• Title/Summary/Keyword: Chemical Sensors

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Analysis of Two-Dimensional Fluorescence Spectra in Biotechnological Processes by Artificial Neural Networks I - Classification of Fluorescence Spectra using Self-Organizing Maps - (인공신경망에 의한 생물공정에서 2차원 형광스펙트럼의 분석 I - 자기조직화망에 의한 형광스펙트럼의 분류 -)

  • Lee Kum-Il;Yim Yong-Sik;Kim Chun-Kwang;Lee Seung-Hyun;Chung Sang-Wook;Rhee Jong Il
    • KSBB Journal
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    • v.20 no.4
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    • pp.291-298
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    • 2005
  • Two-dimensional (2D) spectrofluorometer is often used to monitor various fermentation processes. The change in fluorescence intensities resulting from various combinations of excitation and emission wavelengths is investigated by using a spectra subtraction technique. But it has a limited capacity to classify the entire fluorescence spectra gathered during fermentations and to extract some useful information from the data. This study shows that the self-organizing map (SOM) is a useful and interpretative method for classification of the entire gamut of fluorescence spectral data and selection of some combinations of excitation and emission wavelengths, which have useful fluorometric information. Some results such as normalized weights and variances indicate that the SOM network is capable of interpreting the fermentation processes of S. cerevisiae and recombinant E. coli monitored by a 2D spectrofluorometer.

Operation diagnostic based on PCA for wastewater treatment (PCA를 이용한 하폐수처리시설 운전상태진단)

  • Jun Byong-Hee;Park Jang-Hwan;Chun Myung-Geun
    • Journal of the Korean Institute of Intelligent Systems
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    • v.16 no.3
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    • pp.383-388
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    • 2006
  • SBR is one of the most general sewage/wastewater treatment processes and, particularly, has an advantage in high concentration wastewater treatment like sewage wastewater. A Kernel PCA based fault diagnosis system for biological reaction in full-scale wastewater treatment plant was proposed using only common bio-chemical sensors such as ORP(Oxidation-Reduction Potential) and DO(Dissolved Oxygen). During the SBR operation, the operation status could be divided into normal status and abnormal status such as controller malfunction, influent disturbance and instrumental trouble. For the classification and diagnosis of these statuses, a series of preprocessing, dimension reduction using PCA, LDA, K-PCA and feature reduction was performed. Also, the diagnosis result using differential data was superior to that of raw data, and the fusion data show better results than other data. Also, the results of combination of K-PCA and LDA were better than those of LDA or (PCA+LDA). Finally, the fault recognition rate in case of using only ORP or DO was around maximum 97.03% and the fusion method showed better result of maximum 98.02%.

Wirelessly Driven Cellulose Electro-Active Paper Actuator: Application Research (원격구동 셀룰로오스 종이 작동기의 응용연구)

  • Kim, Jae-Hwan;Yang, Sang-Yeol;Jang, Sang-Dong;Ko, Hyun-U;Mun, Sung-Cheol;Kim, Dong-Gu;Kang, Jin-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.5
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    • pp.539-543
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    • 2012
  • Cellulose Electro-Active Paper (EAPap) is attractive as a biomimetic actuator because of its merits: it is lightweight, operates in dry conditions, has a large displacement output, has a low actuation voltage, and has low power consumption. Cellulose is regenerated so as to align its microfibrils, which results in a piezoelectric paper. When chemically bonded and mixed with carbon nanotubes, titanium oxide, zinc oxide, tin oxides, the cellulose EAPap can be used as a hybrid nanocomposite that has versatile properties and that can meet the requirements of many application devices. This paper presents trends in recent research on the cellulose EAPap, mainly on material preparation and its use in devices, including biosensors, chemical sensors, flexible transistors, and actuators. This paper also explains wirelessly driving technology for the cellulose EAPap, which is attractive for use in biomimetic robotics and micro-aerial vehicles.

