• Title/Summary/Keyword: Chemical Sensors

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Synthesis and Optical Chracterization of 2,5-Difunctional Siloles (2,5-Difunctioanl silole의 합성과 광학적 특성)

  • Choi, Tae-Eun;Yang, Jinseok;Han, Joungmin;Um, Sungyong;Jin, Sunghoon;Cho, Bomin;Cho, Sungdong
    • Journal of Integrative Natural Science
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    • v.2 no.1
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    • pp.50-53
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    • 2009
  • New functionalized siloles have been synthesized and their optical characterizations are investigated. Silole unit has been interested, since silole has a unique optical and electronic properties. Here we report the synthesis of new type of photoluminescent silole. New siloles have been characterized by NMR, FTIR, and UV-vis absorption spectroscopy. Their optical characteristics have been also investigated using photoluminescence spectroscopy. Possible applications such as OLED and chemical sensors will be presented.

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Multiple-Bit Encodings of Bragg Photonic-structures by Using Consecutive Etch with Various Square Wave Currents

  • Lee, Bo-Yeon;Hwang, Minwoo;Cho, Hyun;Kim, Hee-Chol;Cho, Sungdong
    • Journal of Integrative Natural Science
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    • v.4 no.3
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    • pp.192-196
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    • 2011
  • New method to encode multiple photonic features of Bragg type reflector on silicon wafer has been investigated. Multiple bit encodes of distributed Bragg reflector features have been prepared by electrochemical etching of crystalline silicon by using various square wave current densities. Optical characterization of multi-encoding of distributed Bragg reflectors on porous silicon was achieved by Ocean optics 2000 spectrometer for the search of possible applications of multiple bit encoding of distributed Bragg reflectors such as multiplexed assays and chemical sensors. The morphology and cross-sectional structure of multi-encoded distributed Bragg reflectors was investigated by field emission scanning electron micrograph.

Molecular Imprints in Nanostructured Polymer Surfaces - A New Generation of Biomimetic Materials for Chemical Sensors

  • Haupt, Karsten
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.31-32
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    • 2006
  • We describe the preparation of nanostructured molecularly-imprinted surfaces using nanomolding on porous alumina. In molecular imprinting functional and cross-linking monomers are copolymerized in the presence of a molecular template, resulting in synthetic receptor materials. The drug propranolol and the dye fluorescein were used as the molecular imprinting templates. Binding studies with imprinted and non-imprinted surfaces revealed specific recognition of the templates and thus the existence of selective binding sites. In addition, the surface properties of the films were studied by water contact angle measurements. It was found that, depending on the monomers used, certain nanostructures induced great changes in the wetting properties of the surface.

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Ultrasensitive metal-oxide gas sensors obtained using colloidal templates

  • Kim, Il-Doo;Rothschild Avner;Hyodo Takeo;Tuller Harry L..
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.247-247
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    • 2006
  • Chemical and physical synthesis routes were combined to prepare macroporous thin films of semiconducting metal-oxides such as $CaCu_{3}Ti_{4}O_{12}\;and\;TiO_{2}$ by sputtering onto (PMMA) microsphere templated substrates. Subsequently, the colloidal templates were removed by thermal decomposition. The remaining inorganic films comprised a monolayer of hollow hemispheres with diameter commensurate with that of the microspheres. This unique morphology increases the surface area and reduces the interfacial area between film and substrate. Consequently, the surface activity is markedly enhanced while deleterious interfacial effects between film and substrate are significantly reduced. Both effects are highly advantageous for gas sensing applications.

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Fault detection of chemical process using observer scheme (Observer를 이용한 화학공정의 이상감지)

  • 최용진;오영석;윤인섭
    • 제어로봇시스템학회:학술대회논문집
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    • 1993.10a
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    • pp.589-594
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    • 1993
  • This paper presents a fault detection strategy that discriminates the faulty sensor and that detects the component fault using a bank of observers for the system in which sensor fault and component fault can occur simultaneously. Observers as many as the number of measurements are designed, and each observer uses measurements excluding sequentially one measurement, to estimate the state variables. The faulty sensor can be found out by comparing each state variable from different observer. Next, component fault can be detected by using measurements from the sensors excluding the faulty sensor. The suggested strategy is applied to a nonisothermal, series reaction with unknown reaction kinetics in a CSTR. This strategy is found out to perform well even in the case that the sensor and component fault occur simultaneously. Since each observer is designed to be independent of reaction kinetics, this strategy is not affected by the model uncertainty and nonlinearity of the reaction kinetics.

