavy metal in the soil and crop followed by the application of sewage sludge was not observed.

• 한국물환경학회지
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• 제26권2호
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• pp.349-355
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• 2010

Electroflotation (EF) was conducted for activated sludge thickening to investigate the effects of sludge SVI (sludge volume index) and chemical conditioning. Return sludge samples were used for the experiment, which were collected from municipal wastewater treatment plants. The performance of sludge thickening was significantly dependent on sludge SVI. For the sludges with SVI values in a range from 50 to about 150 mL/g, the maximum float content decreased rapidly from 8.4 to 3.5% and flotation compressibility followed the same pattern. In cases of sludges with SVI higher than 150 mL/g, those results showed low content levels without large changes. Gas/solids ratio tended to increase with an increase in SVI. When polyelectrolyte was added into sludges for the conditioning, compressibility increased up to 75% and gas/solids ratio was reduced up to about 35% under the condition of microbubble production rate of 530 mL/h, however, there was no consistent effect of chemical conditioning on the maximum float solids content; some cases were positive but the others negative. It was expected that the optimum dose of electrolyte depends on sludge SVI and an excessive chemical dose causes a performance deterioration of flotation thickening.

• 공업화학
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• 제27권1호
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• pp.62-67
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• 2016

본 연구에서는 정수슬러지를 원료로 사용하여 펠렛형 흡착제를 제조하고 질소흡착법, XRD, XRF 및 암모니아 승온탈착법 등을 사용하여 물리 화학적 특성을 분석하였다. 정수슬러지 유래 펠렛형 흡착제와 첨착활성탄의 암모니아 및 포름알데히드 기체의 흡착 성능을 비교하였다. 정수슬러지로부터 제조된 펠렛형 흡착제는 첨착활성탄보다 표면적과 기공부피는 훨씬 작지만 암모니아를 훨씬 더 많이 흡착할 수 있었다. 이는 정수슬러지로부터 제조된 펠렛형 흡착제 표면에 산점이 훨씬 더 많이 분포해 있어서 화학흡착에 의해 암모니아를 흡착하기 때문이다. 반면에, 산성가스인 포름알데히드 가스 흡착의 경우는 넓은 표면적과 발달된 기공으로 인하여 첨착활성탄의 흡착성능이 정수슬러지로부터 제조된 펠렛형 흡착제에 비해 훨씬 우수하였다.

• 대한화학회지
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• 제55권5호
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• pp.842-845
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• 2011

Wet air oxidation (WAO) of oily sludge was carried out using $Fe^{3+}$ as catalyst, placed in a 0.5 L batch autoclave in the temperature range of $250-330^{\circ}C$. Experiments were conducted to investigate the effects of temperature, the initial COD, reaction time, concentration of catalyst and $O_2$ excess (OE) on the oxidation of the oily sludge. The results showed that in the WAO 88.4% COD was achieved after 9 min reaction at temperature of $330^{\circ}C$, OE of 0.8 and the initial COD of 20000 mg/L. Temperature was found to have a significant impact on the oxidation of oily sludge. Adding a catalyst significantly improved the COD removal. Homogenous catalyst, $Fe^{3+}$, showed effective removal for pollutants. COD removal was 99.7% in the catalytic wet air oxidation (CWAO) over $Fe^{3+}$ catalyst. The results proved that the CWAO was an effective pretreatment method for the oily sludge.

• Korean Chemical Engineering Research
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• 제47권6호
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• pp.775-780
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• 2009

