• Title/Summary/Keyword: Chemical Sensors

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Ultrasensitive Crack-based Mechanosensor Inspired by Spider's Sensory Organ (거미의 감각기관을 모사한 초민감 균열기반 진동압력센서)

  • Suyoun Oh;Tae-il Kim
    • Journal of the Microelectronics and Packaging Society
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    • v.31 no.1
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    • pp.1-6
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    • 2024
  • Spiders detect even tiny vibrations through their vibrational sensory organs. Leveraging their exceptional vibration sensing abilities, they can detect vibrations caused by prey or predators to plan attacks or perceive threats, utilizing them for survival. This paper introduces a nanoscale crack-based sensor mimicking the spider's sensory organ. Inspired by the slit sensory organ used by spiders to detect vibrations, the sensor with the cracks detects vibrations and pressure with high sensitivity. By controlling the depth of these cracks, they developed a sensor capable of detecting external mechanical signals with remarkable sensitivity. This sensor achieves a gauge factor of 16,000 at 2% strain with an applied tensile stress of 10 N. With high signal-to-noise ratio, it accurately recognizes desired vibrations, as confirmed through various evaluations of external force and biological signals (speech pattern, heart rate, etc.). This underscores the potential of utilizing biomimetic technology for the development of new sensors and their application across diverse industrial fields.

Effects of Blended TIPS-pentacene:ph-BTBT-10 Organic Semiconductors on the Photoresponse Characteristics of Organic Field-effect Transistors (TIPS-pentacene:ph-BTBT-10 혼합 유기반도체가 유기전계효과트랜지스터 광반응 특성에 미치는 영향)

  • Chae Min Park;Eun Kwang Lee
    • Clean Technology
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    • v.30 no.1
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    • pp.13-22
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    • 2024
  • In this study, blended 6,13-Bis(triisopropylsilylethynyl)pentacene (TP):2-Decyl-7-phenyl[1]benzothieno[3,2-b][1] benzothiophene (BT):Poly styrene (PS) TFT at different ratios were explored for their potential application as light absorption sensors. Due to the mixing of BT, both off current reduction and on/off ratio improvement were achieved at the same time. In particular, the TP:BT:PS (1:0.25:1 w/w) sample showed excellent light absorption characteristics, which proved that it is possible to manufacture a high-performance light absorption device. Through analysis of the crystal structure and electrical properties of the various mixing ratios, it was confirmed that the TP:BT:PS (1:0.25:1 w/w) sample was optimal. The results of this study outline the expected effects of this innovation not only for the development of light absorption devices but also for the development of mixed organic semiconductor (OSC) optoelectronic systems. Through this study, the potential to create a multipurpose platform that overcomes the limitations of using a single OSC and the potential to fabricate a high-performance OSC TFT with a fine-tuned optical response were confirmed.

Standardization of Substituent Effects based on Benzobisoxazole Molecule (Benzobisoxazole 분자를 활용한 치환기 효과의 표준화)

  • Changhyeok Yang;Ki-Ho Chung;Kyoung Chul Ko
    • Journal of the Korean Chemical Society
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    • v.68 no.4
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    • pp.185-190
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    • 2024
  • Recently, it was reported that the benzobisoxazole (BBO) molecule can be used for independent modulation of the HOMO and LUMO energy levels. In this study, we utilized this interesting property of BBO to quantitatively investigate the substituent effects according the substituents. We designed and proposed four BBO model systems (1BBO, 2BBO, 3BBO and 4BBO) by extending the π-conjugation lengths based on a BBO molecule. Two directions of substitution (x-axis and y-axis) and 15 various substituents were considered. From strong correlation between the LUMO energy levels of x-axis substitution and HOMO energy levels of y-axis substitution calculated from DFT method, it is found that the standardization of substitution effects can be established from BBO model systems. In addition, we demonstrated that the HOMO values of y-axis substituted 3BBO show the best performance to define the order of substituent effects. Our proposed way can be used to expect the substituent effect of any arbitrary substituents and develop the organic sensors and organic light emitting diodes.

Study of the Surface Acoustic Wave Biosensors for Detection of the Immunoglobulin G (자가면역글로불린 G 측정을 위한 표면탄성파 바이오센서에 대한 연구)

  • Kim, Gi-Beum;Cheong, Woo-Suk;Park, Young-Ran;Kim, Shang-Jin;Kim, Seong-Jong;Kang, Hyung-Sub;Kim, Jin-Shang;Hong, Chul-Un
    • Korean Chemical Engineering Research
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    • v.49 no.2
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    • pp.224-229
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    • 2011
  • In this study, we have developed shear horizontal(SH) surface acoustic wave(SAW) sensors for the detection of immunoglobulin G(IgG) on the gold coated delay line of SH-SAW devices. As the result of the experiment, we could uniformly immobilize anti-MIgG(mouse IgG) conjugate on the surface of gold. When displaying results of immobilization on the surface of gold using G-anti MIgG conjugate and blocking buffer in frequency shift, G-anti MIgG conjugate showed frequency shift of 75.1 kHz in the initial frequency, and blocking buffer showed frequency shift of 215.7 kHz. When various concentrations of MIgG was added in 100MHz type sensor, the sensor showed 46.3, 127.45, 161.21 and 262.39 kHz frequency shift at 25, 50, 75 and 100 ${\mu}g$ MIgG concentration, respectively.