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Recent Advances in High-performance Functional Ceramics using 3D Nanostructuring Techniques (3차원 나노구조화 기술을 이용한 고성능 기능성 세라믹 연구개발 동향)

  • Ahn, Changui;Park, Junyong;Jeon, Seokwoo
    • Ceramist
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    • v.22 no.3
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    • pp.230-242
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    • 2019
  • Functional ceramics are widely utilized in a variety of application fields such as structural materials, sensors, energy devices, purification filter and etc due to their high strength, stability and chemical activity. With the breakthrough development of nanotechnology, many researchers have studied new types of nanomaterials including nanoparticle, nanorod, nanowire and nanoplate to realize high-performance ceramics. Especially several groups have focused on the 3D nanostructured ceramics because of their large surface area, efficient load transfer, ultra-fast ion diffusion and superior electrical (or thermal) conductivity. In this review, we introduce the reported fabrication strategies of the 3D nanostructured and functional ceramics, also summarized the 3D nanostructured ceramic based high-performance applications containing photocatalysts, structural materials, energy harvesting and storage devices.

Three-dimensional Nanoporous Graphene-based Materials and Their Applications (3차원 나노 다공성 그래핀의 제조와 응용)

  • Jung, Hyun;Kang, Yein
    • Ceramist
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    • v.22 no.3
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    • pp.243-255
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    • 2019
  • Graphene, a two-dimensional material with a single atomic layer, has recently become a major research focus in various applications such as electronic devices, sensors, energy storage, catalysts, and adsorbents, because of its large theoretical surface area, excellent electrical conductivity, outstanding chemical stability, and good mechanical properties. Recently, 3D nanoporous graphene structures have received tremendous attention to expand the application of 2D graphene. Here, we overview the synthesis of 3D nanoporous graphene network structure with two-dimensional graphite oxide sheets, the control of porous parameters such as specific surface area, pore volume and pore size etc, and the modification of electronic structure by heteroatom doping along with its various applications. The 3D nanoporous graphene shows superior performance in diverse applications as a promising key material. Consequently, 3D nanoporous graphene can lead the future for advanced nanotechnology.

Emerging role of transient receptor potential (TRP) channels in cancer progression

  • Yang, Dongki;Kim, Jaehong
    • BMB Reports
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    • v.53 no.3
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    • pp.125-132
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    • 2020
  • Transient receptor potential (TRP) channels comprise a diverse family of ion channels, the majority of which are calcium permeable and show sophisticated regulatory patterns in response to various environmental cues. Early studies led to the recognition of TRP channels as environmental and chemical sensors. Later studies revealed that TRP channels mediated the regulation of intracellular calcium. Mutations in TRP channel genes result in abnormal regulation of TRP channel function or expression, and interfere with normal spatial and temporal patterns of intracellular local Ca2+ distribution. The resulting dysregulation of multiple downstream effectors, depending on Ca2+ homeostasis, is associated with hallmarks of cancer pathophysiology, including enhanced proliferation, survival and invasion of cancer cells. These findings indicate that TRP channels affect multiple events that control cellular fate and play a key role in cancer progression. This review discusses the accumulating evidence supporting the role of TRP channels in tumorigenesis, with emphasis on prostate cancer.

Application of Electronic Nose for Quality Control of The High Quality and Functional Components (고품질 기능성 물질의 품질관리를 위한 전자코 응용)

  • Noh Bong-Soo
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2006.04a
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    • pp.40-54
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    • 2006
  • It's not easy to detect the high quality and functional compounds for control quality of food materials. The electronic nose was an instrument, which comprised of an array of electronic chemical sensors with partial specificity and an appropriate pattern recognition system, capable of recognizing simple or complex odors. It can conduct fast analysis and provide simple and straightforward results and is best suited for quality control and process monitoring in the field of functional foods. Numbers of applications of an electronic nose in the functional food industry include discrimination of habitats for medicinal food materials, monitoring storage process, lipid oxidation, and quality control of food and/or processing with principal component analysis, neural network analysis and the electronic nose based on GC-SAW sensor. The electronic nose would be possibly useful for a wide variety of quality control in the functional food and plant cultivation when correlating traditional analytical instrumental data with sensory evaluation results or electronic nose data.

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Carbon Nanotubes: State-of-the-art Technology and Safety for Success

  • Endo, Morinobu;Kim, Yoong-Ahm;Hayashi, Takuya
    • Carbon letters
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    • v.10 no.2
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    • pp.87-89
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    • 2009
  • Carbon nanotubes, consisting of rolled graphene layer built from $sp^2$ units, have attracted the imagination of scientists as ideal macromolecules and their unusual physical and chemical properties make them useful in the fabrication of nanocomposites, nano-electronic devices and sensors etc. In this account, the current status and prospect of carbon nanotubes is described with a special emphasis on the safety issue of carbon nanotubes. Even though many challenges to be solved remain, extensive and intensive efforts in both academy and industry will clear out those problems soon and finally enable carbon nanotubes to play a key innovative material of 21st century in numerous industrial processes.