폐수 방류수 중에 포함될 수 있는 내분비계 장애물질의 제거를 위해 생물학적 영양소 제거 공정에 존재하는 질산화 슬러지의 효용성을 탐색하여 보았다. 질산화 슬러지에 포함된 암모니아 산화균은 ammonia monooxygenase(AMO) 활성에 의해 암모니아 산화를 유발하는데, AMO의 기질 특이성이 낮아 암모니아 산화와 동시에 다양한 화합물이 공산화된다고 알려져 왔다. 본 연구에서는 이러한 공산화 활성이 내분비계 장애물질의 제거에 효과적인지 판단하기 위해, 질산화 슬러지, 유기물산화 슬러지, 멸균 슬러지를 각각 이용하여 3가지의 모델물질(bisphenol A(BPA), nonylphenol(NP), dibutyl phthalate(DBP))에 대한 제거 효율을 비교하였다. 질산화 슬러지에 의한 분해에서는 3가지 모델물질 모두, 배지 중에 질소원으로 아질산염보다 암모늄염을 이용했을 때의 초기 분해속도가 빠르게 나타나서 암모니아 산화 활성과 모델 물질의 분해가 관련이 있는 것으로 나타났다. 반면에 아질산염을 공급한 질산화슬러지에서나 혹은 질산화 활성이 낮은 유기물산화 슬러지를 이용한 경우는 일정한 적응 시간이 지난 이후에 모델 물질들의 분해가 시작되었다. 이는 모델 물질을 탄소원으로 이용하는 균주의 성장 및 활성이 일정한 적응 시간 이후에 나타난 것으로 보인다. 모델 물질의 제거에 슬러지에 의한 물리적 흡착이 어느 정도 기여하는지 확인하기 위해서 멸균 슬러지를 이용한 흡착 제거를 시도하였다. 초기 투입량의 10~20% 내외가 흡착에 의해 상등액에서 제거되었는데, 이를 통해 폐수 슬러지를 이용한 BPA, NP, DBP의 제거에는 물리적 흡착보다는 생물학적 분해 기작이 더 중요한 것으로 보인다.

• 유기물자원화
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• 제31권3호
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• pp.35-41
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• 2023

본 연구에서는 반도체 제조공정에서 발생하는 실리콘 슬러지에 금속산화물인 이산화티타늄을 코팅하였으며, 이를 안료 및 도료의 소재로 응용하였다. 상세히는, 불순물이 제거된 판상형의 실리콘 슬러지 분말에 졸-겔법을 통해 이산화티타늄을 코팅하였다. 안료 및 도료의 소재로서 응용 가능성을 확인하기 위해서 친수성 투명 코팅제에 분산하여 페인트를 제조한 후 유리 기판에 분사하였다. 그 결과, 이산화티타늄의 도입으로 인한 발림성 향상과 하얀색의 발현을 확인할 수 있었다. 본 연구를 통해서 실리콘 슬러지에 이산화티타늄을 코팅함으로써 발림성 및 친수성이 향상됨을 확인하였으며, 이를 통해서 반도체 공정에서 발생하는 실리콘 슬러지가 안료 및 도료의 소재로서 응용 가능성을 확인하였다.

• Ocean Science Journal
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• 제40권2호
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• pp.91-100
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• 2005

Bioassay using the marine bacteria, Vibrio fischeri and rotifer, Brachionus plicatilis, and chemical analyses were conducted to assess the toxicity of the various sewage sludges, one of the major ocean dumped materials in the Yellow Sea of Korea. Sludge elutriates extracted by filtered seawater were used to estimate the ecotoxicity of the sludge. Chemical characterization included the analyses of organic contents, heavy metals, and persistent organic pollutants in sludge. Bacterial bioluminescent inhibition (15 min), rotifer mortality (24 hr) and rotifer population growth inhibition (48 hr) assay were conducted to estimate the sludge toxicity. EC50 15 min (inhibition concentration of bioluminescence after 15 minutes exposed) values by Microtox(R) bioassay clearly revealed different toxicity levels depending on the sludge sources. Highest toxicity for the bacteria was found with the sludge extract from dyeing waste and followed by industrial waste, livestock waste, and leather processing waste. Clear toxic effects on the bacteria were not found in the sludge extract from filtration bed sludge and rural sewage sludge. Consistent with Microtox(R) results, rotifer neonate mortality and population growth inhibition test also showed highest toxicity in dyeing waste and low in filtration bed and rural sewage sludge. High concentrations of persistent organic pollutants (POPs) and heavy metals were measured in the samples from the industrial wastes, leather processing plant waste sludge, and urban sewage sludge. However, there was no significant correlation between pollutant concentration levels and the toxicity values of the sludge. This suggests that the ecotoxicity in addition to the chemical analyses of various sludge samples must be estimated before release of potential harmful waste in the natural environment as part of an ecological risk assessment.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2004년도 학술대회지
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• pp.21-26
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• 2004