Preparation of Hydrogels Containing Polypyrrole@lignin Hybrids and Application in Sensors (전도성 고분자/리그닌 복합소재를 함유한 하이드로젤의 제조 및 센서 응용)

  • Park, Sun Young;Park, Soyeon;Kim, Hye Jun;Im, Youngsoon;Bae, Joonwon
    • Applied Chemistry for Engineering
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    • v.31 no.4
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    • pp.411-415
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    • 2020
  • In this article, the preparation of hydrogels containing conducting polymer@lignin hybrids and their application to sensing materials were demonstrated using diverse techniques. A conducting polymer, polypyrrole (PPy) was polymerized on the surface of lignin and successful formation was analyzed with Fourier-transform infrared spectroscopy and scanning electron microscopy. Subsequently, PPy@lignin hybrids were mixed with a hydrogel matrix to obtain a conductive hydrogel. The feasibility of using the hydrogel as a sensing material was shown by obtaining reasonable sensing signals using various electrical measurements when adding solvents and solutions to the sensor system. The significance of sensor signals was confirmed with complementary experiments. This study shows that the hydrogel containing the PPy@lignin could be used for sensor applications.

High Performance of SWIR HgCdTe Photovoltaic Detector Passivated by ZnS

  • Lanh, Ngoc-Tu;An, Se-Young;Suh, Sang-Hee;Kim, Jin-Sang
    • Journal of Sensor Science and Technology
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    • v.13 no.2
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    • pp.128-132
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    • 2004
  • Short wave infrared (SWIR) photovoltaic devices have been fabricated from metal organic vapour phase epitaxy (MOVPE) grown n- on p- HgCdTe films on GaAs substrates. The MOVPE grown films were processed into mesa type discrete devices with wet chemical etching employed for meas delineation and ZnS surface passivatlon. ZnS was thermally evaporated from effusion cell in an ultra high vacuum (UHV) chamber. The main features of the ZnS deposited from effusion cell in UHV chamber are low fixed surface charge density, and small hysteresis. It was found that a negative flat band voltage with -0.6 V has been obtained for Metal Insulator Semiconductor (MIS) capacitor which was evaporated at $910^{\circ}C$ for 90 min. Current-Voltage (I-V) and temperature dependence of the I-V characteristics were measured in the temperature range 80 - 300 K. The Zero bias dynamic resistance-area product ($R_{0}A$) was about $7500{\Omega}-cm^{2}$ at room temperature. The physical mechanisms that dominate dark current properties in the HgCdTe photodiodes are examined by the dependence of the $R_{0}A$ product upon reciprocal temperature. From theoretical considerations and known current expressions for thermal and tunnelling process, the device is shown to be diffusion limited up to 180 K and g-r limited at temperature below this.

In-situ P-doped LPCVD Poly Si Films as the Electrodes of Pressure Sensor for High Temperature Applications (고온용 압력센서 응용을 위한 in-situ 인(P)-도핑 LPCVD Poly Si 전극)

  • Choi, Kyeong-Keun;Kee, Jong;Lee, Jeong-Yoon;Kang, Moon Sik
    • Journal of Sensor Science and Technology
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    • v.26 no.6
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    • pp.438-444
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    • 2017
  • In this paper, we focus on optimization of the in-situ phosphorous (P) doping of low-pressure chemical vapor deposited (LPCVD) poly Si resistors for obtaining near-zero temperature coefficient of resistance (TCR) at temperature range from 25 to $600^{\circ}C$. The deposited poly Si films were annealed by rapid thermal anneal (RTA) process at the temperature range from 900 to $1000^{\circ}C$ for 90s in nitrogen ambient to relieve intrinsic stress and decrease the TCR in the poly Si layer and get the Ohmic contact. After the RTA process, a roughness of the thin film was slightly changed but the grain size and crystallinity of the thin film with the increase in anneal temperature. The film annealed at $1,000^{\circ}C$ showed the behavior of Schottky contact and had dislocations in the films. Ohmic contact and TCR of $334.4{\pm}8.2$ (ppm/K) within 4 inch wafer were obtained in the measuring temperature range of 25 to $600^{\circ}C$ for the optimized 200 nm thick-poly Si film with width/length of $20{\mu}m/1,800{\mu}m$. This shows the potential of in-situ P doped LPCVD poly Si as a resistor for pressure sensor in harsh environment applications.

A Study on CO2 Sensor Module Using NDIR Method (비분산 적외선 방식의 CO2 센서 모듈에 관한 연구)

  • Kim, Gyu-Sik;Oh, Joon-Tae;Kim, Hie-Sik;Kim, Jo-Chun
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.46 no.2
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    • pp.36-40
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    • 2009
  • In this paper we discuss about the practical implementation of a combined CO and CO2 dual sensor module that is adapted by NDIR (Non-Dispersive Infrared) method that measures the absorbance of gas like CO and CO2 by using gas particles' characteristics that absorb specific wave lengths of infrared ray. NDIR has a long life time, excellent measurement and precision compared to the existing contact types or chemical types of CO2 sensors. Since optical cavity technology that had been developed until now can measure CO2 only we research and develop an optimal optical cavity design and density-temperature calibration technologies that can measure CO and CO2 at the same time and is important to decide the performance of the sensor module according to well-designed wave guides of the different length.