The Application of Octa-Substituted Metallophthalocyanine Langmuir-Blodgett films for $NO_2$ Measurement (수정진동자를 이용한 프탈로시아닌 LB박막의 $NO_2$ 감지 특성)

  • Kwon, H.J.;Lee, Y.J.;Chang, Y.K.;Kim, J.D.
    • Journal of Sensor Science and Technology
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    • v.7 no.4
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    • pp.254-262
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    • 1998
  • Multilayer Langmuir-Blodgett (LB) films coated on quartz crystal microbalance (QCM) of octa-substituted metallophhtalocyanines ($MPc(OEH)_8$, M = Cu, Co, and Sn) and dihydrogen phthalocyanines ($H_2Pc(OEH)_8$) were used to quantify $NO_2$ concentrations. They were exposed to various concentrations of $NO_2$ in dry $N_2$. Among the four phthalocyanines we tested, the metal-free $H_2Pc(OEH)_8$ was observed to be most sensitive to $NO_2$. However, its LB film showed a partially irreversible behavior, that is part of the frequency change due to $NO_2$ adsorption could not be recovered even after purging with pure $N_2$ gas for an extended period. Examining the spectra of NMR and FTIR revealed fact that the irreversible portion of frequency change was due to ether groups in the linkage between side chains and the Pc unit. In order to remove the effect of such initial deactivation, on $NO_2$ quantification experiment, a freshly fabricated LB film was treated at a high concentration of $NO_2$ so that the ether sites were saturated. A pretreated LB film showed a reproducible performance for repeated uses. The $CuPc(OEH)_8$ LB film showed a satisfactory sensing performance down to as low as 4 ppm. For the $H_2Pc(OEH)_8$ LB film, the lower detection limit was found to be 35ppb of $NO_2$. In order to make the experimental condition more realistic, the carrier gas, dry nitrogen, was replaced by air. It was observed that the presence of oxygen, a weak electron acceptor, reduced the sensitivity and thus increased the sensing limit to hundreds of ppb. Results of experiments with moisture added showed that the interference of moisture was quite severe.

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Characterization of CdSe Thin Film Using Chemical Bath Deposition Method (Chemical Bath Deposition 방법으로 제작한 CdSe 박막의 특성)

  • Hong, K.J.;Lee, S.Y.;You, S.H.;Suh, S.S.;Moon, J.D.;Shin, Y.J.;Jeong, T.S.;Shin, H.K.;Kim, T.S.;Song, J.H.;Rheu, K.S.
    • Journal of Sensor Science and Technology
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    • v.2 no.1
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    • pp.81-86
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    • 1993
  • Polycrystalline CdSe thin films were grown on ceramic substrate using a chemical bath deposition (CBD) method. They were annealed at various temperature and X-ray diffraction patterns were measured by X-ray diffractometer in order to study CdSe polycrystal structure. Using extrapolation method of X-ray diffraction patterns for the CdSe samples annealed in $N_{2}$ gas at $450^{\circ}C$ it was found hexagonal structure whose lattice parameters $a_{o}$ and $c_{o}$ were $4.302{\AA}$ and $7.014{\AA}$, respectively. Its grain size was about $0.3{\mu}m$. Hall effect on this sample was measured by Van der Pauw method and studied on carrier density and mobility depending on temperature. From Hall data, the mobility was likely to be decreased by piezo electric scattering at temperature range of 33 K and 200 K, and by polar optical scattering at temperature range of 200 K and 293 K. We measured also spectral response, sensitivity (${\gamma}$), maximum allowable power dissipation and response time on these samples.

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Remote Monitoring Panel and Control System for Chemical, Biological and Radiological Facilities (화생방 방호시설을 위한 원격감시 패널 및 제어시스템)

  • Park, Hyoung-Keun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.1
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    • pp.464-469
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    • 2019
  • A remote monitoring panel and control system was developed to control various valves and access control chambers, including gas shutoff valves used in CBR(Chemical, Biological and Radiological) facilities. The remote monitoring panel consisted of a main panel installed in the NBC (Nuclear, Biological and Chemical) control room and auxiliary panel installed in the clean room, and the size was divided into pure control and control including CCTV. This system can be monitored and controlled remotely according to the situation where an explosion door and gas barrier door can occur during war and during normal times. This system is divided into normal mode and war mode. In particular, it periodically senses the operation status of various valves, sensors, and filters in the CBR facilities to determine if each apparatus and equipment is in normal operation, and remotely alerts situation workers when repair or replacement is necessary. Damage due to the abnormal operation of each device in the situation can be prevented. This enables control of the blower, supply and exhaust damper, emergency generator, and coolant pump according to the state of shutoff valve and positive pressure valve in the occurrence of NBC, and prevents damage caused by abrupt inflow of conventional weapons and nuclear explosions.