This study deals with the Hydrated Ability of the Ready-Mixed Concrete's Sludge which is the recycling technology of that sludge. The experiment gathers sludge from Ready-mixed factory. shatters these into pieces in dry condition and understands the differences between current using Portland cement. And then. this examines the possibility of the recycle as a bonding agent through the Compressive Strength and considers the recovery of the hydration. This experiment concludes the same Chemical Composition with the normal Portland cement. while. under the appropriate procedure in hydration recovery. this sludge can be used as the bonding agent in cement. The chemical composition of solid Remicon sludge shows that it has 1.8 times $SiO_2$ than the normal Portland cement. meaning lots of aggregate in Remicon sludge. Also. the specific gravity of Remicon sluge increases with the rise of Baking Temperature and has no difference between 2.77 and 2.94. The mortar flow used for combining the baking material of Remicon sludge does was not changed and is the highest between $750^{\circ}C{\cdot}120min\;and\;800^{\circ}C{\cdot}180min$. Additionally. the Compressive Strength increases with the age, certifying the same Hydrated Ability like cement and the best condition for hydration is $750^{\circ}C{\cdot}120min.$

• 한국초지조사료학회지
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• 제17권1호
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• pp.51-58
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• 1997

An experiment of alum sludge application was carried out on a mountainous site, to know its effect on the growth of forage sorghum hybrid, Pioneer 93 1 (Sorghum bicolor x S. bicolor). When alum sludge with 80% water content was applied at the level of 133 ton per ha, the effect of the application on the growth of Pioneer 931 was much smaller than that of chemical fertilizer. But Eresh yield of the forage, with the sludge application, was greater than that without fertilizer when the soil is not fertile. But when the soil was comparatively fertile, the sludge application gave an adverse affect on the growth of the forage plant. The content of exchangeable K in the soil has a very close positive relation with the Eresh yield and plant height of the plant, while that of exchangeable Ca has a close negative relation with those growing factors. There was a tendency of yield decrease of the forage plant, when alum or compost was applied with NPK to the comparatively infertile soil especially for alum sludge. As a result, when soil is not fertile more attention will be necessary for applying alum sludge with chemical fertilizers. But to soil with better fertility, it is recommended to use alum sludge with chemical fertilizer to obtain more yield of the forage plant.

• 한국토양비료학회지
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• 제33권6호
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• pp.463-471
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• 2000

본 연구는 하수오니의 농경지 이용 가능성을 밝히고자 중랑, 가좌, 나주 및 용인 하수 종말 처리장에서 채취한 하수오니를 처리한 토양에서 옥수수와 배추를 재배하여 생육 및 토양의 화학성 변화에 미치는 영향을 검토하였다. 옥수수의 생육조사결과 오니 처리율이 증가할수록 초기 생육이 저조하였다. 배추의 생육 조사 결과 초기 3주간은 12.5 및 $25Mg\;ha^{-1}$ 처리구가 좋은 생육을 보였고 후기에는 50및 $100Mg\;ha^{-1}$처리구의 생육이 더 좋은 결과를 나타내었다. 그러나 최대 생장을 보인 처리구도 화학비료 시용구에서의 생육에는 미치지 못했다. 양이온치환용량, 유기물 및 질소의 경우는 처리간의 차이는 뚜렷하였지만 재배 전후에는 큰 차이가 없었다. Na, K, Ca, Mg 등의 염기류들도 비슷한 경향을 보였다. 토양포화침출액의 EC는 재배 전과 비교하여 재배후에 감소하였고 오니처리량이 많을수록 감소폭이 커서 재배전보다 오니 처리량 간의 차이가 줄었으나 유료인산 함량은 재배중 뚜렷한 증가 경향이 나타났다. 따라서 오니시용기준은 질소가 아닌 인산을 기준으로 하여 처리량을 결정하며 부족분은 화학비료로 보충하도록 하는 것이 바람직한 것으로 사료된다.