The Analysis of NOx Gas Detection Characteristics for the Gas Sensor Using the MWCNT/ZnO Composites Film (MWCNT/ZnO 복합체 필름을 이용한 가스센서의 NOx가스 검출 특성 분석)

  • Kim, Hyun-Soo;Lee, Won-Jae;Park, Yong-Seo;Jang, Kyung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.5
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    • pp.312-316
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    • 2016
  • In this study, we fabricated $NO_x$ gas sensor by using multi-walled carbon nanotubes(MWCNT)/zinc oxide(ZnO) composite film. Carbon nanotubes (CNTs) have good electronic, chemical-stability, and sensitivity characteristics. And zinc oxide (ZnO) is a wide band gap and large exciton binding energy semiconductor. In particular, gas sensors require characteristics such as high speed, sensitivity, and selectivity. The fabricated gas sensor was used to detect $NO_x$ gas for different values of the $NO_x$ gas concentrations. The gas sensor that absorbed$NO_x$ gas molecules showed a increasing in resistance. The sensitivity of the gas sensor was increased by increasing the gas concentrations. Additionally, while changing the temperature inside the chamber for the MWCNT/ZnO composite film gas sensor, we obtained the sensitivity. And the comparison analysis to ZnO film gas sensor for detecting $NO_x$ gas. From the experiment result, we confirmed improvement of $NO_x$ gas detection characteristics using the MWCNT/ZnO composite film.

Analysis of Acoustic Emission Signal Sensitivity to Variations in Thin-film Material Properties During CMP Process (CMP 공정중 박막 종류에 따른 AE 신호 분석)

  • Park, Sun Joon;Lee, Hyun Seop;Jeong, Hae Do
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.8
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    • pp.863-867
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    • 2014
  • In this study, an acoustic emission (AE) sensor was used for measuring the abrasive and molecular-scale phenomena in chemical mechanical polishing (CMP). An AE sensor is a transducer that converts a mechanical wave into an electrical signal, and is capable of acquiring high-level frequencies from materials. Therefore, an AE sensor was installed in the CMP equipment and the signals were measured simultaneously during the polishing process. In this study, an AE monitoring system was developed for investigating the sensitivity of the AE signal to (a) the variations in the material properties of the pad, slurry, and wafer and (b) the change in conditions during the CMP process. This system was adapted to Oxide and Cu CMP processes. AE signal parameters including AE raw frequency, FFT, and amplitude were analyzed for understanding the abrasive and molecular-level phenomena in the CMP process. Finally, we verified that AE sensors with different bandwidths could function in complementary ways during CMP process monitoring.

Effect of process parameters of antimony doped tin oxide films prepared on flexible substrate at room temperature

  • Lee, Seong-Uk;Hong, Byeong-Yu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.175-175
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    • 2010
  • Transparent conducting oxide (TCO) films are widely used as transparent conducting thin film material for application in various fields such as solar cells, optoelectronic devices, heat mirrors and gas sensors, etc. Recently the increased utilization of many transparent electrodes has accelerated the development of inexpensive TCO materials. Indium tin oxide (ITO) film is well-known for TCO materials because of its low resistivity, but there is disadvantage that it is too expensive. ZnO film is cheaper than ITO but it shows thermally poor stability. On the contrary, antimony-doped tin oxide films (ATO) are more stable than TCO films such as Al-doped zinc oxide (AZO) and ITO. Moreover, SnO2 film shows the best thermal and chemical stability, low cost and mechanical durability except the poor conductivity. However, annealing is proved to improve the conductivity of ATO film. Therefore, in this work, antimony (6 wt%) doped tin oxide films to improve the conductivity were deposited on 7059 corning glass by RF magnetron sputtering method for the application to transparent electrodes. In general, of all TCO films, glass is the most commonly selected substrate. However, for future development in flexible devices, glass is limited by its intrinsic inflexibility. In this study, we report the growth and properties of antimony doped tin oxide (ATO) films deposited on PES flexible substrate by using RF magnetron sputtering. The optimization process was performed varying the sputtering parameters, such as RF power and working pressure, and parameter effect on the structural, electrical and optical properties of the ATO films were investigated.

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