Characteristics of Potentiometric Urea Sensors Based on Poly(3-methylthiophene) and Polypyrrole Constructed by Electropolymerization (Poly(3-methylthiophene)과 Polypyrrole을 전기 중합하여 제작한 전위차 요소센서의 특성 비교)

  • Park, Su-Hyun;Jin, Joon-Hyung;Min, Nam-Ki;Hong, Suk-In
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1660-1663
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    • 1999
  • 혈액 내의 요소 농도는 신장병 진단의 척도로서 정확한 측정이 필요하다. 요소의 농도는 전위차법을 이용하여 정확히 검출할 수 있으며 이를 위하여 효소를 고정화시킨 전극형 센서를 사용하였다. 전도성 고분자로서 P3MT(Poly(3-methylthiophene) )와 PPy(polypyrrole)를 효소 고정화에 이용하였다. PPy는 전기적 특성이 좋고 중합 및 효소의 고정화가 용이하며 중합 과정이 상대적으로 신속하고 비용도 저렴하다는 장점은 있으나. 다소 불안정하다. P3MT는 PPy와 마찬가지로 전극 상에 단량체가 전기적 산화에 의하여 중합되고 일반적으로 전해질 이온이 도우핑된 상태나 도우핑 되지 않은 상태 모두에서 산소. 습도. 온도에 대하여 매우 안정하다. 본 연구에서는 3-methylthiophene과 pyrrole을 전기 중합하여 urease를 고정화한 요소센서의 특성(감도, 안정성, 직선성)을 비교하였다. P3MT를 이용한 센서와 PPy를 이용한 센서 각각에 대해 감도는 P3MT가 32.3mV/decade, PPy가 4.7mV/decate로서 P3MT가 우수하였고 직선성도 보다 뛰어났으며 순환 전압 전류 곡선을 분석한 결과 P3MT가 PPy보다 안정성도 우수한 특성을 보였다.

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Design of Capacitive Displacement Sensor and Gap Measurement with High Precision Using Surface Acoustic Wave Device (표면 탄성파 장치를 응용한 용량 성 변위센서의 설계 및 초정밀 간극 측정)

  • Kim, Jae-Geun;Lee, Taek-Joo;Lim, Soo-Cheol;Park, No-Cheol;Park, Young-Pil;Park, Kyoung-Su
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.20 no.5
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    • pp.437-443
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    • 2010
  • SAW device is widely used as band pass filters, chemical or physical sensors, and actuators. In this paper, we propose the capacitive gap measurement system with high precision using SAW device. The research process is mainly composed of theoretical and experimental part. In the theoretical part, equivalent circuit model was used to predict the SAW response by the change of load impedance. In the experimental part, commercialized capacitor was used to see the SAW response by the change of load capacitance to check the feasibility as a sensor unit. After that, experimental setup to measure and adjust the gap was made and the SAW response by the change of gap which caused the capacitance change was measured. Finally, resolution and stroke was decided compared with the signal change and basic measurement noise level.

Fabrication of Pd/poly 3C-SiC Schottky diode hydrogen sensors (다결정 3C-SiC 마이크로 공진기의 온도 특성)

  • Ryu, Kyong-Il;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.130-130
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    • 2009
  • This paper describes the temperature characteristics of polycrystalline 3C-SiC micro resonators. The 1.2 ${\mu}m$ and 0.4 ${\mu}m$ thick polycrystalline 3C-SiC cantilever and doubly clamped beam resonators with 60 ~ 100 ${\mu}m$ lengths were fabricated using a surface micromachining technique. Polycrystalline 3C-SiC micro resonators were actuated by piezoelectric element and their fundamental resonance was measured by a laser vibrometer in vacuum at temperature range of $25{\sim}200^{\circ}C$. The TCF(Temperature Coefficient of Frequency) of 60, 80 and 100 ${\mu}m$ long cantilever resonators were -9.79, -7.72 and -8.0 $ppm/^{\circ}C$. On the other hand, TCF of 60, 80 and 100 ${\mu}m$ long doubly clamped beam resonators were -15.74, -12.55 and -8.35 $ppm/^{\circ}C$. Therefore, polycrystalline 3C-SiC resonators are suitable with RF MEMS devices and bio/chemical sensor applications in harsh environments.

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